LAI Hua-sheng, CHEN Bao-jiu, XU Wu, WANG Xiao-jun, XIE Yi-hua, DI Wei-hua. Photoluminescence of Y(P,V)O<sub>4</sub>:Tm<sup>3+</sup> Phosphor Prepared by Coprecipitation Reaction[J]. Chinese Journal of Luminescence, 2005,26(2): 205-210
LAI Hua-sheng, CHEN Bao-jiu, XU Wu, WANG Xiao-jun, XIE Yi-hua, DI Wei-hua. Photoluminescence of Y(P,V)O<sub>4</sub>:Tm<sup>3+</sup> Phosphor Prepared by Coprecipitation Reaction[J]. Chinese Journal of Luminescence, 2005,26(2): 205-210DOI:
Much attention has been paid to search for high-efficient phosphor since the plasma display panels (PDP) edged competitively in the market of large flat panel display. The commercial PDP blue phosphor BaMgAl
10
O
17
:Eu
2+
suffers from decreasing performance of brightness and color because of the serious processing thermal degradation and timing deterioration. New blue phosphor with stable activation ion may be a better way to solve this problem. In the lanthanide series
Tm
3+
may be a feasible candidate for the blue emissions originating from
1
D
2
3
H
4
(around 450nm)
1
G
4
3
H
6
(around 480nm) transitions. Conventionally
the phosphor production is prepared using solid-state reactions between oxide sources at high temperature. However
it is difficult to control over particles size and morphology
uniform dopant concentration. On the contrary to conventional methods
aerosol synthesis technique has been employed successfully to prepared phosphor particles with good morphology in recent years. By coprecipitation reaction
high quality Y(P
V)O
4
:Tm
3+
phosphor was prepared. The phosphor was characterized by XRD
SEM
and photoluminescence under VUV (147nm) or UV (254nm) excitation. The XRD patterns disclosed that the obtained Y(P
V)O
4
:Tm
3+
is not a mixture
but a compound. The SEM image showed that the size of the phosphor particles is uniform and submicron
and the morphology is regular and no agglomeration. Under VUV and UV excitation
there are two emission peaks for most phosphors observed
the narrow one at 475nm originates from the Tm
3+
ion transition
1
G
4
3
H
6
and the weak broad-band around 430nm belongs to VO
4
3-
group. With increasing Tm
3+
concentration
the narrow peak intensity enhanced while the Tm
3+
concentration is lower than 0.005 in mole. When the Tm
3+
concentration is higher than 0.005
the intensity of the transition
1
G
4
3
H
6
decreases with increasing Tm
3+
concentration. The intensity of broad-band de-creases with Tm
3+
concentration in full studied concentration region. It is expected that Y(P