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中国科学技术大学物理系
收稿:1983-09-14,
纸质出版:1984-02-29
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汪鸿, 施朝淑, 楼立人, 张慰萍, 陆肖璞, 张纪法. LaOBr:Ce,Tb中Ce<sup>3+</sup>对Tb<sup>3+</sup>发光的影响[J]. 发光学报, 1984,5(1): 36-43
Wang Hong, Shi Chao-shu, Lou Li-ren, Zhang Wei-ping, Lu Xiao-pu, Zhang Ji-fa. THE EFFECT OF Ce<sup>3+</sup> ON Tb<sup>3+</sup> LUMINESCENCE IN LaOBr:Tb<sup>3+</sup>,Ce<sup>3+</sup>[J]. Chinese Journal of Luminescence, 1984,5(1): 36-43
汪鸿, 施朝淑, 楼立人, 张慰萍, 陆肖璞, 张纪法. LaOBr:Ce,Tb中Ce<sup>3+</sup>对Tb<sup>3+</sup>发光的影响[J]. 发光学报, 1984,5(1): 36-43 DOI:
Wang Hong, Shi Chao-shu, Lou Li-ren, Zhang Wei-ping, Lu Xiao-pu, Zhang Ji-fa. THE EFFECT OF Ce<sup>3+</sup> ON Tb<sup>3+</sup> LUMINESCENCE IN LaOBr:Tb<sup>3+</sup>,Ce<sup>3+</sup>[J]. Chinese Journal of Luminescence, 1984,5(1): 36-43 DOI:
近年来人们对LaOBr:Tb的合成及其发光特性的研究日益增多。LaOBr:Tb不仅是良好的X光增感屏材料
也是较好的阴极射线发光材料。为了进一步提高它的亮度
降低了b的含量(因Tb很贵)
寻求LaOBr中Tb
3+
发光的敏化剂是很重要的。
The luminescence of LaOBr:Ce
LaOBr:Ce
Tb and LaOBr:Tb phosphors under UV and cathode ray excitation has been studied.The excitation spectra of Tb
3+
ion in LaOBr:Tb consists of a strong broad 4f→5d transition band at 254nm and some weak 4f→4f transition lines in the wavelength range of 300-400nm.The excitation bands of LaOBr:Ce at 352.5
314.5 and 289nm originate from transition between the 4f-ground state(7F)and the 5d-excited state(2D).The excitation spectrum of Tb
3+
ion in LaOBr:Ce
3+
Tb
3+
consists of four bands at 254
289
314.5 and 352.5nm due to Tb
3+
and Ce
3+
.It is clear that only the excitation bard at 254nm belong to Tb
3+
ions and the other three bards are the excitation bands of Ce
3+
ion.With increasing Ce
3+
concentration the intensity of Tb
3+
excitation band at 254nm decreases
at the same time the intensities of the Ce
3+
excitation bands at 289
314.5 and 352.5nm increase.
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