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上海科技大学材料科学系
收稿日期:1988-02-29,
纸质出版日期:1989-08-30
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丁兰芳, 蒋雪茵, 张志林, 许少鸿. ZnS:Eu<sup>2+</sup>的长余辉发光[J]. 发光学报, 1989,10(3): 263-264
Ding Lanfang, Jiang Xueyin, Zhang Zhilin, Xu Shaohong. LONG PERSISTENT LUMINESCENCE OF ZnS:Eu<sup>2+</sup>[J]. Chinese Journal of Luminescence, 1989,10(3): 263-264
Eu
2+
的5d能级在许多晶体中都低于其4f能级的最低激发态(
6
P
7/2
)
因此发光呈带状光谱
且发射波长随基质变化很大。由于5L→4f是容许跃迁
所以发光的衰减很快
通常在μs数量级
出人意料的是ZnS:Eu的发光尽管也是Eu
2+
的5d→4f跃迁
但衰减却极慢
达几十分钟的数量级。弛豫曲线的分析表明
这种长的弛豫是电子陷阱造成的。
An abnormal property of luminescence of ZnS:Eu
2+
is reported.The excitation and emission spectra of ZnS:Eu
2+
are shown in Fig.1. Both are wide bands peaking at 400 nm and 550 nm respectively. This indicates that the luminescence is due to f-d transition of Eu
2+
.The afterglow of the yellow emission was measured.It was surprising to observe that the decay turns out to be tens of minutes long and follow a power law
I
≅
t
-n
with n=1.24 (Fig.2).Since f-d transition is an allowed one
the luminescence corresponding to it should have a very short lifetime
e. g. 1us. So it is believed that this long persistent afterglow must be due to the existence of some kind of electron traps
the origin and the nature of which are to be clarified.
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