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中国科学技术大学物理系
收稿日期:1985-01-29,
纸质出版日期:1985-08-30
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杨明, 金东明, 张慰萍, 姜文娣, 王冠中, 方容川. LaOBr:Er<sup>3+</sup>,Tm<sup>3+</sup>红外跃迁的研究[J]. 发光学报, 1985,6(3): 179-185
Yang Ming, Jin Dongming, Zhang Weiping, Jiang Wendi, Wang Guanzhong, Fang Rongchuan. INFRARED TRANSITIONS IN LaOBr:Er<sup>3+</sup>,Tm<sup>3+</sup> PHOSPHORS[J]. Chinese Journal of Luminescence, 1985,6(3): 179-185
杨明, 金东明, 张慰萍, 姜文娣, 王冠中, 方容川. LaOBr:Er<sup>3+</sup>,Tm<sup>3+</sup>红外跃迁的研究[J]. 发光学报, 1985,6(3): 179-185 DOI:
Yang Ming, Jin Dongming, Zhang Weiping, Jiang Wendi, Wang Guanzhong, Fang Rongchuan. INFRARED TRANSITIONS IN LaOBr:Er<sup>3+</sup>,Tm<sup>3+</sup> PHOSPHORS[J]. Chinese Journal of Luminescence, 1985,6(3): 179-185 DOI:
对在基质LaOBr中分别加入Er
3+
和Tm
3+
稀土离子时的红外光谱强度随Er
3+
和Tm
3+
离子浓度的变化规律进行了研究.通过对在基质LaOBr中同时加入Er
3+
和Tm
3+
稀土离子对它们的发光强度随着浓度的变化呈现不同规律的研究
证实了发生于Er
3+
和Tm
3+
稀土离子之间的能量转移是影响Er
3+
和Tm
3+
红外发光的重要因素.并且
这种能量转移过程是以共振传递的方式进行的.另外
通过对Er
3+
的
4
S
3/2
能级寿命的测量
给出这种能量转移的直接证据.
The purpose of this paper is to investigate infrared transtions of Er
3+
and Tm
3+
ions and energy transfer between them in LaOBr material.Jouart has studied energy transfer between Er
3+
and Tm
3+
ions in cadimium fluoride crystals
[1]
.But there are no publishes about energy transfer between Er
3+
and Tm
3+
ions in rare earth material in the infrared region so far.Here we present the results for energy transfer between Er
3+
and Tm
3+
ions in the LaOBr material for the first time.We find that there are a number of luminescence lines of Er
3+
and Tm
3+
ions jn the infrared region from 0.8μ to 2.0μ by the excitation of 5145Åor 4880Åof argon laser.They come seperately from four energy levels of Er
3+
and Tm
3+
ions.The intensities of fluorescence of Er
3+
and Tm
3+
ions strongly depend on the concentration of Er
3+
and Tm
3+
ions.Coresponding to emission lines from different energy levels of ions
the laws of concentration quenching are different.This kind of self-quenching phenomenon may be related with the interactions of multipolar cross relaxation of Er
3+
and Tm
3+
ions energy levels.Our results provide an information to look for the best doping-con-centration of infrared transitions of this kind of material.
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