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中国科学院长春物理研究所 长春,130021
收稿日期:1993-05-20,
纸质出版日期:1994-02-28
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唐明道, 刘义俊, 罗晞. ZnS型发光材料光老化的研究[J]. 发光学报, 1994,15(1): 33-37
Tang Mingdao, Liu Yijun, Luo Xi. INVESTIGATION FOR PHOTOAGEING OF ZnS TYPE PHOSPHORS[J]. Chinese Journal of Luminescence, 1994,15(1): 33-37
用X射线衍射谱证实了ZnS光致发光材料经紫外线照射后
体色逐渐变灰至黑是由于ZnS离解析出Zn所引起并发现尚有其它组分存在.还研究了不同波长的紫外线照射和材料粒经大小对ZnS发光材料光老化的影响得出一些新的实验结果.
Under UV radiation
the body colour of ZnS type photoluminescent phosphor changes from gray to dark
at the same time the brightness of phosphor decreases (pho-toageing). As well known
light deterioration mechanism has been clarified
that is
under UV radiation
zinc atom which comes from the dissociation of ZnS
results in the brightness decay and the change of material colour. In this paper
the above conclusion has been identified by X-ray diffraction patterns measurement and analysis of ZnS phosphors. It is also found
that non-zinc element impurity phase is presented in X-ray diffraction patterm. The effects of different wavelength UV radiation on light deterioration of phosphors are studied in this paper. It is shown that the photoageing of phosphors is caused by 185nm UV. The effect of particle size on photoageing is also examined
it is concluded
that the smaller the particle size
the more serious the photoageing.
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