
浏览全部资源
扫码关注微信
中国科学院长春物理研究所
纸质出版:1984-05-30
移动端阅览
刘行仁, 马龙. YAG:Ce,Tb磷光体中的能量传递现象[J]. 发光学报, 1984,5(2): 93-96
Liu Xingren, Ma Long. ENERGY TRANSFER PHENOMENON IN YAG:Ce,Tb[J]. Chinese Journal of Luminescence, 1984,5(2): 93-96
引言 Ce
3+
和Tb
3+
等稀土离子激活的YAG发光材料已引起人们的兴趣.我们对YAG:Ce
Tb磷光体的阴极射线发光性质已进行了研究.在进一步研究时
我们发现在紫外线激发下
能量从Tb
3+
离子传递到Ce
3+
离子的现象.在过去的一些报导中
能量多是从Ce
3+
离子传递给Tb
3+
离子的.这种反过来传递的过程还是不多见的.
Energy transfer between different kinds of rare earth ions has been studied in various hosts coactivated by Ces and Tb3+17-14. It has been found that in all cases the excitation energy transfers from Ce
3+
to Tb
3+
. In investigating the. photoluminescence of YAG:Ce
Tb phosphors
however
excitation energy is found to transfer from Tb
3+
to Ce
3+
. This is shown in Fig.5 and 6 where a new excitation band appears at 270nm for YAG: Ce
Tb when the intensity of Ce
3+
emission at 520nm is monitored. This band excites Tb3+ luminescence quite efficiently in YAG:Tb
3+
(Fig.3) but is almost ineffective for the Ce
3+
520nm emission in YAGsCe
3+
(Fig.4)
unless the latter is codoped with Tb
3+
. These results imply that the energy absorbed by Tb
3+
ions transfers to Ce
3+
ions.
0
浏览量
87
下载量
0
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621