Hydrothermal Systheis and Upconversion Emission Properties of GdInO3: Yb3+/Ho3+ Phosphors

LIAO Jin-sheng; KONG Li-yun; WANG Ming-hua; PENG Guang-huai

doi:10.3788/fgxb20194012.1486

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Hydrothermal Systheis and Upconversion Emission Properties of GdInO₃: Yb³⁺/Ho³⁺ Phosphors

Synthesis and Properties of Materials | 更新时间：2020-08-12

- Hydrothermal Systheis and Upconversion Emission Properties of GdInO₃: Yb³⁺/Ho³⁺ Phosphors
- Chinese Journal of Luminescence Vol. 40, Issue 12, Pages: 1486-1493(2019)
- 作者机构：
  
  江西理工大学化学化工学院,江西赣州,341000
- 作者简介：
- 基金信息：
  
  Spported by National Natural Science Foundation of China(51862012);Major Project o
- DOI：10.3788/fgxb20194012.1486
  CLC： O484.4
- Received：03 July 2019，
  
  Revised：05 September 2019，
  
  Published Online：05 December 2019，
  
  Published：05 December 2019
- 稿件说明：
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廖金生, 孔莉芸, 王明华等. 水热法合成GdInO3:Yb3+/Ho3+荧光粉及其上转换发光性能[J]. 发光学报, 2019,40(12): 1486-1493

LIAO Jin-sheng, KONG Li-yun, WANG Ming-hua etc. Hydrothermal Systheis and Upconversion Emission Properties of GdInO3: Yb3+/Ho3+ Phosphors[J]. Chinese Journal of Luminescence, 2019,40(12): 1486-1493
廖金生, 孔莉芸, 王明华等. 水热法合成GdInO3:Yb3+/Ho3+荧光粉及其上转换发光性能[J]. 发光学报, 2019,40(12): 1486-1493 DOI： 10.3788/fgxb20194012.1486.

LIAO Jin-sheng, KONG Li-yun, WANG Ming-hua etc. Hydrothermal Systheis and Upconversion Emission Properties of GdInO3: Yb3+/Ho3+ Phosphors[J]. Chinese Journal of Luminescence, 2019,40(12): 1486-1493 DOI： 10.3788/fgxb20194012.1486.

摘要

采用水热过程与进一步热处理的方法合成了六方相GdInO

:Yb

/Ho

荧光粉。采用X射线粉末衍射（PXRD）对晶体结构和相纯度进行了检测，结构精修结果表明，获得的样品为纯的六方相GdInO

:Yb

/Ho

荧光粉。用扫描电镜（SEM）和透射电镜（TEM）对合成材料的形貌进行了表征。在980 nm激光激发下，观察到Ho

离子的539 nm绿光发射（

）和665 nm红光发射（

）。此外，还发现通过改变Ho

浓度得到了从绿光到黄光的可调发光特性。可调发光是由交叉弛豫（

）过程引起的。GdInO

:Yb

/Ho

是一种很好的上转换材料，可用于照明和显示领域。

Abstract

and Ho

codoped hexagonal GdInO

phosphor has been synthesized by hydrothermal process and further heat treatment. The crystal structure and phase purity were checked by means of powder X-ray diffraction (PXRD)

and the refinement results showed that pure phase GdInO

:Yb

/Ho

phosphors were obtained. The morphology of the synthesized materials was characterized by SEM and TEM. The upconversion (UC) luminescence properties of the phosphor were investigated. Green emission at 539 nm (

) and red emission at 665 nm (

) of Ho

were observed upon 980 nm laser excitation. Moreover

it has been found that tuneable emission characteristics from green to yellow were obtained

via

the Ho

concentration modulation. The tunable emission is due to the cross-relaxation process (

). The GdInO

:Yb

/Ho

can be a good candidate for upconversion material in lighting and display fields.

关键词

Keywords

references

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