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中国科学院感光化学研究所
收稿日期:1988-02-18,
纸质出版日期:1989-11-30
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叶建平, 虞群, 曹红, 寿涵森. 水杨酸酯-铽络合物的发光及其向铕离子的能量传递[J]. 发光学报, 1989,10(4): 325-331
Ye Jianping, Yu Qun, Cao Hong, Shou Hanscn. LUMINESCENCE OF TERBIUM (Ⅱ)-SALICYLATE COMPLEX AND ITS ENERGY TRANSFER TO EUROPIUM(Ⅲ)[J]. Chinese Journal of Luminescence, 1989,10(4): 325-331
本文应用稳态和瞬态光谱技术探讨了稀土离子铽与水杨酸甲酯
苯酯所形成络合物的发光特性
它们向铕离子的能量传递过程;以及pH值对络合物的发光和能量传递的影响。络合物的发光比络合前铽离子的发光增强了几至十几倍;介质的pH变化影响到络合物的发光强度和能量传递效率
中性介质(pH:6~8)下的量传递效率最高。
The formation and luminescence properties of the complex of terbium ion (Tb
3+
)-salicylates (methyl salicylate MS
and phenyl salicylate PS) and the energy transfer processes from the complex to europium ion (Eu
3+
) have been investigated by use of the steady state and transient state time-resolved emission spectroscopy.From the fluorecence spectra and lifetime data of the MP system (Table 1)
it can be seen that
with the increase of Tb
3+
concentration
the fluorescence intensity of the MP decreases and the characteristic emission of Tb
3+
ions increases.Plots of F
0
/F against the concentration of Tb
3+
ions satisfy the Stern-Volmer equation.But the fluorescence lifetime remains constant
τ
0
/τ≈1. this is a typical static quenching process
[4]
. Absorption changes are also observed in the absorption spectra and the absorption peaks of complex appear at longer wavelength than those of MS and PS do.We can conclude from the study that Tb
3+
ions form steady complex in ground state with MP
MS by certain proportion and transfer the absorption energy effectively to center Tb
3+
ions. The terbium luminescence intensity is increased by many times in the complex than that in the studied systems.
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