Synthesis and Application of Nitrogen-doped Carbon Dots

QU Song-nan; SUN Ming-hong; TIAN Zhen; BAO Xin; ZHOU Zheng-jie; ZHOU Ding; LI Di

doi:10.3788/fgxb20194005.0557

您当前的位置：

首页 >

文章列表页 >

Synthesis and Application of Nitrogen-doped Carbon Dots

Invited Paper | 更新时间：2020-08-12

- Synthesis and Application of Nitrogen-doped Carbon Dots
- Chinese Journal of Luminescence Vol. 40, Issue 5, Pages: 557-580(2019)
- 作者机构：
  
  1. 中国科学院长春光学精密机械与物理研究所发光学及应用国家重点实验室,吉林长春,130033
  2. 中国科学院大学北京,100049
- 作者简介：
- 基金信息：
  
  Supported by National Natural Science Foundation of China(51602304);Outstanding Young Scientists Program of Chinese Academy of Sciences(20170101191JC);Youth Innovation Promotion Association of CAS(20170101042JC);Jilin Province Science and Technology Research(20160520008JH,20150519003JH)
- DOI：10.3788/fgxb20194005.0557
  CLC： O482.31
- Received：20 February 2019，
  
  Revised：18 March 2019，
  
  Published Online：19 March 2019，
  
  Published：05 May 2019
- 稿件说明：
移动端阅览
曲松楠, 孙铭鸿, 田震等. 氮掺杂碳点的合成与应用[J]. 发光学报, 2019,40(5): 557-580

QU Song-nan, SUN Ming-hong, TIAN Zhen etc. Synthesis and Application of Nitrogen-doped Carbon Dots[J]. Chinese Journal of Luminescence, 2019,40(5): 557-580
曲松楠, 孙铭鸿, 田震等. 氮掺杂碳点的合成与应用[J]. 发光学报, 2019,40(5): 557-580 DOI： 10.3788/fgxb20194005.0557.

QU Song-nan, SUN Ming-hong, TIAN Zhen etc. Synthesis and Application of Nitrogen-doped Carbon Dots[J]. Chinese Journal of Luminescence, 2019,40(5): 557-580 DOI： 10.3788/fgxb20194005.0557.

摘要

碳纳米点（碳点）是一种新型的纳米发光材料，具有优异的发光性能、良好的生物相容性、低毒性、水溶性好和表面易功能化等特性，在光电器件、生物成像、光热治疗等领域展现了潜在应用价值。然而，合成碳点的前驱体材料多种多样，合成方法各有不同，导致其发光机理复杂多样。本文主要针对使用柠檬酸作为碳源、尿素或氨水作为氮源，采用微波和溶剂热的合成方法制备的氮掺杂碳点，探索碳点的发光机理和抑制碳点聚集诱导荧光猝灭的方法，并进一步研究碳点在固态照明、可见光光通讯、生物成像和光热治疗等领域的应用前景。

Abstract

Carbon nanodots(carbon dots) are a new type of nano-luminescent materials

which have such characteristics as excellent luminescence performance

good biocompatibility

low toxicity

good water solubility and easy surface functionalization

and have shown potential application value in the fields of optoelectronic devices

biological imaging and photothermal therapy. However

there are a variety of precursor materials for the synthesis of carbon nanodots

and the synthesis methods are different

leading to the complex and diverse luminescence mechanisms. This article mainly aims at preparing of nitrogen doped carbon nanodots by using citric acid as a carbon source or ammonia and urea as nitrogen source and solvent and microwave thermal methods

exploring the luminous mechanism of the carbon and inhibition of carbon accumulation induced fluorescence quenching method

and further research points of carbon in solid state lighting

visible in the field of optical communication

biological imaging and treatment of field application prospect.

关键词

Keywords

references

XU X Y,RAY R,GU Y L,et al.. Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments[J]. J. Am. Chem. Soc., 2004,126(40):12736-12737.

SUN Y P,ZHOU B,LIN Y,et al.. Quantum-sized carbon dots for bright and colorful photoluminescence[J]. J. Am. Chem. Soc., 2006,128(24):7756-7757.

BAKER S N,BAKER G A. Luminescent carbon nanodots:emergent nanolights[J]. Angew. Chem. Int. Ed. Engl., 2010,49(38):6726-6744.

YAN X,CUI X,LI L S. Synthesis of large,stable colloidal graphene quantum dots with tunable size[J]. J. Am. Chem. Soc., 2010,132(17):5944-5945.

LIU R L,WU D Q,LIU S H,et al.. An aqueous route to multicolor photoluminescent carbon dots using silica spheres as carriers[J]. Angew. Chem. Int. Ed. Engl., 2009,48(25):4598-4601.

BOURLINOS A B,STASSINOPOULOS A,ANGLOS D,et al.. Photoluminescent carbogenic dots[J]. Chem. Mater., 2008,20(14):4539-4541.

GUO X,WANG C F,YU Z Y,et al.. Facile access to versatile fluorescent carbon dots toward light-emitting diodes[J]. Chem. Commun., 2012,48(21):2692-2694.

