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武汉大学化学系
纸质出版:1981-11-30
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钟兴厚, 蒋昌武, 孙聚堂, 何喜庆, 杜秀珍, 鲁德初. 耐湿性荧光粉和X线增感屏[J]. 发光学报, 1981,2(4): 40-46
Zhong Xing-hou, Jiang Chang-wu, Sun Ju-tang, He Xi-qing, Du Xiu-zhen, Lu De-chu. MOISTURE-RESISTANT PHOSPHOR AND X-RAY INTENSIFYING SCREEN[J]. Chinese Journal of Luminescence, 1981,2(4): 40-46
稀土发光材料溴氧化镧掺铽是一种高效率X线发光材料.但其化学性质很不稳定
特别是在潮湿的空气中
易潮解而使发光效率显著降低
甚至完全丧失发光能力.因此
如何防止溴氧化镧的潮解成了这一优良新材料能否应用的关键问题.本文提出了一种制备耐湿性溴氧化镧荧光粉的新方法.用这种方法制成的LaOBr:Tb荧光粉在75℃水中浸泡105小时发光强度基本不变
这种荧光粉及其所制成的X线增感屏
在45℃饱和水蒸汽压恒温室内放置265天
发光强度和屏对x光胶片的感黑度也基本保持不变.而原来的LaOBr:Th荧光粉在70℃水中浸泡不到20分钟就发生水解变质
原来的LaOBr:Tb荧光粉及增感屏
在45℃饱和水蒸汽压恒温室中放置不到10天就发生了水解变质.
Terbium-activated lanthanum oxybromide phosphor is a highly efficient X-ray luminescent material
but its chemical property is very unstable
particularly in a moisture containing atmosphere.In this paper
a new method of preparing moisture-resistant terdium-activated lanthanum oxybromide Phosphor and X-ray intensifying screen is provided:Firstly
a small quantity of water-unsolvable substance
such as aluminium Phosphate
aluminium sili-cate
aluminium hydroxide
zinc Phosphate or zinc silicate etc
is deposited on the surface of phosphor particles.Secondly
the Phosphor particles with appropriate quantity of anhydrous magnesium sulfate are mixed by ball mill
so that the Phosphor particles surrounded by anhydrous magnesium sulfate powder. The method of Xrray intensifying screen is the same as that of calcium tungstate screen.The Phorsphor
after immersion in water at 75℃ for 105 hours
showed no decrease in the emission in tensity
whereas the Phosphor started to hydrolyze after 20 minutes.The phosphor and the X-ray intensifying screen after storage at 45℃ and 100% hymi-dity for 260 days
also showed no decrease in the emission intentity
but the untreated phosphor and screen started to show a marked decreese in the emission intensity after about 10 days.
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