Upconversion Luminescence of Mn2+ in Yb3+-Mn2+ Codoped CaF2 Materials

ZHENG Ke-zhi; QIN Wei-ping

doi:10.3788/fgxb20194011.1321

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Upconversion Luminescence of Mn²⁺ in Yb³⁺-Mn²⁺ Codoped CaF₂ Materials

Synthesis and Properties of Materials | 更新时间：2020-08-12

- Upconversion Luminescence of Mn²⁺ in Yb³⁺-Mn²⁺ Codoped CaF₂ Materials
- Chinese Journal of Luminescence Vol. 40, Issue 11, Pages: 1321-1326(2019)
- 作者机构：
  
  吉林大学电子科学与工程学院集成光电子学国家重点实验室,吉林长春,130012
- 作者简介：
- 基金信息：
  
  Supported by National Natural Science Foundation of China(11774133,11774132,11474132)
- DOI：10.3788/fgxb20194011.1321
  CLC： O482.31
- Received：29 July 2019，
  
  Revised：25 August 2019，
  
  Published Online：09 September 2019，
  
  Published：05 November 2019
- 稿件说明：
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郑克志, 秦伟平,. CaF2:Yb3+/Mn2+体系中Mn2+的上转换发光[J]. 发光学报, 2019,40(11): 1321-1326

ZHENG Ke-zhi, QIN Wei-ping,. Upconversion Luminescence of Mn2+ in Yb3+-Mn2+ Codoped CaF2 Materials[J]. Chinese Journal of Luminescence, 2019,40(11): 1321-1326
郑克志, 秦伟平,. CaF2:Yb3+/Mn2+体系中Mn2+的上转换发光[J]. 发光学报, 2019,40(11): 1321-1326 DOI： 10.3788/fgxb20194011.1321.

ZHENG Ke-zhi, QIN Wei-ping,. Upconversion Luminescence of Mn2+ in Yb3+-Mn2+ Codoped CaF2 Materials[J]. Chinese Journal of Luminescence, 2019,40(11): 1321-1326 DOI： 10.3788/fgxb20194011.1321.

摘要

稀土离子的上转换发光通常具有发射带宽窄及峰位难以调节等问题。为了获得近红外光激发下的宽带上转换发光，我们对Yb

-Mn

共掺杂CaF

材料的上转换发光性质进行了研究。将稀土离子Yb

及过渡族金属离子Mn

掺入到CaF

材料中作为发光中心，利用高温固相反应法制备了Yb

单独掺杂及不同浓度Yb

及Mn

离子共掺杂的CaF

体相材料。在980 nm近红外光激发下对不同样品的上转换发光进行了比较研究。实验结果表明，与单独掺杂Yb

离子的材料相比，CaF

:Yb

/Mn

材料在980 nm激光激发下出现了一个位于620 nm附近的宽带发光，我们认为这个发光来自于Yb

团簇向Mn

离子的合作敏化，对应于Mn

离子的

跃迁。因此，CaF

体系中存在Yb

离子二聚体向Mn

离子的合作能量传递过程。

Abstract

Lanthanide-doped upconversion luminescence generally features in narrow emission band and fixed emission wavelength. In order to obtain photo upconversion with wide-spectrum emission characteristic upon near-infrared laser excitation

upconversion luminescence of CaF

:Yb

and CaF

:Yb

/Mn

materials is investigated. Yb

and Mn

ions are codoped into CaF

materials as activators. CaF

:Yb

and CaF

:Yb

/Mn

bulky materials are synthesized using high-temperature solid state reactions. The upconversion luminescence properties of Yb

doped and Yb

-Mn

codoped CaF

materials are investigated upon 980 nm laser excitation. The experimental results indicate that compared with CaF

:Yb

system

a new upconversion emission peaked at 620 nm is obtained in CaF

:Yb

/Mn

materials. The cooperative energy transfer from Yb

-dimers to Mn

is considered to be the main reason for populating excited state of Mn

ions and the emission peaked at 620 nm comes from its

transition. The cooperative energy transfer from Yb

-dimers to Mn

is efficient in CaF

:Yb

/Mn

materials to populate excited Mn

and to obtain room-temperature upconversion emission of Mn

ions.

关键词

Keywords

references

AUZEL F. Upconversion and anti-Stokes processes with f and d ions in solids[J]. Chem. Rev., 2004,104(1):139-174.

POLLNAU M,GAMELIN D R,LTHI S R,et al.. Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems[J]. Phys. Rev. B, 2000,61(5):3337-3346.

ZHOU J,LIU Q,FENG W,et al.. Upconversion luminescent materials:advances and applications[J]. Chem. Rev., 2015,115(1):395-465.

HUANG X Y,HAN S Y,HUANG W,et al.. Enhancing solar cell efficiency:the search for luminescent materials as spectral converters[J]. Chem. Soc. Rev., 2013,42(1):173-201.

DENG R R,QIN F,CHEN R F,et al.. Temporal full-colour tuning through non-steady-state upconversion[J]. Nat. Nanotechnol., 2015,10(3):237-242.

ZHOU B,SHI B Y,JIN D Y,et al.. Controlling upconversion nanocrystals for emerging applications[J]. Nat. Nanotechnol., 2015,10(11):924-936.

ZHENG K Z,HAN S Y,ZENG X,et al.. Rewritable optical memory through high-registry orthogonal upconversion[J]. Adv. Mater., 2018,30(30):1801726-1-5.

