Upconversion Luminescence and Optical Temperature Sensing Properties for Lu2O3(Y2O3): Yb3+/Er3+/Gd3+ Phosphors

ZHANG Yu-hong; LIU Dan; WANG Ting-ting; JIA Hui; LIU Hang; FU Zuo-ling

doi:10.3788/fgxb20194012.1478

您当前的位置：

首页 >

文章列表页 >

Upconversion Luminescence and Optical Temperature Sensing Properties for Lu₂O₃(Y₂O₃): Yb³⁺/Er³⁺/Gd³⁺ Phosphors

Synthesis and Properties of Materials | 更新时间：2020-08-12

- Upconversion Luminescence and Optical Temperature Sensing Properties for Lu₂O₃(Y₂O₃): Yb³⁺/Er³⁺/Gd³⁺ Phosphors
- Chinese Journal of Luminescence Vol. 40, Issue 12, Pages: 1478-1485(2019)
- 作者机构：
  
  1. 吉林建筑大学电气与计算机学院,吉林长春,130118
  2. 吉林大学物理学院,吉林长春,130021
- 作者简介：
- 基金信息：
  
  Supported by National Natural Science Foundation of China(61705077);Science Founda
- DOI：10.3788/fgxb20194012.1478
  CLC： O482.31
- Received：09 July 2019，
  
  Revised：12 August 2019，
  
  Published Online：05 September 2019，
  
  Published：05 December 2019
- 稿件说明：
移动端阅览
张玉红, 刘丹, 王婷婷等. Yb3+/Er3+/Gd3+掺杂Lu2O3、Y2O3荧光粉的上转换发光及温度特性[J]. 发光学报, 2019,40(12): 1478-1485

ZHANG Yu-hong, LIU Dan, WANG Ting-ting etc. Upconversion Luminescence and Optical Temperature Sensing Properties for Lu2O3(Y2O3): Yb3+/Er3+/Gd3+ Phosphors[J]. Chinese Journal of Luminescence, 2019,40(12): 1478-1485
张玉红, 刘丹, 王婷婷等. Yb3+/Er3+/Gd3+掺杂Lu2O3、Y2O3荧光粉的上转换发光及温度特性[J]. 发光学报, 2019,40(12): 1478-1485 DOI： 10.3788/fgxb20194012.1478.

ZHANG Yu-hong, LIU Dan, WANG Ting-ting etc. Upconversion Luminescence and Optical Temperature Sensing Properties for Lu2O3(Y2O3): Yb3+/Er3+/Gd3+ Phosphors[J]. Chinese Journal of Luminescence, 2019,40(12): 1478-1485 DOI： 10.3788/fgxb20194012.1478.

摘要

通过溶胶-凝胶法制备了Er

、Yb

和Gd

共掺杂的Y

、Lu

荧光粉，并研究了其上转换发光和温度敏感特性。在980 nm激光激发下，样品辐射出明亮的绿光、红光和弱的紫外光。并讨论了紫外区Er

的能量传递。利用荧光强度比方法研究了基于Er

的

11/2

和

3/2

两个热耦合能级在313~573 K范围内的光学温度传感特性，当Gd

离子掺杂浓度为10%时，样品的灵敏度最大为0.005 91 K

-1

。

Abstract

):Yb

/Er

/Gd

phosphors were synthesized using a sol-gel method.Upconversion(UC) luminescence and temperature-sensing properties were investigated. Under 980 nm excitation

bright green

red

and weak ultraviolet emissions were observed. The optimal Gd

doping concentrations in Lu

) was 10%. The energy transfer processes from Er

to Gd

ions has been investigated and discussed. By utilizing the fluorescence intensity ratio (FIR) technique

the temperature sensing behaviors of the optimal sample are investigated based on the thermally coupled levels of

11/2

and

of Er

ions from 313 K to 573 K. The maximal sensitivity was gained to be 0.005 91 K

-1

for Y

:1%Er

/1%Yb

/10%Gd

关键词

Keywords

references

PRASAD P N. Nanophotonics[M]. Hoboken,N.J.:Wiley, 2004.

WANG Y H,SHEN P,LI C Y,et al.. Upconversion fluorescence resonance energy transfer based biosensor for ultrasensitive detection of matrix metalloproteinase-2 in blood[J]. Anal. Chem., 2012,84(3):1466-1473.

LI Z Q,LI X D,LIU Q Q,et al.. Core/shell structured NaYF4:Yb3+/Er3+/Gd+3 nanorods with Au nanoparticles or shells for flexible amorphous silicon solar cells[J]. Nanotechnology, 2012,23(2):025402.

LIU J A,BU W B,ZHANG S J,et al.. Controlled synthesis of uniform and monodisperse upconversion core/mesoporous silica shell nanocomposites for bimodal imaging[J]. Chem.-A Eur. J., 2012,18(8):2335-2341.

DAI Y L,MA P A,CHENG Z Y,et al.. Up-conversion cell imaging and pH-induced thermally controlled drug release from NaYF4:Yb3+/Er3+@hydrogel core-shell hybrid microspheres[J]. ACS Nano, 2012,6(4):3327-3338.

WANG C,CHENG L,LIU Z. Upconversion nanoparticles for photodynamic therapy and other cancer therapeutics[J]. Theranostics, 2013,3(5):317-330.

CHEN G Y,OHULCHANSKYY T Y,KUMAR R,et al.. Ultrasmall monodisperse NaYF4:Yb3+/Tm3+ nanocrystals with enhanced near-infrared to near-infrared upconversion photoluminescence[J]. ACS Nano, 2010,4(6):3163-3168.

