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中国科学院长春物理研究所
收稿日期:1985-04-15,
纸质出版日期:1985-11-30
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赵福潭, 曹丽芸, 徐叙瑢. LaOBr:Ce<sup>3+</sup>,Tb<sup>3+</sup>中Ce<sup>3+</sup>与Tb<sup>3+</sup>间能量传递[J]. 发光学报, 1985,6(4): 305-313
Zhao Futan, Cao Liyun, Xu Xurong. ENERGY TRANSFER FROM Ce<sup>3+</sup> TO Tb<sup>3+</sup> IN LaOBr: Ce<sup>3+</sup>, Tb<sup>3+</sup> POWDER[J]. Chinese Journal of Luminescence, 1985,6(4): 305-313
赵福潭, 曹丽芸, 徐叙瑢. LaOBr:Ce<sup>3+</sup>,Tb<sup>3+</sup>中Ce<sup>3+</sup>与Tb<sup>3+</sup>间能量传递[J]. 发光学报, 1985,6(4): 305-313 DOI:
Zhao Futan, Cao Liyun, Xu Xurong. ENERGY TRANSFER FROM Ce<sup>3+</sup> TO Tb<sup>3+</sup> IN LaOBr: Ce<sup>3+</sup>, Tb<sup>3+</sup> POWDER[J]. Chinese Journal of Luminescence, 1985,6(4): 305-313 DOI:
本文利用毫微秒技术在ns秒量级测量了不同浓度组分的LaOBr:Ce
3+
Tb
3+
中Ce
3+
发射带的衰减常数τC
e
值和时间分辨光谱
确立了Ce
3
到Tb
3+
能量传递过程模型
建立了动力学方程和导出能量传递的计算公式。据此计算出Ce
3+
到Tb
3+
的能量传递几率和效率
得出Ce
3+
Tb
3+
的最佳浓度。
We have systematically studied the interaction between Ce
3+
and Tb
3+
ions in LaOBr: Ce
3+
Tb
3+
. We have measured emission spectra of a series of samples with the model MPF-4 spectrometer.The excitation wavelength is 337nm.The emission spectra of LaOBr:Tb
3+
consist of the
5
D
3
-
7
F
J
and
5
D
4
-
7
F
J
(J=0
1
2
…
6) transitions. The main characteristic lines in these two groups are
5
D
3
-
7
F
J
(415.9nm
436.6nm) and
5
D
4
-
7
F
J
(485.4nm
543.1nm) transitions. In the emission spectra of the LaOBr: Ce
3+
Tb
3+
there are not only the emission band of the Ce
3+
but also the
5
D
3
-
7
F
J
and
5
D
4
-
7
F
J
transitions of the Tb
3+
ion when xce≤3×10
-4
. But the emission intensity of the Tb
3+
ion is about 15-25 times higher than that of the sample without Ce
3+
ion.The emission spectra of the LaOBr:Ce
3+
Tb
3+
consist of the emission band of the Ce
3+
ion and the emission lines of the Tb
3+
ion
which is only
5
D
4
-
7
F
J
when
x
Ce
>
3×10
-3
. The emission intensity of the Tb
3+
ion (
5
D
4
-
7
F
J
) increases with the increasing Ce
3+
concentration.
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