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中国科学院长春应用化学研究所
纸质出版日期:1986-02-28
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苏锵. 稀土有机化合物的发光与能量传递[J]. 发光学报, 1986,7(1): 1-5
Su Qiang. LUMINESCENCE AND ENERGY TRANSFER OF RARE EARTH ORGANIC COMPOUNDS[J]. Chinese Journal of Luminescence, 1986,7(1): 1-5
本文讨论了稀土有机化合物发光的能量传递过程;有机配位体的三重态相对于稀土离子的激发态的位置关系;形成三元配合物后对发光强度和谱带劈裂的影响;有机物中具有高能振动的含氢基团对荧光的猝灭作用;以及水分子的存在与采用不同的有机溶剂等因素对稀土发光的影响。文中还介绍了稀土有机发光材料的可能应用。
The energy transfer in the rare earth organic phosphors was discussed. Organic ligands with suitable position of triplet may be used to sensitize the luminescence of rare earth ions
or the position of the triplet of the organic ligands may be estimated according to the position of theof the excited state of the luminescent rare earth ions. The intensity of emission may be enhanced and the emission bands may be splitted by the formation of organic complexes
especially of organic complexes with mixed ligands. But the function groups containing hydrogen such as -OH having high vibronic frequence may quench the luminescence of the rare earth ions
so the intensity of emission and the lifetime may be enhanced by use of the deuterated or fluorinated organic compounds or systems containing other heavy atoms. Therefore
organic solvents or water molecules have important effect on the luminescence of the rare earth ions. Rare earth organic phosphors have been used in such fields as: liquid laser materials
solar luminescence concen-tractor
luminescent plastic films
detection of defects
diagnosis of integrated circuit by thermal imaging
analysis of trace amount of rare earth and luminescent probes for biomolecular systems.
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