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中国科学院长春物理研究所
收稿日期:1985-06-06,
纸质出版日期:1985-11-30
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王汪, 张开义, 潘金声. 体极化子的类相变行为[J]. 发光学报, 1985,6(4): 278-293
Wang Wang, Zhang Kaiyi, Pan Jinsheng. THE PHASE TRANSITION-LIKE BEHAVIOUR OF THE BULK POLARON[J]. Chinese Journal of Luminescence, 1985,6(4): 278-293
本文将电子的动量和位置的线性组合作为算符
应用了Bogolyubov不等式
并对哈密顿量进行两次么正变换
对电子-声子耦合常数α的整个区域和温度的尽可能广泛范围计算了体极化子的基态能量
有效质量及电子周围的平均声子数。发现对应一定的温度
当α超过一定值α
c
时
极化子将发生相变。并且本文还找到了一个临界温度
T
c
当温度大于
T
c
与温度小于
T
c
时其相变行为是不同的。
Recently
there present many works to discuss the phase transition-like behaviour of the polaron in polar crystals. However
all these works didn't consider the incorporate effect of the temperature and electron-phonon Frohlich Coupling constant r. In this paper
starting from the Bogolyubov inequality for the free energy
we discuss this incorporate effect on the phase transition-like behaviour of the polaron.The Hamiltonian of a system consisting of the electrons and phonons is shown as (2.1) in the text. And assume that the Bogolyubov ineqality between the real free energy
F(H)
and the model free energy
F
mod
(H)
also holds for the polaron. The Bogolyubov ineqality has the form (2.4) in the text. In this representation
H
can be regarded as the sum of
H
0
and a perturbed term (
H-H
0
).
H
0
is represented [by (2.8) which is called the model Hamiltonian. In the course of calculation
we introduce two unitary transformations U
1
and U
2
. Then
applying these transformations to (2.4)
we finally obtain the expression (2.27) from which the free energy can be determinded. Lagrange multiplier
u
in (2.27) has the meaning of the translation velocity of the polaron. The effective mass of the polaron and the mean numbers of phonons N in the cloud around the electron are
respectively
represented by (3.5) and (3.6). The expectation value of the polaron energy with respect to the ground state |0
>
at the different temperature is expressed by (3.4).
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