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中国科学院长春物理研究所
收稿日期:1990-06-26,
纸质出版日期:1991-02-28
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何大伟, 李长宽, 赵成久, 周映雪, 于宝贵, 唐明道. (La,Ce,Tb)(PO<sub>4</sub>,BO<sub>3</sub>)的光谱特性研究[J]. 发光学报, 1991,12(1): 40-46
He Dawei, Li Changkuan, Zhao Chengjiu, Zhou Yingxue, Yu Baogui, Tang Mingdao. SPECTROSCOPY OF(La, Ce, Tb)(PO<sub>4</sub>, BO<sub>3</sub> )[J]. Chinese Journal of Luminescence, 1991,12(1): 40-46
何大伟, 李长宽, 赵成久, 周映雪, 于宝贵, 唐明道. (La,Ce,Tb)(PO<sub>4</sub>,BO<sub>3</sub>)的光谱特性研究[J]. 发光学报, 1991,12(1): 40-46 DOI:
He Dawei, Li Changkuan, Zhao Chengjiu, Zhou Yingxue, Yu Baogui, Tang Mingdao. SPECTROSCOPY OF(La, Ce, Tb)(PO<sub>4</sub>, BO<sub>3</sub> )[J]. Chinese Journal of Luminescence, 1991,12(1): 40-46 DOI:
本文合成制备了(La
Ce
Tb)(PO
4
BO
3
)(Gp)绿色发光材料
比较了CeMgAl
11
O
19
:Tb(G
A1
)和Gp在室温下的发光、激发光谱的差异
Gp的
5
D
4
-
7
F
5
跃迁谱线的半宽度及相对强度均小于G
A1
而
5
D
4
-
7
F
3
、
5
D
4
-
7
F
3
跃迁谱线的相对强度则大于G
A1
.激发光谱的差异主要是Gp的激发带强度高于G
A1
自310nm后明显升高
在313nm处的强度比G
A1
提高近3倍
在351、369、377nm处的强度也比G
A1
分别提高近2.3-3.3倍
分析井讨论了Gp和G
A1
在发光、激发光谱上的差异对材料发光性能的影响.发光光谱的差异引起Gp发光色坐标的x值比G
A1
大
而y值变小.激发光谱的差异使得Gp在254nm激发下的发光亮度高于G
A1
在313、365nm激发下的发光亮度则明显高于G
A1
.本文还讨论发La、Ce比对Gp发光性能的影响
只有在Ce的含量为0情况下
Gp的发光性能才显著变化.
Ce
Tb activated LaPO
4
(G
P
) is one of the high effective rare earth green luminescent materials
which has been applied in three basic color fluorescent lamp in the last ten years. In present work
G
P
has been synthesized
analysed and compared with pratical green phosphor CeMgA111O19;Tb(G
A1
) on excitation and emission spectra. It can be seen on emission spectra that the 543nm (
5
D
4
-
7
F
5
) halfwidth of Gp is 3nm smaller than G
A1
and its intensity is lower. The intensities for longer wavelengths 584nm (
5
D
4
-
7
F
4
) and 620nm (
5
D
4
-
7
F
3
) are stronger than that of G
A1
however the y value of which is smaller than G
A1
Therefore
in order to get the same color temperature
when G
P
is selected for the green component
the amount of red phosphor can be deduced.There are some differences in excitation spectra. One is that the measured brightness of G
P
is 7% higher than G
A1
when excited under 254nm. The other is the excitation spectra bands sited after 310nm of Gp are increased
excited intensity of which at 313nm is three times higher than G
A1
. In addition
intensities of G
P
at 351
369 and 377nm are 2-3 times increased than G
A1
. When rare earth three basic phosphors are used for lamps
the luminescence caused by the secondary mercury lines (313
365nm) must be considered. According to the relative intensities of 313nm and 365nm line in low pressure mercury lamp and relative excited intensities of 313nm and 365nm in G
A1
the brightness increased by 313nm and 365nm excitation is calculated. The increasing factor for G
P
is about 1%
but for G
A1
it is only 0.1%. Thus
it is shown that G
P
is of more benefit to the increase of luminous flux in lamp fabrication.This paper also deals with the effects of La
Ce proportion on emission and excitation spectra of G
P
. It is indicated that emission and excitation spectra of G
P
are all the same when La
Ce proportions are different (La is changed from 0 to 0.58
Ce is varied from 0.8 to 0.22). The above fact means that the function of Ce is not only sentisizer but also a part of host which plays the same role as La. In the case of lack of Ce
the emission spectra of G
P
still shows the Tb luminescent lines
but the brightness of which is obviously decreased.
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