Preparation and Luminescence Properties of Near Infrared Luminescent Material Mg2SnO4: Cr3+

CAI Ji-ze; PANG Ran; YU Zhan; LIU Li-yan; LI Cheng-yu

doi:10.3788/fgxb20194012.1505

您当前的位置：

首页 >

文章列表页 >

Preparation and Luminescence Properties of Near Infrared Luminescent Material Mg₂SnO₄: Cr³⁺

Synthesis and Properties of Materials | 更新时间：2020-08-12

- Preparation and Luminescence Properties of Near Infrared Luminescent Material Mg₂SnO₄: Cr³⁺
- Chinese Journal of Luminescence Vol. 40, Issue 12, Pages: 1505-1513(2019)
- 作者机构：
  
  1. 沈阳师范大学化学化工学院, 辽宁沈阳 110034
  2. 中国科学院长春应用化学研究所稀土资源利用国家重点实验室, 吉林长春 130022
- 作者简介：
- 基金信息：
  
  Supported by National Key Research and Development Plan(2016YFB07010003);Scientifi
- DOI：10.3788/fgxb20194012.1505
  CLC： O482.31;O614.61
- Received：03 July 2019，
  
  Revised：31 July 2019，
  
  Published Online：05 December 2019，
  
  Published：05 December 2019
- 稿件说明：
移动端阅览
蔡吉泽, 庞然, 于湛等. 近红外发光材料Mg2SnO4:Cr3+的制备及发光性质[J]. 发光学报, 2019,40(12): 1505-1513

CAI Ji-ze, PANG Ran, YU Zhan etc. Preparation and Luminescence Properties of Near Infrared Luminescent Material Mg2SnO4: Cr3+[J]. Chinese Journal of Luminescence, 2019,40(12): 1505-1513
蔡吉泽, 庞然, 于湛等. 近红外发光材料Mg2SnO4:Cr3+的制备及发光性质[J]. 发光学报, 2019,40(12): 1505-1513 DOI： 10.3788/fgxb20194012.1505.

CAI Ji-ze, PANG Ran, YU Zhan etc. Preparation and Luminescence Properties of Near Infrared Luminescent Material Mg2SnO4: Cr3+[J]. Chinese Journal of Luminescence, 2019,40(12): 1505-1513 DOI： 10.3788/fgxb20194012.1505.

摘要

采用高温固相法合成了一种新型近红外发光材料Mg

SnO

。利用X射线粉末衍射仪对样品的结构进行了表征，证明所得到的荧光粉具有单一尖晶石结构，掺杂离子的加入并没有改变晶体结构。利用荧光光谱和荧光衰减光谱对荧光粉的发光性质进行了研究。当被470 nm的蓝光激发时，荧光粉在700 nm处出现一个尖锐的发射峰（R锐线）和中心发射在750 nm处的宽带发射峰，分别归属于Cr

的

和

（

F）

跃迁。研究不同浓度Cr

掺杂对样品发光性质的影响，发现样品的发光强度随着Cr

浓度的增加而增大。当Cr

掺杂浓度

=0.02时达到最大值，之后出现发光强度的猝灭，猝灭机理为多极相互作用。样品的荧光寿命随着Cr

掺杂浓度的增大逐渐减小，从而证明Cr

之间存在着能量传递现象。Mg

SnO

系列荧光粉还表现出了近红外长余辉发光性质。

Abstract

A novel near-infrared luminescent material Mg

SnO

was synthesized by high temperature solid phase method. The structure of the sample was characterized using X-ray powder diffractometer. It was proved that the obtained phosphor had a single spinel structure

and the addition of doping ions did not significantly change the crystal structure. The luminescent properties of the samples were investigated using fluorescence spectroscopy and fluorescence decay spectroscopy. When excited at 470 nm

the phosphor exhibits a sharp emission at 700 nm and a strong broad band emission centered at 750 nm

which belong to the

and

(

transitions of Cr

respectively. The effects of Cr

doping concentrations on the luminescence properties of the samples were investigated. It was found that the luminescence intensity of the samples increased with the increase of Cr

concentration and reached its maximum at

=0.02. Then luminescence intensity quenching occurred and the quenching mechanism is the electric dipole-electric dipole interaction. The fluorescence lifetime of the sample decreases with the increase of Cr

doping concentration

which proves that there is energy transfer between Cr

ions. The Mg

SnO

phosphors also exhibit near-infrared long-lasting luminescence properties.

关键词

Keywords

references

IGNE B,ZACOUR B M,SHI Z Q,et al.. Online monitoring of pharmaceutical materials using multiple NIR sensors-part I:blend homogeneity[J]. J. Pharm. Innov., 2011,6(1):47-59.

