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中国科学院长春应用化学研究所
收稿:1982-04-08,
纸质出版:1982-11-30
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张思远. f<sup>N</sup>组态的电偶极跃迁[J]. 发光学报, 1982,(4): 11-17
Zhang Si-yuan. TRANSITION OF ELECTRIC DIPOLE OF f<sup>N</sup> CONFIGURATION[J]. Chinese Journal of Luminescence, 1982,(4): 11-17
张思远. f<sup>N</sup>组态的电偶极跃迁[J]. 发光学报, 1982,(4): 11-17 DOI:
Zhang Si-yuan. TRANSITION OF ELECTRIC DIPOLE OF f<sup>N</sup> CONFIGURATION[J]. Chinese Journal of Luminescence, 1982,(4): 11-17 DOI:
本文考虑了晶体的对称性和奇、偶次晶场项对f
N
组态电植极跃迁的影响.引进一个新的波函数
计算了晶体中稀土掺杂离子f
组态能级间电偶极跃迁的矩阵元表达式.讨论和解释了J
1
=0→J
2
=0的跃迁
并和Judd公式进行了比较讨论.
The crystal symmetry and the influnce of the crystal field terms (odd and even) to the transition of electric dipole of f
configuration
are considered. The new wave function is given. The element matrix expression of electric dipole transition between the energy levels of f
configuration is derived. By using the expression
we disscus and explain the J
=0 transition
and it is compared with Judd result.
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