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中国科学院长春应用化学研究所
收稿日期:1989-04-05,
纸质出版日期:1990-02-28
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于英宁, 孙孝忠, 王文韵. 单态氧(1,0)<sup>1</sup>Δ<sub>g</sub>→<sup>3</sup>∑<sub>g</sub><sup>-</sup>近红外磷光的直接光谱观察[J]. 发光学报, 1990,11(1): 55-60
Yu Yingning, Sun Xiaozhong, Wang Wenyun. DIRECT SPECTROSCOPIC OBSERVATION OF NEAR-INFRARED PHOSPHORESCENCE OF O<sub>2</sub>(<sup>1</sup>△<sub>g</sub>)[J]. Chinese Journal of Luminescence, 1990,11(1): 55-60
于英宁, 孙孝忠, 王文韵. 单态氧(1,0)<sup>1</sup>Δ<sub>g</sub>→<sup>3</sup>∑<sub>g</sub><sup>-</sup>近红外磷光的直接光谱观察[J]. 发光学报, 1990,11(1): 55-60 DOI:
Yu Yingning, Sun Xiaozhong, Wang Wenyun. DIRECT SPECTROSCOPIC OBSERVATION OF NEAR-INFRARED PHOSPHORESCENCE OF O<sub>2</sub>(<sup>1</sup>△<sub>g</sub>)[J]. Chinese Journal of Luminescence, 1990,11(1): 55-60 DOI:
从光谱上直接观察了单态氧~1.07μm谱带。血卟啉、原卟啉、卟啉C和四氯四碘荧光素钠等含极性基团的光敏剂与非极性的四苯基卟吩在相同的溶剂中所产生的谱带形状有所不同
测量了
β
-胡萝卜素对单态氧的猝灭常数
与文献在1.27μm测得的数值一致。
The chemicd and kinetic properties of singlet molecular oxygen in liquid phase have attracted much attention of chemists and biochemists owing to its involvement in many chemical and biological processes. This transient entity
however
had evaded direct observation until a decade ago when the 1270nm luminescence from the forbidden tiansition
1
△
g
O
2
(v=O)→
3
∑
g
-
O
2
(v=O) was detected via photosensitization in solution. The success of this measurement was achieved by using germanium photodiode (with much highei sensitivity in the infrared legion than in the visible region in contrast to photomultipliei tubes) coupled to fast
high-gain amplifiers. However
Ge photodiodes satisfying the measurement of ultra-weak 1270 nm band of O
2
(
1
△
g
) are not yet available in our country. Based on the results of Krasnovsky in direct observation of singlet oxygen emission at 1270 nm with red-sensitive PMT
it is of interest to see the feasibility to detect the (1
0) transition emission of O
2
(
1
△
g
) at 1070 nm by using PMT of S-1 photocathode with a spectral response ranging from 300 to 1150 nm
and a successful demonstration of this proposed approach is described in this paper.
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