WANG Xiao-jun, DUAN Gui-hua, ZHAO Xiao-xia, ZHAO Xue-ping, CUI Yu-ming, SHEN Lian-chun, XIE Yi-hua, YANG Hua. Synthesis and Characterization of Surface-modified BaAl<sub>12</sub>O<sub>19</sub>:Mn<sup>2+</sup>[J]. Chinese Journal of Luminescence, 2005,26(1): 56-60
WANG Xiao-jun, DUAN Gui-hua, ZHAO Xiao-xia, ZHAO Xue-ping, CUI Yu-ming, SHEN Lian-chun, XIE Yi-hua, YANG Hua. Synthesis and Characterization of Surface-modified BaAl<sub>12</sub>O<sub>19</sub>:Mn<sup>2+</sup>[J]. Chinese Journal of Luminescence, 2005,26(1): 56-60DOI:
The plasma display panels PDPs are regarded as a medium of large-format panel display. The performance and lifetime of PDPs are strongly related to the nature of phosphors used in it. The working of PDPs is realized by a conversion of vacuum ultraviolet VUV light to visible light. VUV light has higher energy than that of the ultraviolet (UV) light used as the excitation source of conventional lamp phosphors
therefore
the surface morphology of PDP phosphors suffering from VUV radiation is damaged
and the luminescent performance is decreased with PDPs working time
thus shortening the life of PDPs. This indicates that PDP phosphors should not only have high luminescent efficiency
but also are highly resistant to VUV radiation. Obviously
it is essential to choose an appropriate coating material to resist the VUV radiation.In this work
BaAl
12
O
19
:Mn
2+
powders were prepared by the conventional solid-reaction method. MgF
2
was coated at the surface of BaAl
12
O
19
:Mn
2+
powders by the emulsion method. Some factors
such as reagent concentration and reaction procedure
were investigated
the optimal coating conditions and technique were obtained. The structure analysis of surface-modified (BaAl
12
O
19
:)Mn
2+
powders was performed by XRD
TEM
IR measurements. The phosphor screen was prepared also for the aging measurement.The results indicated that MgF
2
was successfully coated at the surface of BaAl
12
O
19
:Mn
2+
. The luminescent intensity of surface-modified BaAl
12
O
19
:Mn
2+
decreased only 1.6% at the starting. After aging for 8 h
the luminescence decay of surface-modified samples was significantly less than that of non-modified samples.