XU J,XU L G,WANG C Y,et al.. Near-infrared-triggered photodynamic therapy with multitasking upconversion nanoparticles in combination with checkpoint blockade for immunotherapy of colorectal cancer[J]. ACS Nano, 2017,11(5):4463-4474.

RAO L,BU L L,CAI B,et al.. Cancer cell membrane-coated upconversion nanoprobes for highly specific tumor imaging[J]. Adv. Mater., 2016,28(18):3460-3466.

CHEN S,WEITEMIER A A,ZENG X,et al. Near-infrared deep brain stimulation via upconversion nanoparticle-mediated optogenetics[J]. Science, 2018,359(6376):679-684.

LIU X W,WANG Y,LI X Y,et al. Binary temporal upconversion codes of Mn2+-activated nanoparticles for multilevel anti-counterfeiting[J]. Nat. Commun., 2017,8:899-1-7.

LI X Y,LIU X W,CHEVRIER D M,et al.. Energy migration upconversion in manganese(Ⅱ)-doped nanoparticles[J]. Angew. Chem. Int. Ed., 2015,127(45):13510-13515.

HEER S,WERMUTH M,KRMER K,et al.. Up-conversion excitation of sharp Cr3+2E emission in YGG and YAG codoped with Cr3+ and Yb3+[J]. J. Lumin., 2015,94-95:337-341.

YANG L Y,DONG Y J,CHEN D P,et al.. Upconversion luminescence from2E state of Cr3+ in Al2O3 crystal by infrared femtosecond laser irradiation[J]. Opt. Express, 2005,13(20):7893-7898.

GARCA-REVILLA A,GERNER P,GDEL H U,et al.. Yb3+-sensitized visible Ni2+ photon upconversion in codoped CsCdBr3 and CsMgBr3[J]. Phys. Rev. B, 2005,72(12):125111-1-9.

SONG E H,WANG J L,YU D C,et al.. Anomalous tunable visible to near infrared emission in the Mn2+-doped spinel MgGa2O4 and room-temperature upconversion in the Mn2+ and Yb3+-codoped spinel[J]. J. Mater. Chem. C, 2014,2(41):8811-8816.

PALUMBO D T,BROWN JR J J. Electronic states of Mn2+-activated phosphors Ⅰ. Green-emitting phosphors[J]. J. Electrochem. Soc., 1971,117(9):1184-1188.

PALUMBO D T,BROWN JR J J. Electronic states of Mn2+-activated phosphors Ⅱ. Orange-to-red emitting phosphors[J]. J. Electrochem. Soc., 1971,118(7):1159-1164.

YU J H,KWON S H,PETREK Z,et al.. High-resolution three-photon biomedical imaging using doped ZnS nanocrystals[J]. Nat. Mater., 2013,12(4):359-366.

VALIENTE R,WENGER O,GDEL H U. New photon upconversion processes in Yb3+ doped CsMnCl3 and RbMnCl3[J]. Chem. Phys. Lett., 2000,320(5-6):639-644.

QIN W P,LIU Z Y,SIN C N,et al.. Multi-ion cooperative processes in Yb3+ clusters[J]. Light:Sci. Appl., 2014,3:e193-1-6.

LI Y Y,GUO J J,LIU X H,et al.. White upconversion luminescence in CaF2:Yb3+/Eu3+ powders via the incorporation of Y3+ ions[J]. Phys. Chem. Chem. Phys., 2016,18(24):16094-16097.

GUO J J,DI W H,AIDILIBIKE T,et al.. Cooperative energy acceptor of three Yb3+ ions[J]. J. Rare Earths, 2018,36(5):461-467.

AIDILIBIKE T,GUO J J,WANG L L,et al.. Ultraviolet upconversion emission of Pb2+ ions sensitized by Yb3+-trimers in CaF2[J]. RSC Adv., 2017,7(5):2676-2681.

LIU X H,AIDILIBIKE T,GUO J J,et al.. Upconversion luminescence of Sm2+ ions[J]. RSC Adv., 2017,7(23):14010-14014.

AIDILIBIKE T,LI Y Y,GUO J J,et al.. Blue upconversion emission of Cu2+ ions sensitized by Yb3+-trimers in CaF2[J]. J. Mater. Chem. C, 2016,4(11):2123-2126.

刘晓辉,马世童,郑克志,等. 基于合作能量传递的Sm2+离子上转换发光[J]. 发光学报, 2017,38(11):1413-1419. LIU X H,MA S T,ZHENG K Z,et al.. Upconversion luminescence of Sm2+ ions based on cooperative energy transfer[J]. Chin. J. Lumin., 2017,38(11):1413-1419. (in Chinese)

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Related Author

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MA Shi-tong

ZHENG Ke-zhi

QIN Wei-ping

CHI Ziheng

HE Shuai

DING Shoujun

ZHANG Chuancheng

Related Institution

吉林大学电子科学与工程学院

College of Science， Inner Mongolia University of Science & Technology

School of Microelectronics and Data Science， Anhui University of Technology， Ma’anshan

Department of Mathematics and Physics， Chongqing University of Posts and Telecommunications

State Key Laboratory of Luminescence and Applications， Changchun Institute of Optics， Fine Mechanics and Physics， Chinese Academy of Sciences

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