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中国科学院长春物理研究所
收稿日期:1990-11-07,
纸质出版日期:1991-08-30
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曹望和, 张联苏, 高福斌. <i>n</i>-Si(As):Yb1130nm四能级发光研究[J]. 发光学报, 1991,12(3): 190-195
Cao Wanghe, Zhang Liansu, Gao Fubin. STUDY OF 1130nm FOUR LEVEL LUMINESCENCE IN <i>n</i>-Si(As):Yb[J]. Chinese Journal of Luminescence, 1991,12(3): 190-195
在
n
-Si(As):Yb中首次观察到1130nm的尖锐发光.通过掺入Yb的剂量与发光强度的关系以及红外吸收、透射光谱的测量
讨论了敏化剂Yb与激活剂As之间能量传递过程.适当选取Yb与As的浓度比可提高发光效率.
The sharp luminescence of
n
-Si(As):Yb at 1130nm is reported for the first time in this paper. Its half width is 23.2nm. The three weak peaks with wavelength of 1190nm(1.04eV)
1150nm(1.08eV) and 1100nm (1.13eV)
respectively
are also observed at the same time. However
the both peaks at 1190nm and 1100nm are observed only when the light signal is amplified. We think that the three lines are the phonon replicas.The experimental results demonstrate that the emission intensity at 1130nm increases with increasing Yb dose. For lower dopar.t ones
especially
the intensity is significantly increased with slightly increasing Yb dose. For the range of ion number between 5×10
12
to 1×10
13
the intensity is almostly proportional to Yb dose. The intersily increasing becomes gradual when Yb exceedes 1×10
13
ions cm
-2
.In order to find the emission evidence
the absorption and tramsmi-ssion spectra (ATS) for the host and the luminescent samples were measured
respectively. Due to having no similar data previously
therefore
ATS oi
n
-Si(As):Er is shown for comparison to
n
-Se(As):Yb. Via an analysis we concluded that:the emission at 1130nm in
n
-Si(As):Yb does not arise from Si bandside; the excited energy of He-Ne laser (632.8nm) is not decrectly absorbed by As impurity in Si; and it does not arise from the radiative transition
2
F
5/2
-
2
F
7/2
of Yb
3+
(4f
13
).Finally
we think that the emission is a result of both sensitizer Yb and activator As. Here Yb acts as a shallow acceptor and is in the vicinity of top of valent band in Si. The energy transfer procedure between Yb and As are discussed
and a four level luminescent mode is proposed. It is found that the luminescent efficiency can be improved by appropriate selection of concentration ratios between Yb and As.
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