VATS M,MISHRA S K,BAGHINI M S,et al.. Near infrared fluorescence imaging in nano-therapeutics and photo-thermal evaluation[J]. Int. J. Mol. Sci., 2017,18(5):924-1-19.

YANG Y M,AW J,XING B G. Nanostructures for NIR light-controlled therapies[J]. Nanoscale, 2017,9(11):3698-3718.

BNZLI JC G,ELISEEVA S V. Lanthanide NIR luminescence for telecommunications,bioanalyses and solar energy conversion[J]. J. Rare Earths, 2010,28(6):824-842.

BARBIERI A,BANDINI E,MONTI F,et al.. The rise of near-infrared emitters:organic dyes,porphyrinoids,and transition metal complexes[J]. Top. Curr. Chem., 2016,374(4):47.

YU D C,YE S,PENG M Y,et al.. Efficient near-infrared downconversion in GdVO4:Dy3+ phosphors for enhancing the photo-response of solar cells[J]. Solar Energy Mater. Solar Cells, 2011,95(7):1590-1593.

张继森,张立国,任建岳,等. YAG中Cr3+和Yb3+的发光特征以及Cr3+和Yb3+之间的能量传递过程[J]. 发光学报, 2015,36(3):262-266. ZHANG J S,ZHANG L G,REN J Y,et al.. Properties of NIR emissions with energy-transfer processes in Cr3+-and Yb3+-doped Y3Al5O12 powder materials[J]. Chin. J. Lumin., 2015,36(3):262-266. (in Chinese)

BESSIRE A,SHARMA S K,BASAVARAJU N,et al.. Storage of visible light for long-lasting phosphorescence in chromium-doped zinc gallate[J]. Chem. Mater., 2014,26(3):1365-1373.

ABDUKAYUM A,CHEN J T,ZHAO Q,et al.. Functional near infrared-emitting Cr3+/Pr3+ Co-doped zinc gallogermanate persistent luminescent nanoparticles with superlong afterglow for in vivo targeted bioimaging[J]. J. Am. Chem. Soc., 2013,135(38):14125-14133.

YAN W Z,LIU F,LU Y Y,et al.. Near infrared long-persistent phosphorescence in La3Ga5GeO14:Cr3+ phosphor[J]. Opt. Express, 2010,18(19):20215-20221.

LU Y Y,LIU F,GU Z J,et al.. Long-lasting near-infrared persistent luminescence from -Ga2O3:Cr3+ nanowire assemblies[J]. J. Lumin., 2011,131(12):2784-2787.

PAN Z,LU Y Y,LIU F. Sunlight-activated long-persistent luminescence in the near-infrared from Cr3+-doped zinc gallogermanates[J]. Nat. Mater., 2011,11(1):58-63.

CHEN D Q. Near-infrared long-lasting phosphorescence in transparent glass ceramics embedding Cr3+-doped LiGa5O8 nanocrystals[J]. J. Eur. Ceram. Soc., 2014,34(15):4069-4075.

CHEN D Q,CHEN Y,LU H W,et al.. A bifunctional Cr/Yb/Tm:Ca3Ga2Ge3O12 phosphor with near-infrared long-lasting phosphorescence and upconversion luminescence[J]. Inorg. Chem., 2014,53(16):8638-8645.

JIN Y H,HU Y H,YUAN L F,et al.. Multifunctional near-infrared emitting Cr3+-doped Mg4Ga8Ge2O20 particles with long persistent and photostimulated persistent luminescence,and photochromic properties[J]. J. Mater. Chem. C, 2016,4(27):6614-6625.

LIN H H,YU T,BAI G X,et al.. Enhanced energy transfer in Nd3+/Cr3+ co-doped Ca3Ga2Ge3O12 phosphors with near-infrared and long-lasting luminescence properties[J]. J. Mater. Chem. C, 2016,4(16):3396-3402.

XUE F H,HU Y H,FAN L M,et al.. Cr3+-activated Li5Zn8Al5Ge9O36:a near-infrared long-afterglow phosphor[J]. J. Am. Ceram. Soc., 2017,100(7):3070-3079.

LI Y,LI Y Y,CHEN R C,et al.. Tailoring of the trap distribution and crystal field in Cr3+-doped non-gallate phosphors with near-infrared long-persistence phosphorescence[J]. NPG Asia Mater., 2015,7:e180-1-11.

SHANNON R D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides[J]. Acta Cryst. Sect. A, 1976,32(5):751-767.

LI H F,ZHAO R,JIA Y L,et al.. Sr1.7Zn0.3CeO4:Eu3+novel red-emitting phosphors:synthesis and photoluminescence properties[J]. ACS Appl. Mater. Interfaces, 2014,6(5):3163-3169.

