WANG Zhong-dong, WANG Yu-tian. Theoretical and Experimental Study on Fluorescence Characteristics of Common Pesticides[J]. Chinese Journal of Luminescence, 2005,26(1): 120-124
WANG Zhong-dong, WANG Yu-tian. Theoretical and Experimental Study on Fluorescence Characteristics of Common Pesticides[J]. Chinese Journal of Luminescence, 2005,26(1): 120-124DOI:
The basic principles that a related organic substance can emit fluorescence as it is excited by ultraviolet rays is described
the relationships of molecular structures of organic substances and generation of fluorescence are studied
molecular structures and chemical characteristics of a few common pesticides such as carbaryl
carbofuran
carbisoprocarb and acetamiprid are analyzed and their mechanism of generation of fluorescence is revealed. Moreover
the fluorescence spectrum experiments are conducted by means of a steady-state fluorescent spectrograph with the solutions of carbaryl
carbofuran and acetamiprid using pure methanol
the mixture of 80% of water and 20% of methanol and the alkalescent mixtures (pH=13) as solvents respectively and that their fluorescence spectrograms have been obtained and the relationships of their own molecular structures and characteristics of fluorescence are analyzed. The results indicate that some pesticides
for example carbaryl
carbofuran and acetamiprid
who have groups with plane rigidity structures or conjugate system like aryl ring and heterocyclic ring
can emit fluorescence as they are excited in a certain solvent or under the condition of acid or alkalescence
and they can be analyzed and measured directly or indirectly by fluorescence analysis. Study on fluorescence characteristics of pesticides provides a feasible theoretic basis for further researching and developing a fluorescence spectrometer for pesticides.