YANG Hai-gui, DAI Zhen-wen, SUN Zhi-wei, SUN Gui-juan. Fluorescent Properties and Lifetimes of <sup>3</sup>P<sub>0</sub> and <sup>1</sup>D<sub>2</sub> Levels in Pr<sup>3+</sup>:ZBLAN Glass[J]. Chinese Journal of Luminescence, 2005,26(1): 42-46
YANG Hai-gui, DAI Zhen-wen, SUN Zhi-wei, SUN Gui-juan. Fluorescent Properties and Lifetimes of <sup>3</sup>P<sub>0</sub> and <sup>1</sup>D<sub>2</sub> Levels in Pr<sup>3+</sup>:ZBLAN Glass[J]. Chinese Journal of Luminescence, 2005,26(1): 42-46DOI:
Heavy-metal fluoride glasses have attracted much attention as host materials due to smaller multi-phonon relaxation rate and high transparence. The optical properties of Pr
3+
ion doped in hosts have also been investigated extensively for its potential application on full-color displays
optical data storage and biomedical instruments. Since detailed spectroscopic studies provide information leading to an assessment of the application of Pr
3+
ions
it is very urgent to explore the optical properties of different levels of Pr
3+
ions in different host materials. The purpose of this paper is to investigate optical characteristics of the
3
P
0
and
1
D
2
levels in Pr
3+
:ZBLAN fluoride glass. Firstly the absorption spectra of Pr
3+
:ZBLAN with two concentrations (110
-3
and 510
-3
in mass fraction were measured by using a spectrophotometer. Then by using time-resolved laser spectroscopy technique
the fluorescence spectra and the lifetimes of the
3
P
0
and
1
D
2
excited states of Pr
3+
ions were investigated under one-photon resonant excitation by a laser beam from the optical parameter oscillator and amplifier system. Experimental fluorescence intensities of the different emission bands were compared with the calculated radiative rates by the Judd-Ofelt theory in literature which indicating that the phenomenological intensity parameters for the Judd-Ofelt theory obtained for Pr
3+
:ZBLAN is reliable. Due to the concentration quenching
the fluorescent intensity of the 110
-3
sample is stronger than that of the 510
-3
sample. However
the lifetimes of the
3
P
0
and
1
D
2
excited states of Pr
3+
ions in ZBLAN glass are not influenced by the concentration. For 110