ZHANG L L,WANG D D,HAO Z D,et al.. Cr3+-doped broadband NIR garnet phosphor with enhanced luminescence and its application in NIR spectroscopy[J]. Adv. Opt. Mater., 2019,7(12):1900185.

ZHUANG Y X,UEDA J,TANABE S,et al.. Band-gap variation and a self-redox effect induced by compositional deviation in ZnxGa2O3+x:Cr3+ persistent phosphors[J]. J. Mater. Chem. C, 2014,2(28):5502-5509.

于潘龙,田莲花. Mn2+离子掺杂的NaTaOGeO4:Tb3+的发光性能[J]. 发光学报, 2018,39(9):1200-1206. YU P L,TIAN L H. Photoluminescence properties and color tunable of NaTaOGeO4:Tb3+co-doped with Mn2+ion[J]. Chin. J. Lumin., 2018,39(9):1200-1206. (in Chinese)

BLASSE G. Energy transfer in oxidic phosphors[J]. Phys. Lett. A, 1968,28(6):444-445.

肖玲,周建,刘桂珍. Li+掺杂Sr2MgSi2O7:Eu2+,Dy3+长余辉材料的发光性能[J]. 发光学报, 2017,38(9):1143-1148. XIAO L,ZHOU J,LIU G Z. Luminescent properties of Li+ doped Sr2MgSi2O7:Eu2+,Dy3+phosphors[J]. Chin. J. Lumin., 2017,38(9):1143-1148. (in Chinese)

过诚,丛妍,董斌,等. (Zn(1-x),Mgx)2GeO4:Mn2+的荧光以及长余辉发光性能[J]. 发光学报, 2017,38(9):1161-1166. GUO C,CONG Y,DONG B,et al.. Photoluminescence and long-lasting phosphorescence characteristics of (Zn1-x,Mgx)2GeO4:Mn2+[J]. Chin. J. Lumin., 2017,38(9):1161-1166. (in Chinese)

LV W Z,JIAO M M,ZHAO Q,et al.. Ba1.3Ca0.7SiO4:Eu2+,Mn2+:a promising single-phase,color-tunable phosphor for near-ultraviolet white-light-emitting diodes[J]. Inorg. Chem., 2014,53(20):11007-11014.

SOHN K S,CHOI Y Y,PARK H D. Photoluminescence behavior of Tb3+-activated YBO3 phosphors[J]. J. Electrochem. Soc., 2000,147(5):1988-1992.

HUANG C H,KUO T W,CHEN T M. Novel red-emitting phosphor Ca9Y(PO4)7:Ce3+,Mn2+ with energy transfer for fluorescent lamp application[J]. ACS Appl. Mater. Interfaces, 2010,2(5):1395-1399.

LI K,LIAN H Z,SHANG M M,et al.. A novel greenish yellow-orange red Ba3Y4O9:Bi3+,Eu3+ phosphor with efficient energy transfer for UV-LEDs[J]. Dalton Trans., 2015,44(47):20542-20550.

LI J Y,PANG R,SUN W Z,et al.. A new blue long-lasting phosphorescence phosphor Mg2SnO4:Bi3+:synthesis and luminescence properties[J]. J. Mater. Sci.:Mater. Electron., 2018,29(5):4163-4170.

Views

273

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Preparation and Luminescence Properties of Yellow Phosphors Ba₃Y₄O₉: Dy³⁺ Excited by Near UV Light

Efficient and Long Lifetime Blue Light Material Based on Anthracene[2,3-b]benzofuran Framework

Synthesis, Luminescence Mechanism and Applications of Carbon Dots with Afterglow

Sensing Properties of Chitosan Derivatives-based Polymer Carbon Dots to Pd²⁺

Effects of Eu³⁺-doped Concentration and Matricial Oxygen Vacancies on The Luminescence Properties of Ca_2-xEu_xSnO₄

Related Author

LI Cheng-yu

LIU Li-yan

YU Zhan

PANG Ran

LI Jia-yu

LI Jiangnan

YANG Dandan

LIU Kaipeng

Related Institution

School of Chemistry and Chemical Engineering, Shenyang Normal University

Xi'an Manareco New Materials Co.， Ltd.

School of Chemistry and Chemical Engineering, Anhui University

Guangxi Key Laboratory of Natural Polymer Chemistry and Physics, College of Chemistry and Materials, Nanning Normal University

Key Laboratory of Functional Composite Materials of Guizhou Province, Department of Electronic Science, College of Big Data and Information Engineering, Guizhou University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