MAO L H,TANG W Q,DENG Z Y,et al.. Facile access to white fluorescent carbon dots toward light-emitting devices[J]. Ind. Eng. Chem. Res., 2014,53(15):6417-6425.

MOON B J,OH Y,SHIN D H,et al.. Facile and purification-free synthesis of nitrogenated amphiphilic graphitic carbon dots[J]. Chem. Mater., 2016,28(5):1481-1488.

XU H,YANG X P,LI G,et al.. Green synthesis of fluorescent carbon dots for selective detection of tartrazine in food samples[J]. J. Agric. Food Chem., 2015,63(30):6707-6714.

BALDOVI H G,VALENCIA S,ALVARO M,et al.. Highly fluorescent C-dots obtained by pyrolysis of quaternary ammonium ions trapped in all-silica ITQ-29 zeolite[J]. Nanoscale, 2015,7(5):1744-1752.

STAN C S,ALBU C,COROABA A,et al.. One step synthesis of fluorescent carbon dots through pyrolysis of N-hydroxysuccinimide[J]. J. Mater. Chem. C, 2015,3(4):789-795.

XU M H,XU S S,YANG Z,et al.. Hydrophilic and blue fluorescent N-doped carbon dots from tartaric acid and various alkylol amines under microwave irradiation[J]. Nanoscale, 2015,7(38):15915-15923.

SONG L,CUI Y Y,ZHANG C F,et al.. Microwave-assisted facile synthesis of yellow fluorescent carbon dots from o-phenylenediamine for cell imaging and sensitive detection of Fe3+ and H2O2[J]. RSC Adv., 2016,6(21):17704-17712.

YUAN F L,WANG Z B,LI X H,et al.. Bright multicolor bandgap fluorescent carbon quantum dots for electroluminescent light-emitting diodes[J]. Adv. Mater., 2017,29(3):1604436-1-6.

YUAN F L,YUAN T,SUI L Z,et al.. Engineering triangular carbon quantum dots with unprecedented narrow bandwidth emission for multicolored LEDs[J]. Nat. Commun., 2018,9(1):2249-1-11.

YANG S T,WANG X,WANG H F,et al.. Carbon dots as nontoxic and high-performance fluorescence imaging agents[J]. J. Phys. Chem. C, 2009,113(42):18110-18114.

RUSSO P,HU A M,COMPAGNINI G,et al.. Femtosecond laser ablation of highly oriented pyrolytic graphite:a green route for large-scale production of porous graphene and graphene quantum dots[J]. Nanoscale, 2014,6(4):2381-2389.

RUSSO P,LIANG R,JABARI E,et al.. Single-step synthesis of graphene quantum dots by femtosecond laser ablation of graphene oxide dispersions[J]. Nanoscale, 2016,8(16):8863-8877.

NIU F S,XU Y H,LIU M L,et al.. Bottom-up electrochemical preparation of solid-state carbon nanodots directly from nitriles/ionic liquids using carbon-free electrodes and the applications in specific ferric ion detection and cell imaging[J]. Nanoscale, 2016,8(10):5470-5477.

ZHENG L Y,CHI Y W,DONG Y Q,et al.. Electrochemiluminescence of water-soluble carbon nanocrystals released electrochemically from graphite[J]. J. Am. Chem. Soc., 2009,131(13):4564-4565.

MING H,MA Z,LIU Y,et al.. Large scale electrochemical synthesis of high quality carbon nanodots and their photocatalytic property[J]. Dalton Trans., 2012,41(31):9526-9531.

SHIH C C,CHEN P C,LIN G L,et al.. Optical and electrochemical applications of silicon-carbon dots/silicon dioxide nanocomposites[J]. ACS Nano, 2015,9(1):312-319.

LI H T,HE X D,KANG Z H,et al.. Water-soluble fluorescent carbon quantum dots and photocatalyst design[J]. Angew. Chem. Int. Ed. Engl., 2010,49(26):4430-4434.

QU S N,WANG X Y,LU Q P,et al.. A biocompatible fluorescent ink based on water-soluble luminescent carbon nanodots[J]. Angew. Chem. Int. Ed. Engl., 2012,51(49):12215-12218.

QU S N,LIU X Y,GUO X Y,et al.. Amplified spontaneous green emission and lasing emission from carbon nanoparticles[J]. Adv. Funct. Mater., 2014,24(18):2689-2695.

LOU Q,QU S N,JING P T,et al.. Water-triggered luminescent "nano-bombs" based on supra-(carbon nanodots)[J]. Adv. Mater., 2015,27(8):1389-1394.

QU S N,ZHOU D,LI D,et al.. Toward efficient orange emissive carbon nanodots through conjugated sp2-domain controlling and surface charges engineering[J]. Adv. Mater., 2016,28(18):3516-3521.

TIAN Z,ZHANG X T,LI D,et al.. Full-color inorganic carbon dot phosphors for white-light-emitting diodes[J]. Adv. Opt. Mater., 2017,5(19):1700416-1-9.

LI D,HAN D,QU S N,et al.. Supra-(carbon nanodots) with a strong visible to near-infrared absorption band and efficient photothermal conversion[J]. Light Sci. Appl., 2016,5:e16120-1-8.

