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北京大学, 物理学院, 人工微结构与介观物理国家重点实验室, 北京, 100871
收稿日期:2004-10-15,
修回日期:2004-12-25,
纸质出版日期:2005-05-20
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明帆, 林红斌, 胡成余, 秦志新, 陈志忠, 张国义. TiAl<sub>3</sub>和Ti/TiAl<sub>3</sub>非合金化电极n型GaN欧姆接触的实现[J]. 发光学报, 2005,26(3): 399-403
MING Fan, LIN Hong-bin, HU Cheng-yu, QIN Zhi-xin, CHEN Zhi-zhong, ZHANG Guo-yi. Realization of Nonalloyed TiAl<sub>3</sub> And Ti/TiAl<sub>3</sub> Ohmic Contact to n-GaN[J]. Chinese Journal of Luminescence, 2005,26(3): 399-403
明帆, 林红斌, 胡成余, 秦志新, 陈志忠, 张国义. TiAl<sub>3</sub>和Ti/TiAl<sub>3</sub>非合金化电极n型GaN欧姆接触的实现[J]. 发光学报, 2005,26(3): 399-403 DOI:
MING Fan, LIN Hong-bin, HU Cheng-yu, QIN Zhi-xin, CHEN Zhi-zhong, ZHANG Guo-yi. Realization of Nonalloyed TiAl<sub>3</sub> And Ti/TiAl<sub>3</sub> Ohmic Contact to n-GaN[J]. Chinese Journal of Luminescence, 2005,26(3): 399-403 DOI:
在不进行合金化的情况下
首次直接采用TiAl
3
合金材料作为金属接触电极。在蓝宝石衬底上生长的n型载流子浓度为2×10
18
cm
-3
的GaN上
成功地得到低接触电阻的欧姆接触
并由环形传输线模型方法测得比接触电阻率为3×10
-5
Ω·cm
2
。与通常n型欧姆接触采用的Ti/Al双层结构比较
TiAl
3
合金结构更容易形成非合金化的n型欧姆接触。在此实验基础上
进一步分析了N空位和界面层处的TiAl
3
在形成非合金化或低温退火欧姆接触中发挥的作用
由此设计的Ti/TiAl
3
/Ni/Au接触结构
在TiAl
3
合金结构基础上明显地降低了接触电阻率。
The realization of ohimic contact to n-GaN is usually achieved by using Ti/Al bilayer electrodes with high temperature annealing. Nevertheless
the process of high temperature annealing may destruct the electronic structure of devices
such as quantum well and superlattice structure. The ultimate objective of this research work is to obtain low resistance ohimic contact to n-GaN without high temperature annealing
thus avoiding the destruction of electronic structure effectively. In the research both nonalloyed condition and low temperature annealing are applied. Under nonalloyed condition
we firstly use alloyed TiAl
3
as contact electrode material directly on n-GaN with carrier concentration of 2×10
18
cm
-3
. Compared with conventional Ti/Al bilayer structure
alloyed TiAl
3
structure facilitates the realization of nonalloyed n-type ohmic contact. However
with annealing at 500℃
the contact behavior of Ti/Al bilayer is improved rapidly and achieves ohmic
which is lower than the temperature assumed in some papers. After applying RIE process
both Ti/Al bilayer and TiAl
3
alloyed electrodes behave ohmic
which indicates that the surface of GaN is cleaning
thus intimate contact of Ti and GaN is vital to achieve ohmic contact to n-GaN. In the further experiment
Ti/TiAl
3
bilayer structure is introduced to compare with TiAl
3
alloyed structure. Both of the two structures behave ohmic with RIE process
yet TiAl
3
alloyed shows lower contact resistance
and excess Ti has no obvious effect to contact behavior under nonalloyed condition. After annealing with different temperature
Ti/TiAl
3
bilayer structure tends to form an ohmic contact with lower contact resistance. It proves that excess Ti is activated to form ohmic contact at high temperature annealing. Further analysis implies both of the nitrogen vacancies and TiAl
3
mechanisms play a critical role to form a low contact resistance ohmic contact to n-GaN
under the condition of nonalloyed or low annealing temperature. Accordingly
based on alloyed TiAl
3
structure
Ti/TiAl
3
/Ni/Au structure is designed
which decreases the contact resistance significantly
and the specific contact resistance of 3×10
-5
Ω·cm
2
is obtained with CTLM measurement.The introduction of TiAl
3
alloyed material can make a role as high temperature annealing in the aspect of forming TiAl
3
at the interface. With a certain thickness ratio
Ti/TiAl
3
can achieved low ohmic contact with low temperature annealing. Therefore
TiAl
3
alloyed will be promising in the application field of photoelectron and micro-electron devices that require strict temperature conditions.
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