ELECTRON PARAMAGNETIC RESONANCE OF Mn2+ IN (C5H5NH)2MnxZn1-xCl4 AND ((CH3)4N)2MnxZn1-xCl4
发光学报1982年3卷第2期 页码:16-21
作者机构:
中国科学院长春物理研究所
作者简介:
基金信息:
DOI:
中图分类号:
收稿:1982-02-19,
纸质出版:1982-05-30
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B. CANNY, D. CURIE, 刘洪楷, K. NIKOLIC, C. PORTE. (C<sub>5</sub>H<sub>5</sub>NH)<sub>2</sub>Mn<sub>x</sub>Zn<sub>1-x</sub>Cl<sub>4</sub>和((CH<sub>3</sub>)<sub>4</sub>N)<sub>2</sub>Mn<sub>x</sub>Zn<sub>1-x</sub>Cl<sub>4</sub>中Mn<sup>2+</sup>的电子顺磁共振[J]. 发光学报, 1982,3(2): 16-21
B. CANNY, D. CURIE, Liu Hong-Kai, K. NIKOLIC, C. PORTE. ELECTRON PARAMAGNETIC RESONANCE OF Mn<sup>2+</sup> IN (C<sub>5</sub>H<sub>5</sub>NH)<sub>2</sub>Mn<sub>x</sub>Zn<sub>1-x</sub>Cl<sub>4</sub> AND ((CH<sub>3</sub>)<sub>4</sub>N)<sub>2</sub>Mn<sub>x</sub>Zn<sub>1-x</sub>Cl<sub>4</sub>[J]. Chinese Journal of Luminescence, 1982,3(2): 16-21
B. CANNY, D. CURIE, 刘洪楷, K. NIKOLIC, C. PORTE. (C<sub>5</sub>H<sub>5</sub>NH)<sub>2</sub>Mn<sub>x</sub>Zn<sub>1-x</sub>Cl<sub>4</sub>和((CH<sub>3</sub>)<sub>4</sub>N)<sub>2</sub>Mn<sub>x</sub>Zn<sub>1-x</sub>Cl<sub>4</sub>中Mn<sup>2+</sup>的电子顺磁共振[J]. 发光学报, 1982,3(2): 16-21DOI:
B. CANNY, D. CURIE, Liu Hong-Kai, K. NIKOLIC, C. PORTE. ELECTRON PARAMAGNETIC RESONANCE OF Mn<sup>2+</sup> IN (C<sub>5</sub>H<sub>5</sub>NH)<sub>2</sub>Mn<sub>x</sub>Zn<sub>1-x</sub>Cl<sub>4</sub> AND ((CH<sub>3</sub>)<sub>4</sub>N)<sub>2</sub>Mn<sub>x</sub>Zn<sub>1-x</sub>Cl<sub>4</sub>[J]. Chinese Journal of Luminescence, 1982,3(2): 16-21DOI:
have been extensively studied. But their E. P. R. spectra show only very wide bands without any fine and hyperfine structure. By incorporating low concentrations of Mn
2+
(x=1%)in isomorphous(C
5
H
5
NH)
2
Mn
x
Zn
1-x
Cl
4
or ((CH
3
)
4
N)
2
Mn
x
Zn
1-x
Cl
4
we could derive from angular variations the whole set of parameters of the spin Hamiltonian. The tetrahedra are highly distorded