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中国科学院长春物理研究所
纸质出版:1983-02-28
移动端阅览
钟国柱. ZnS:Cu,Nd,Cl薄膜电致发光出现受激发射的可能性[J]. 发光学报, 1983,4(1): 7-10
Zhong Guo-zhu. POSSIBILITY OF STIMULATED EMISSION IN DCEL OF ZnS:Cu,Nd,Cl THIN FILM[J]. Chinese Journal of Luminescence, 1983,4(1): 7-10
ZnS:Cu
Nd
Cl具有很好的直流电致发光
而且钕离子是一个稳定的发光中心
加之薄膜发光器件有两个平行电极
可以形成一个谐振腔.本文探讨了ZnS:Cu
Nd
Cl薄膜电致发光出现受激发射的可能性.在实验上发现
来自
4
F
3/2
到
4
I
9/2
和
4
I
11/2
能级之间的跃迁中某些谱线强度随外加电压的增加而非常迅速地增加
这很可能是能级之间出现粒子数反转
并在适当谐振条件下产生了受激发射.
ZnS:Cu
Nd
Cl thin films have been shown to give good DCEL with spectrum characteristic of trivalent neodymium ions. Nd
3+
ions form stable luminescence centers and can directly convert electrical energy into optical energy with efficiency of~10
-4
W/W.The thin films have two parallel electrodes consisting of a semi-transparent mirror formed by the conducting SnO
2
on the glass and a completely reflecting gold back electrode. These parallel electrodes form an ideal cavity for producing the oscillations of a given wavelength emission.More attentions are paied to the transitions from excited state
4
F
3/2
to ground state
4
I
9/2
with production of the emission at ~900nm and to state
4
I
11/2
with production of the emission at ~1080nm. In these two spectral groups
some sharp spectral lines increase more quickly with applied voltage than the common spectral lines. These results are attributed to a tendency of population inversion involving the excited state
4
F
3/2
and sub-levels of the ground states
4
I
9/2
and
4
I
11/2
and then to an occurrence of stimulated emission in the suitable harmonic oscillation cavity formed by two parallel electrodes.The experimental results reported here show the possibility of fabricating a thin film laser device in II-VI compounds doped with rare earth ions.
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