LI D,JING P T,SUN L H,et al.. Near-infrared excitation/emission and multiphoton-induced fluorescence of carbon dots[J]. Adv. Mater., 2018,30(13):1705913-1-8.

JING P T,HAN D,LI D,et al.. Origin of anisotropic photoluminescence in heteroatom-doped carbon nanodots[J]. Adv. Opt. Mater., 2017,5(8):1601049-1-7.

JING P T,HAN D,LI D,et al.. Surface related intrinsic luminescence from carbon nanodots:solvent dependent piezochromism[J]. Nanoscale Horiz., 2019,4(1):175-181.

SUN M Y,QU S N,HAO Z D,et al.. Towards efficient solid-state photoluminescence based on carbon-nanodots and starch composites[J]. Nanoscale, 2014,6(21):13076-13081.

ZHAI Y C,WANG Y,LI D,et al.. Red carbon dots-based phosphors for white light-emitting diodes with color rendering index of 92[J]. J. Colloid Interface Sci., 2018,528:281-288.

ZHAI Y C,ZHOU D,JING P T,et al.. Preparation and application of carbon-nanodot@NaCl composite phosphors with strong green emission[J]. J. Colloid Interface Sci., 2017,497:165-171.

ZHOU D,ZHAI Y C,QU S N,et al.. Electrostatic assembly guided synthesis of highly luminescent carbon-nanodots@BaSO4 hybrid phosphors with improved stability[J]. Small, 2017,13(6):1602055.

ZHOU D,LI D,JING P T,et al.. Conquering aggregation-induced solid-state luminescence quenching of carbon dots through a carbon dots-triggered silica gelation process[J]. Chem. Mater., 2017,29(4):1779-1787.

ZHOU Z J,TIAN P F,LIU X Y,et al.. Hydrogen peroxide-treated carbon dot phosphor with a bathochromic-shifted,aggregation-enhanced emission for light-emitting devices and visible light communication[J]. Adv. Sci., 2018,5(8):1800369-1-8.

ZHOU D,JING P T,WANG Y,et al.. Carbon dots produced via space-confined vacuum heating:maintaining efficient luminescence in both dispersed and aggregated states[J]. Nanoscale Horiz., 2019,4(2):388-395.

LIU F,JANG M H,HA H D,et al.. Facile synthetic method for pristine graphene quantum dots and graphene oxide quantum dots:origin of blue and green luminescence[J]. Adv. Mater., 2013,25(27):3657-3662.

BAO X,YUAN Y,CHEN J Q,et al.. In vivo theranostics with near-infrared-emitting carbon dots-highly efficient photothermal therapy based on passive targeting after intravenous administration[J]. Light Sci. Appl., 2018,7(1):91-1-11.

娄庆,曲松楠. 基于超级碳点的水致荧光"纳米炸弹"[J]. 中国光学, 2015,8(1):91-98. LOU Q,QU S N. Water triggered luminescent "nano-bombs" based on supra-carbon-nanodots[J]. Chin. Opt., 2015,8(1):91-98. (in Chinese)

TIAN Z,LI D,USHAKOVA E V,et al.. Multilevel data encryption using thermal-treatment controlled room temperature phosphorescence of carbon dot/polyvinylalcohol composites[J]. Adv. Sci., 2018,5(9):1800795.

于淑娟,陈宽,汪丰,等. 壳聚糖基聚合物碳点荧光材料合成及其自组装载药应用[J]. 中国光学, 2018,11(3):420-430. YU S J,CHEN K,WANG F,et al.. Synthesis of chitosan-based polymer carbon dots fluorescent materials and application of self-assembled drug-loading[J]. Chin. Opt., 2018,11(3):420-430. (in Chinese)

Views

3852

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research Progress in Development of Dioxetane Intermediates-based Afterglow Luminescent Materials and Their Applications in Bioimaging

Advances in Luminescence Characteristics, Luminescence Mechanisms and Applications of Inorganic Mechanoluminescent Materials

Synthesis and Luminescent Properties of Self-activated LiSr₂Ca₂（BN₂）₃ Phosphor

Research Progress on Pr³⁺ Doped Red Persistent Luminescent Materials

Preparation of Controllable Luminescence CDs@MOFs Fluorescent Composites and Their Application in High Color Rendering White LED

Related Author

DING Dan

JI Shenglu

WANG Nannan

CAI Gemei

WANG Jin

AO Yuchen

WANG Kai-xuan

NA Ri-su

Related Institution

Frontiers Science Center for New Organic Matter， State Key Laboratory of Medicinal Chemical Biology， Key Laboratory of Bioactive Materials， Ministry of Education， College of Life Sciences， Nankai University

The Key Laboratory of Biomedical Materials， School of Life Science and Technology， Xinxiang Medical University

School of Material Science and Engineering， Central South University

Inner Mongolia Engineering Research Center of New Energy Storage Materials

Inner Mongolia Key Laboratory for Physics and Chemistry of Functional Materials， Inner Mongolia Normal University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