CHEN G Y,LIU H C,LIANG H J,et al.. Upconversion emission enhancement in Yb3+/Er3+-codoped Y2O3 nanocrystals by tridoping with Li+ ions[J]. J. Phys. Chem. C, 2008,112(31):12030-12036.

SCHIETINGER S,AICHELE T,WANG H Q,et al.. Plasmon-enhanced upconversion in single NaYF4:Yb3+/Er3+ codoped nanocrystals[J]. Nano Lett., 2010,10(1):134-138.

HAN P D,JIANG X P,CHENG S,et al.. Upconversion luminescent materials of Y-Gd oxysulfide binary system codoped with Yb and Er[J]. J. Mater. Sci.:Mater. Electron., 2015,26(9):6599-6605.

URBINA-FRAS A,LPEZ-LUKE T,OLIVA J,et al.. Strong enhancement of the upconversion emission in ZrO2:Yb3+,Er3+,Gd3+ nanocubes synthesized with Na2S[J]. J. Lumin., 2016,172:154-160.

FU J P,PANG R,JIA Y L,et al.. Intense red-green up-conversion emission and their mechanisms of SrO:Er3+/Yb3+,Gd3+,Lu3+,Bi3+[J]. J. Lumin., 2017,181:240-245.

SINGH S K,KUMAR K,RAI S B. Er3+/Yb3+ codoped Gd2O3 nano-phosphor for optical thermometry[J]. Sens. Actuators A, 2009,149(1):16-20.

XU W,CUI Y,HU Y W,et al.. Optical temperature sensing in Er3+-Yb3+ codoped CaWO4 and the laser induced heating effect on the luminescence intensity saturation[J]. J. Alloys Compd., 2017,726:547-555.

RAMASAMY P,CHANDRA P,RHEE S W,et al.. Enhanced upconversion luminescence in NaGdF4:Yb,Er nanocrystals by Fe3+ doping and their application in bioimaging[J]. Nanoscale, 2013,5(18):8711-8717.

TIAN B N,CHEN B J,TIAN Y,et al.. Excitation pathway and temperature dependent luminescence in color tunable Ba5Gd8Zn4O21:Eu3+ phosphors[J]. J. Mater. Chem. C, 2013,1(12):2338-2344.

ZHENG H,CHEN B J,YU H Q,et al.. Influence of microwave hydrothermal reaction factor on the morphology of NaY(MoO4)2 nano-/micro-structures and luminescence properties of NaY(MoO4)2:Tb3+[J]. RSC Adv., 2015,5(69):56337-56347.

SUO H,GUO C F,ZHENG J M,et al.. Sensitivity modulation of upconverting thermometry through engineering phonon energy of a matrix[J]. ACS Appl. Mater. Interfaces, 2016,8(44):30312-30319.

SUO H,ZHAO X Q,ZHANG Z Y,et al.. Local symmetric distortion boosted photon up-conversion and thermometric sensitivity in lanthanum oxide nanospheres[J]. Nanoscale, 2018,10(19):9245-9251.

HAO Y X,LV S C,MA Z J,et al.. Understanding differences in Er3+-Yb3+ codoped glass and glass ceramic based on upconversion luminescence for optical thermometry[J]. RSC Adv., 2018,8(22):12165-12172.

WANG S S,ZHOU H,WANG X X,et al.. Up-conversion luminescence and optical temperature-sensing properties of Er3+-doped perovskite Na0.5Bi0.5TiO3 nanocrystals[J]. J. Phys. Chem. Solids, 2016,98:28-31.

ZHANG X T,FU Z L,SUN Z,et al.. Temperature-induced phase transition and temperature sensing behavior in Yb3+ sensitized Er3+ doped YPO4 phosphors[J]. Opt. Mater., 2016,60:526-532.

LIU G F,FU L L,GAO Z Y,et al.. Investigation into the temperature sensing behavior of Yb3+ sensitized Er3+ doped Y2O3,YAG and LaAlO3 phosphors[J]. RSC Adv., 2015,5(64):51820-51827.

XU W,ZHANG Z G,CAO W W. Excellent optical thermometry based on short-wavelength upconversion emissions in Er3+/Yb3+ codoped CaWO4[J]. Opt. Lett., 2012,37(23):4865-4867.

Views

195

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Upconversion Optical Temperature Sensing of YbNbO₄∶Ho³⁺ with Host Sensitization

Dual-mode Optical Thermometry with High Sensitivity Achieved in Na₃Y(VO₄)₂∶Yb³⁺/Er³⁺

Luminescent Properties and Temperature Sensing of Ca₂MgTeO₆∶Bi³⁺, Mn⁴⁺ Phosphors

Preparation and Temperature Sensing Properties of Bi³⁺, Eu³⁺ Co-doped Double Perovskite Gd₂ZnTiO₆ Phosphor

Down-conversion Luminescence and Temperature Sensing Characters of KBaGd（MoO₄）₃∶Er³⁺ Under NUV Excitation

Related Author

CHI Ziheng

HE Shuai

DING Shoujun

ZHANG Chuancheng

SU Wenzhi

WANG Miaomiao

XIANG Guotao

YI Yuanyuan

Related Institution

School of Microelectronics and Data Science， Anhui University of Technology， Ma’anshan

College of Science， Inner Mongolia University of Science & Technology

Department of Mathematics and Physics， Chongqing University of Posts and Telecommunications

College of Physics， Taiyuan University of Technology

Institute of Optoelectronic Materials and Devices， China University of Metrology

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