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中国科学院长春应用化学研究所
收稿日期:1988-09-13,
纸质出版日期:1989-05-30
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孙焕英, 刘彤宇. 同质白色ACEL粉末材料的研究[J]. 发光学报, 1989,10(2): 147-151
Sun Huanying, Liu Tongyu. THE STUDY OF WHITE-EMITTING HOMOGENENOUS ACEL POWDER[J]. Chinese Journal of Luminescence, 1989,10(2): 147-151
通过对C440/Fl.Na/Saf.-T三元混合染料体系的荧光光谱研究
了解到这三种染料之间有较充分的能量转移。又通过对C440/Fl.Na和Fl.Na/Saf.-T两个混合染料体系的荧光寿命测量
讨论了分子间能量转移过程和机理
并做了一些定量的分析。
The energy transfer in a proper mixture of dyes is now established as an effective mechanism of extending the wavelength region of lasing and of achieving more efficient conversion of pump light by an organic dye which alone has only small absorption at a particular pump laser wavelength (for example 337.1nm nitrogen line).It has been reported in literature that attempts made to lase safranin-T using nitrogen laser without a donor were unsuccessful
and accordingly Rho-damine6G/Safranin-T dys mixture is proposed to lase the latter.As is known that Coumarin 440 is a laser dye which strongly absorbs the 337.1nm radiation from the nitrogen laser.If an intermediary dye could be found to couple Coumarin 440 and Safranin-T spectrally
then an ternary energy transfer laser dye system might be formed. Motivated by this intention
we have investigated on the Coumarin 440/Fluorescein scdium/Safranin-T(C440/F1.Na/Saf.-T) dye mixture system. Since there are good overlaps between the fluorescence of C440 and the absorption of F1.Na and between the fluorescence of Fl.Na and the absorption of Saf.-T
and in the mean time the fluorescence quantum yields of these dyes are all reasonably high
we can predict an efficient energy transfer of the excitation from C440 cascading through Fl.Na to Saf.-T.
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