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中国科学院长春应用化学研究所
收稿日期:1985-08-20,
纸质出版日期:1985-02-28
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白云起, 孙长英, 张思远. Dy<sub>x</sub>Tb<sub>y</sub>Y<sub>1-x-y</sub>P<sub>5</sub>O<sub>14</sub>晶体的荧光性质[J]. 发光学报, 1985,6(1): 41-45
Bai Yunqi, Sun Changying, Zhang Siyuan. FLUORESCENT PRQPERTIES OF DY<sub>x</sub>Tb<sub>y</sub>Y<sub>1-x-y</sub>P<sub>5</sub>O<sub>14</sub> CRYSTALS[J]. Chinese Journal of Luminescence, 1985,6(1): 41-45
白云起, 孙长英, 张思远. Dy<sub>x</sub>Tb<sub>y</sub>Y<sub>1-x-y</sub>P<sub>5</sub>O<sub>14</sub>晶体的荧光性质[J]. 发光学报, 1985,6(1): 41-45 DOI:
Bai Yunqi, Sun Changying, Zhang Siyuan. FLUORESCENT PRQPERTIES OF DY<sub>x</sub>Tb<sub>y</sub>Y<sub>1-x-y</sub>P<sub>5</sub>O<sub>14</sub> CRYSTALS[J]. Chinese Journal of Luminescence, 1985,6(1): 41-45 DOI:
研究了Dy
x
Tb
g
Y
1-x-y
P
5
O
14
晶体的荧光特征
Dy
3+
离子对Tb
3+
离子
5
D
3
能级的猝灭作用和对
5
D
4
能级的敏化作用
讨论了Tb
3+
离子和Dy
3+
离子浓度间的关系及对荧光强度和荧光寿命的影响。
In this paper
the fluorescent properties of Dy
x
Tb
y
Y
1-x-y
P
5
O
14
crystals have been investigated. An important difference with Tb
x
Tb
y
Y
1-x-y
P
5
O
14
crystals is that the
5
D
3
-
7
F
J
transitions of Tb
3+
ions are quenched at low concentration and
5
D
4
-
7
F
J
transitions of Tb3+ ions are sensitized because the Dy
3+
presents in crystals. The reason is that the
5
D
3
-
5
D
4
transition of Tb
3+
and the
6
H
15/2
-
6
H
11/2
transition of Dy
3+
produce the cross relaxation
in addition to the
7
F
8
-
7
F
0
transition of Tb
3+
.We compared the fluorescent intensities between Tb
0.1
Dy
0.1
Y
0.8
P
5
O
14
and Tb
0.1
Dy
0.1
Y
0.9
P
5
O
14
crystals
it was found that the fluorescent intensities of Tb
0.1
Dy
0.1
Y
0.8
P
5
O
14
crystals was much stronger than Tb
0.1
Dy
0.1
Y
0.9
P
5
O
14
crystals in the same condition. When the Tb
3+
concentration is constant
the fluorescent intensities of Tb
3+
decrease with the increase of Dy
3+
concentration
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