Three-primary-color Upconversion in Single Lanthanide Based Nanoparticle

SUN Jian-fei; YAN Dong; LIU Lu

doi:10.3788/fgxb20204101.0001

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Three-primary-color Upconversion in Single Lanthanide Based Nanoparticle

Synthesis and Properties of Materials | 更新时间：2020-08-12

- Three-primary-color Upconversion in Single Lanthanide Based Nanoparticle
- Chinese Journal of Luminescence Vol. 41, Issue 1, Pages: 1-8(2020)
- 作者机构：
  
  1. 黑龙江大学建筑工程学院, 黑龙江哈尔滨 150080
  2. 哈尔滨工程大学物理与光电工程学院, 黑龙江哈尔滨 150001
- 作者简介：
- 基金信息：
  
  Supported by 111 Project to Harbin Engineering University(B13015);Fundamental Rese
- DOI：10.3788/fgxb20204101.0001
  CLC： O433.4;O432.1+2
- Received：03 September 2019，
  
  Revised：12 October 2019，
  
  Published Online：15 October 2019，
  
  Published：05 January 2020
- 稿件说明：
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孙剑飞, 闫东, 刘禄. 单颗粒稀土纳米晶的三基色上转换发光[J]. 发光学报, 2020,41(1): 1-8

SUN Jian-fei, YAN Dong, LIU Lu. Three-primary-color Upconversion in Single Lanthanide Based Nanoparticle[J]. Chinese Journal of Luminescence, 2020,41(1): 1-8
孙剑飞, 闫东, 刘禄. 单颗粒稀土纳米晶的三基色上转换发光[J]. 发光学报, 2020,41(1): 1-8 DOI： 10.3788/fgxb20204101.0001.

SUN Jian-fei, YAN Dong, LIU Lu. Three-primary-color Upconversion in Single Lanthanide Based Nanoparticle[J]. Chinese Journal of Luminescence, 2020,41(1): 1-8 DOI： 10.3788/fgxb20204101.0001.

摘要

可调谐发光颜色的上转换荧光纳米粒子具有广阔的应用前景。本文设计并成功合成了结构紧凑的多层核-壳纳米颗粒。在不同波段激光的泵浦下，该颗粒中不同壳层分别产生红、绿、蓝3种颜色的上转换荧光。光谱测试结果表明，样品三基色发光的颜色纯度较好，并且可以实现全色域的颜色实时调节。此外，还测试了样品发光强度与泵浦功率之间的依赖关系，用于研究其中的上转换发光机理。这种在单颗粒水平上具有全色域可调发光的紧凑核-壳结构纳米晶体在多通道生物检测及成像、超高分辨率显示器件、高端防伪应用等领域显示出巨大的潜力。

Abstract

Upconversion nanocrystals capable of tunable emitting color have shown wide application prospects. In this paper

we designed and successfully synthesized compact multi-layer core-shell nanocrystals. Different layers in a nanocrystal respectively produce upconversion luminescence with red

green and blue color

excited by various lasers. The emitting color with high purity can be further tuned in real-time within full color range. In addition

the luminescence intensity dependences on the pump power were recorded and used to investigate the luminescence mechanisms. The proposed compact core-shell nanocrystal with tunable color in a single nanoparticle shows great potentials for the applications such as bio-detection and imaging

display devices with ultrahigh resolution and advanced anti-counterfeiting.

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references

KANO T,YAMAMOTO H,OTOMO Y. NaLnF4:Yb3+,Er3+ (Ln:Y,Gd,La):efficient green-emitting infrared-excited phosphors[J]. J. Electrochem. Soc., 1972,119(11):1561-1564.

李洋洋,李大光,张丹,等. 小尺寸NaLuF4:Yb3+/Tm3+纳米晶的生长及上转换发光[J]. 发光学报, 2018,39(6):764-770. LI Y Y,LI D G,ZHANG D,et al.. Growth process and upconversion luminescence of NaLuF4:Yb3+/Tm3+ nanocrystals[J]. Chin. J. Lumin., 2018,39(6):764-770. (in Chinese)

SOMMERDIJK J L. Influence of host lattice on the infrared-excited visible luminescence in Yb3+,Er3+-doped fluorides[J]. J. Lumin., 1973,8(2):126-130.

