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1. 天津理工学院材料物理研究所 天津,300191
2. 东北师范大学化学系 长春,130024
收稿日期:1994-01-29,
纸质出版日期:1994-02-28
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郜军, 华玉林, 黄宗浩, 王荣顺, 谢德民, 白永平, 仇永清. 聚对苯乙炔(PPV)的薄膜电致发光特性[J]. 发光学报, 1994,15(1): 78-80
Gao Jun, Hua Yulin, Huang Zhonghao, Wang Rongshun, Xie Demin, Bai Yongping, Qiu Yongqing. THE THIN FILM ELECTROLUMINESCENCE CHARACTERS OF PPV POLYMER[J]. Chinese Journal of Luminescence, 1994,15(1): 78-80
聚对苯乙炔[poly(p-phenylene vinylene)
缩写为PPV]是一种典型的线性共轭高分子.早在1968年
美国化学家Wessling就宣布合成出了PPV
[1]
但由于当时对该材料的应用前景不清
故未能引起科学界的重视.80年代中期
Murase等用AsF
5
及其它多种掺杂剂成功地对PPV进行了掺杂导电研究
[2]
使其电导率提高了16个数量级
由绝缘体变成了导体.
A kind of polymer electroluminescence (EL) material poly(p-phenylene vinylene) (PPV) was synthesized and the EL devices were fabricated by spin-coatin. It was shown that this material had strong PL and good EL performance
and the spectra shapes changed with the thickness of the PPV thin films
also the EL spectra changed with the drive voltages
this is attributed to the reabsorption of the PPV film itself.Moreover
the PPV film was found can act as the hole transport layer (HTL) of the multi-layer TEFL devices. The EL devices using PPV as HTL and 8-hydroxyquino-line aluminum (Alq3) as emitting material were made
high brihtness more than 3700nt was measured
much better than that of those devices without PPV HTLs.
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