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中国科学院长春应用化学研究所
收稿:1983-08-26,
纸质出版:1984-02-29
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苏锵, 王庆元, 武士学, 洪广言, 越淑英. 用Judd-Ofelt理论计算TmP<sub>5</sub>O<sub>14</sub>晶体中Tm<sup>3+</sup>的光谱参数[J]. 发光学报, 1984,5(1): 19-28
Su Qiang, Wang Qing-yuan, Wu Shi-xue, Hong Guang-yan, Yue Shu-ying. SPECTRAL PARAMETERS OF Tm<sup>3+</sup> IN CRYSTAL TmP<sub>5</sub>O<sub>14</sub> CALCULATED BY JUDD-OFELT THEORY[J]. Chinese Journal of Luminescence, 1984,5(1): 19-28
苏锵, 王庆元, 武士学, 洪广言, 越淑英. 用Judd-Ofelt理论计算TmP<sub>5</sub>O<sub>14</sub>晶体中Tm<sup>3+</sup>的光谱参数[J]. 发光学报, 1984,5(1): 19-28 DOI:
Su Qiang, Wang Qing-yuan, Wu Shi-xue, Hong Guang-yan, Yue Shu-ying. SPECTRAL PARAMETERS OF Tm<sup>3+</sup> IN CRYSTAL TmP<sub>5</sub>O<sub>14</sub> CALCULATED BY JUDD-OFELT THEORY[J]. Chinese Journal of Luminescence, 1984,5(1): 19-28 DOI:
根据Judd-Ofelt理论
测得了Tm
3+
在TmP
5
O
14
晶体中的强度参数分别为Q
2
=:1.50×10
-20
cm
2
Q
4
=1.51×10
-20
cm
2
Q
6
=0.916×10
-20
cm
2
计算的振子强度P
cal
.与实验值P
exp
.符合较好
平均根方误差为2.60×10
-7
。求得Q
λ
后
计算了J多重激发态之间的振子强度
自发辐射跃迁速率
辐射寿命和荧光分支出
与YAlO
3
:Tm
3+
YAG:Tm
3+
、Y
2
O
3
:Tm
3+
等晶体和掺Tm
3+
玻璃的光谱参数进行了比较
并就
3
H
4
→3H
6
3
F
4
→
3
H
5
1
D
2
→3H
4
和
1
G
4
→
3
H
4
的跃迁进行了对比和讨论。观察到Tm
3+
在不同介质中的P
exp
.与强度参数的总和∑τλ=τ
2
+τ
4
+τ
6
存在P
exp
=α∑τλ+b的关系。
According to Judd-Ofelt theory the intensity parameters of Tm
3+
in crystal TmP
5
O
14
were measured.Their values are Ω
2
=1.50×10
-20
cm
2
Q
4
=1.5×10
-20
cm
2
and Ω
6
=0.916×10
-20
cm
2
respectively.The calculated oscillator strengths Pcal.agree with the experimental values Paxp.quite well
the root mean square deviation(rms)is 2.60×10
-7
.With these Ω
λ
values
the oscillator strengths
spontaneous radiative transition rates
radiative lifetimes and branching ratios between the excited J manifolds were calculated.The spectral parameters obtained were compared with
those of crytals YAlOs:Tm
3+
YAG:Tm
3+
Y
2
O
3
:Tm
3+
and glasses doped with Tm
3+
.The summation of intensity parameters(∑τλ=τz +τ
4
+τ
6
)of Tm
3+
in crystal TmP
5
O
14
are lower than those of phosphate glass as well as other glasses(borate
germanate and tellurate).∑τλ is a parameter
we found that it is proportional to the oscillator strength P and may be expressed by following equation:P=α∑τλ+b where a and b are two constants obtained from experiments.
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