AUZEL F. Upconversion and anti-Stokes processes with f and d ions in solids[J]. Chem. Rev., 2004,104(1):139-174.

CHEN G Y,SEO J,YANG C H,et al.. Nanochemistry and nanomaterials for photovoltaics[J]. Chem. Soc. Rev., 2013,42(21):8304-8338.

贺飞,盖世丽,杨飘萍,等. 稀土上转换荧光材料的发光性质调变及其应用[J]. 发光学报, 2018,39(1):92-106. HE F,GAI S L,YANG P P,et al.. Luminescence modification and application of the lanthanide upconversion fluorescence materials[J]. Chin. J. Lumin., 2018,39(1):92-106. (in Chinese)

WANG F,LIU X G. Recent advances in the chemistry of lanthanide-doped upconversion nanocrystals[J]. Chem. Soc. Rev., 2009,38(4):976-989.

WU Y F,SUO H,HE D,et al.. Highly sensitive up-conversion optical thermometry based on Yb3+-Er3+ co-doped NaLa-(MoO4)2 green phosphors[J]. Mater. Res. Bull., 2018,106:14-18.

MA Y,XIANG G T,ZHANG J H,et al.. Upconversion properties and temperature sensing behaviors in visible and near-infrared region based on fluorescence intensity ratio in LuVO4:Yb3+/Er3+[J]. J. Alloys Compd., 2018,769:325-331.

XIANG G T,LIU X T,ZHANG J H,et al.. Dual-mode optical thermometry based on the fluorescence intensity ratio excited by a 915 nm wavelength in LuVO4:Yb3+/Er3+@SiO2 nanoparticles[J]. Inorg. Chem., 2019,58(12):8245-8252.

HAASE M,SCHFER H. Upconverting nanoparticles[J]. Angew. Chem. Int. Ed., 2011,50(26):5808-5829.

WANG L Y,YAN R X,HUO Z Y,et al.. Fluorescence resonant energy transfer biosensor based on upconversion-luminescent nanoparticles[J]. Angew. Chem. Int. Ed., 2005,44(37):6054-6057.

YI G S,LU H C,ZHAO S Y,et al.. Synthesis,characterization,and biological application of size-controlled nanocrystalline NaYF4:Yb,Er infrared-to-visible up-conversion phosphors[J]. Nano Lett., 2004,4(11):2191-2196.

WANG L Y,LI Y D. Green upconversion nanocrystals for DNA detection[J]. Chem. Commun., 2006(24):2557-2559.

HEER S,KMPE K,GDEL H U,et al.. Highly efficient multicolour upconversion emission in transparent colloids of lanthanide-doped NaYF4 nanocrystals[J]. Adv. Mater., 2004,16(23-24):2102-2105.

VAN DERIJKE F,ZIJLMANS H,LI S,et al.. Up-converting phosphor reporters for nucleic acid microarrays[J]. Nat. Biotechnol., 2001,19(3):273-276.

SUO H,ZHAO X Q,ZHANG Z Y,et al.. Upconverting LuVO4:Nd3+/Yb3+/Er3+@SiO2@Cu2S hollow nanoplatforms for self-monitored photothermal ablation[J]. ACS Appl. Mater. Interfaces, 2018,10(46):39912-39920.

ZHAO J B,LU Z D,YIN Y D,et al.. Upconversion luminescence with tunable lifetime in NaYF4:Yb,Er nanocrystals:role of nanocrystal size[J]. Nanoscale, 2013,5(3):944-952.

NA H,WOO K,LIM K,et al.. Rational morphology control of -NaYF4:Yb,Er/Tm upconversion nanophosphors using a ligand,an additive,and lanthanide doping[J]. Nanoscale, 2013,5(10):4242-4251.

NIU N,HE F,GAI S L,et al.. Rapid microwave reflux process for the synthesis of pure hexagonal NaYF4:Yb3+,Ln3+,Bi3+ (Ln3+=Er3+,Tm3+,Ho3+) and its enhanced UC luminescence[J]. J. Mater. Chem., 2012,22(40):21613-21623.

MAI H X,ZHANG Y W,SI R,et al.. High-quality sodium rare-earth fluoride nanocrystals:controlled synthesis and optical properties[J]. J. Am. Chem. Soc., 2006,128(19):6426-6436.

