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集成光电子学国家重点联合实验室吉林大学,吉林 长春,130023
收稿日期:2000-06-18,
修回日期:2000-08-01,
纸质出版日期:2000-08-30
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杨开霞, 黄劲松, 高文宝, 李传南, 赵毅, 刘宏宇, 李峰, 冯晶, 刘式墉. 有机/聚合物白光电致发光器件[J]. 发光学报, 2000,21(3): 257-260
YANG Kai-xia, HUANG Jin-song, GAO Wen-bao, LI Chuan-nan, ZHAO Yi, LIU Hong-yu, LI Feng, FENG Jing, LIU Shi-yong. Organic/Polymer White Light-Emitting Device[J]. Chinese Journal of Luminescence, 2000,21(3): 257-260
杨开霞, 黄劲松, 高文宝, 李传南, 赵毅, 刘宏宇, 李峰, 冯晶, 刘式墉. 有机/聚合物白光电致发光器件[J]. 发光学报, 2000,21(3): 257-260 DOI:
YANG Kai-xia, HUANG Jin-song, GAO Wen-bao, LI Chuan-nan, ZHAO Yi, LIU Hong-yu, LI Feng, FENG Jing, LIU Shi-yong. Organic/Polymer White Light-Emitting Device[J]. Chinese Journal of Luminescence, 2000,21(3): 257-260 DOI:
将聚合物材料作为空穴传输材料
以有机小分子蓝光染料1
1
4
4四苯基丁二烯
绿光染料8-羟基喹啉铝和黄光染料5
6
11
12-四苯基四苯并作为产生白光所需要的三种色源
制备了有机/聚合物白光电致发光器件.这种器件的设计使聚合物的热电稳定性好的优点与有机小分子材料荧光效率高的优点相结合
拓宽了材料的选择范围
更有利于选择能带匹配的材料体系.器件的开启电压为2.5V左右
发光效率在9V时达到最大1.24lm/W
该电压下的亮度达到1600cd/m
2
器件的最大亮度超过20000cd/m
2
(18V)
器件最佳色度为(0.319
0.332)
这在目前国际上有报道的有机/聚合物白光发光器件中居领先水平.
After the first report of a bright green light organic electroluminescent(EL) device by Tang and Van Slyke
intensive research efforts have been made to realize other emission colors. Various emission colors
including blue
green
red and white
can be obtained at high luminance levels
which promises the application of these devices to flat panel full color displays.Among them
white light emission is very important for applying organic EL devices to full display
backlight and illumination light source.Owing to the lack of the single active material
which emits white light
several fluorescent dyes with different emission colors should be used to generate white light.Therefore
it is necessary to develop special device structures for this purpose. This work have developed a high brightness and efficiency white light devices.The device structure of ITO/poly(N-vinylcarbazole)(PVK)/1
1
4
4-tetraphenyl 1
1
3-butadiene(TPB)/aluminum complex(Alq)doped with rubrene/Alq/Mg/Al was employed.The turn-on voltage is as low as 2.5V.Blue fluorescent TPB
orange fluorescent rubrene
and green fluorescent Alq are used as three primary colors.The Commission Internationale de 1′E clairage(C.I.E)coordinates of the emitted light are (x=0.319
y=0.332)at 10V
which is located in the white light region.Bright white-light
over 20000cd/m
2
was successfully obtained
and the maximum efficiency reaches to 1.24lm/W at 9V. In this paper
the structure of the white-light-emitting device belongs to common multilayer structures
but at present the brightness and efficiency of the device was in the lead in international reported white light-emitting devices.The reason the author considered probably are as follows:polymer PVK acts as hole transport layer
the thick PVK layer(200nm)can not only reduce the amount of pinhole of the film
enhance the evenness of the film
but also reduce hole current
namely majority current
which benefit to charge carrier injection balance and improve the formation probability of exciton
and at the same time
the thick PVK layer can depress the jouleheat made by largger current
bring down the effect of heat on fluorescence efficiency of organic material
which also benefit to achieving high-performance devices.
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