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上海科技大学材料系
收稿日期:1990-12-05,
纸质出版日期:1991-11-30
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朱佳, 徐景明, 刘祖刚, 张志林, 许少鸿. Cd<sub>x</sub>Zn<sub>1-x</sub>S:SmF<sub>3</sub>的红色薄膜电致发光[J]. 发光学报, 1991,12(4): 285-290
Zhu Jia, Xu Jingming, Liu Zhugang, Zhang Zhilin, Xu Shaohong. RED THIN FILM ELECTROLUMINESCENCE OF Cd<sub>x</sub>Zn<sub>1-x</sub>:SmF<sub>3</sub>[J]. Chinese Journal of Luminescence, 1991,12(4): 285-290
朱佳, 徐景明, 刘祖刚, 张志林, 许少鸿. Cd<sub>x</sub>Zn<sub>1-x</sub>S:SmF<sub>3</sub>的红色薄膜电致发光[J]. 发光学报, 1991,12(4): 285-290 DOI:
Zhu Jia, Xu Jingming, Liu Zhugang, Zhang Zhilin, Xu Shaohong. RED THIN FILM ELECTROLUMINESCENCE OF Cd<sub>x</sub>Zn<sub>1-x</sub>:SmF<sub>3</sub>[J]. Chinese Journal of Luminescence, 1991,12(4): 285-290 DOI:
本文首次报道了用Cd
x
Zn
1-x
S替代ZnS作为基质
改进SmF
3
的TFEL的实验;通过适当地在基质中掺杂CdS
在一定程度上提高了SmF
3
的TFEL发光亮度;分析了Cd
x
Zn
1-x
S基质中Cd含量对SmF
3
的TFEL的影响
探讨了发光亮度提高的原因.
It is reported in this paper that Cd
x
Zn
1-x
has been used to replace ZnS as the host in order to improve SmF
3
red thin film electrolu-minesence.According to the PL excitation spectra shown in Fig.2
SmF
3
exhibits better EL characteristics in Cd
x
Zn
1-x
than in ZnS crystal.The TFEL panels prepared for the experiment were made with the usual MISIM structure. It is demonstrated in Fig. 3 and Fig. 4 that the luminescence of SmF
3
in CdS doped ZnS host shows higher brightness at the same applied voltage than in pure ZnS when the dope concentration is appropriate.Comparison between the simultaneous emission of Er
3+
and SmEr
3+
in the two different hosts has been made to investigate the cause of brightness increase. As Er
3+
is considered having approximately the same exciting cross-section
it can be deduced from Fig. 6 that Sm has larger cross-section in Cd
x
Zn
1-x
than in ZnS. This is probably due to the change of crystal field of Sm3+ luminecence center.However
the Cd concentration in host influences Sm3+ TFEL characteristics not only in increasing the SmEr
3+
exciting cross-section
but also in causing the drop of the high field in thin film. This is because of the narrower forbidden band and higher mobility of holes and electrons of CdS.The drop of high field will destroy the SmEr
3+
TFEL when the CdS dope is too high. The best value of x in Cd
x
Zn
1-x
obtained in our lab is around 0.13.
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