王睿,张凡. 镧系元素掺杂的高效率上转换纳米粒子的合成[J]. 发光学报, 2018,39(1):50-68. WANG R,ZHANG F. Synthesis of highly efficient lanthanide upconversion nanoparticles[J]. Chin. J. Lumin., 2018,39(1):50-68. (in Chinese)

SIVAKUMAR S,VAN VEGGEL F C J M,RAUDSEPP M. Bright white light through up-conversion of a single NIR source from sol-gel-derived thin film made with Ln3+-doped LaF3 nanoparticles[J]. J. Am. Chem. Soc., 2005,127(36):12464-12465.

WANG F,HAN Y,LIM C S,et al.. Simultaneous phase and size control of upconversion nanocrystals through lanthanide doping[J]. Nature, 2010,463(7284):1061-1065.

WANG F,LIU X G. Upconversion multicolor fine-tuning:visible to near-infrared emission from lanthanide-doped NaYF4 nanoparticles[J]. J. Am. Chem. Soc., 2008,130(17):5642-5643.

EHLERT O,THOMANN R,DARBANDI M,et al.. A four-color colloidal multiplexing nanoparticle system[J]. ACS Nano, 2008,2(1):120-124.

DENG R R,QIN F,CHEN R F,et al.. Temporal full-colour tuning through non-steady-state upconversion[J]. Nat. Nanotechnol., 2015,10(3):237-242.

LIU J,CHENG Y X,XIE Z Y,et al.. White electroluminescence from a star-like polymer with an orange emissive core and four blue emissive arms[J]. Adv. Mater., 2008, 20(7):1357-1362.

YANG Y J,LOWRY M,SCHOWALTER C M,et al.. An organic white light-emitting fluorophore[J]. J. Am. Chem. Soc., 2006,128(43):14081-14092.

LIU L,LU K L,XU L,et al.. Highly efficient upconversion luminescence of Er heavily doped nanocrystals through 1530 nm excitation[J]. Opt. Lett., 2019,44(3):711-714.

翟雪松,刘世虎,范柳燕,等. 强上转换发光的LiLu1-xYbxF4:Tm@LiGdF4核壳纳米晶的制备[J]. 发光学报, 2017,38(9):1149-1154. ZHAI X S,LIU S H,FAN L Y,et al.. Preparation of LiLu1-xYbxF4:Tm@LiGdF4 core-shell nanocrystals with enhanced upconversion luminescence[J]. Chin. J. Lumin., 2017,38(9):1149-1154. (in Chinese)

LIU L,LU K L,YAN D,et al.. Concentration dependent optical transition probabilities in ultra-small upconversion nanocrystals[J]. Opt. Express, 2018,26(18):23471-23479.

ZUO J,LI Q Q,XUE B,et al.. Employing shells to eliminate concentration quenching in photonic upconversion nanostructure[J]. Nanoscale, 2017,9(23):7941-7946.

XIE X J,GAO N Y,DENG R R,et al.. Mechanistic investigation of photon upconversion in Nd3+-sensitized core-shell nanoparticles[J]. J. Am. Chem. Soc., 2013,135(34):12608-12611.

ZHONG Y T,TIAN G,GU Z J,et al.. Elimination of photon quenching by a transition layer to fabricate a quenching-shield sandwich structure for 800 nm excited upconversion luminescence of Nd3+-sensitized nanoparticles[J]. Adv. Mater., 2014,26(18):2831-2837.

WANG K,QINCHENG W L,ZHANG Y,et al.. Synthesis of Nd3+/Yb3+ sensitized upconversion core-shell nanocrystals with optimized hosts and doping concentrations[J]. RSC Adv., 2015,5(77):62899-62904.

LIU D M,XU X X,DU Y,et al.. Three-dimensional controlled growth of monodisperse sub-50 nm heterogeneous nanocrystals[J]. Nat. Commun., 2016,7(1):10254.

VETRONE F,BOYER J C,CAPOBIANCO J A,et al.. Significance of Yb3+ concentration on the upconversion mechanisms in codoped Y2O3:Er3+,Yb3+ nanocrystals[J]. J. Appl. Phys., 2004,96(1):661-667.

POLLNAU M,GAMELIN D R,LTHI S R,et al.. Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems[J]. Phys. Rev. B, 2000,61(5):3337-3346.

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