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上海科学技术大学材料系
收稿日期:1989-11-23,
纸质出版日期:1990-08-30
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蒋雪茵, 张志林, 许少鸿. 粉末LaOCl:Eu<sup>3+</sup>的<sup>5</sup>D<sub>1</sub>能级的无辐射跃迁几率[J]. 发光学报, 1990,11(3): 161-166
Jiang Xueyin, Zhang Zhilin, Xu Shaohong. NONRADIATIVE TRANSITION PROBABILITY OF <sup>5</sup>D<sub>1</sub> STATE IN POWDER LaOCl:Eu<sup>3+</sup>[J]. Chinese Journal of Luminescence, 1990,11(3): 161-166
蒋雪茵, 张志林, 许少鸿. 粉末LaOCl:Eu<sup>3+</sup>的<sup>5</sup>D<sub>1</sub>能级的无辐射跃迁几率[J]. 发光学报, 1990,11(3): 161-166 DOI:
Jiang Xueyin, Zhang Zhilin, Xu Shaohong. NONRADIATIVE TRANSITION PROBABILITY OF <sup>5</sup>D<sub>1</sub> STATE IN POWDER LaOCl:Eu<sup>3+</sup>[J]. Chinese Journal of Luminescence, 1990,11(3): 161-166 DOI:
本文使用多次漫反射法测得粉末LaOCl:Eu的漫反射吸收谱
结合所测的LaOCl:Eu的激发光谱
直接得出
5
D
1
能级的无辐射量子效率
再由所测
5
D
1
能级寿命得出它的无辐射跃迁几率。另一方面
使用Ω参数法
即利用Ω参数计算
5
D
1
的辐射跃迁几率
然后由所测寿命值计算出无辐射跃迁几率
来验证第一种方法所得结果。两者结果接近
表明前一种方法是简便可行的。
To methods have been used to determine the non-radiative transition probability of
5
D
1
state of Eu
3+
.(1)Partlo's method.The quantum efficiency from state A to state B(Fig.4) can be obtained from the absorption spectrum and the excitation spectrum according to formula(1)
where
P
A
and
P
B
are the power absorbed by A and B respectivel
P
AL
and P
BL
are the emission intensities of L generated by excitation to A state and B state respectivel
and
v
A
and
v
B
are respectively the energies(in wavenumber) of A and B. The absorption spectrum of the phosphor can be determined from the diffuse reflection spectrum according to our previous work. The quantum efficienc from
5
D
1
to
5
D
0
is then determined to be 79.6%. The non-radiative transition probability of
5
D
1
is 5.64×10
-3
/sec.(2)Judd-Ofelt's method. In calculating the intensity parameters j(j=2
4
6) from the emission spectrum according to J-O theory the index of refraction n of LaOCl(which is unkno n) is evaluated by the method we proposed in a recent paper.The nonradiative transition probability of
5
D
1
which can be obtained from the radiative transition probability of
5
D
1
to
7
F
j
(for all j values) and the measuied lifetime
is 5.28×10
-3
/sec
which agree fairly well with the fromer value.It appears that the first method is more convenient and probably more accurate.
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