Synthesis and Properties of A Novel Colorimetric Fluorescent Probe for Fe3+ at Dual Emission Wavelengths

ZENG Jing; LIU Rui-jiao; CHEN Jia-min

doi:10.3788/fgxb20194004.0542

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Synthesis and Properties of A Novel Colorimetric Fluorescent Probe for Fe³⁺ at Dual Emission Wavelengths

Luminescence Applications and Interdisciplinary Fields | 更新时间：2020-08-12

- Synthesis and Properties of A Novel Colorimetric Fluorescent Probe for Fe³⁺ at Dual Emission Wavelengths
- Chinese Journal of Luminescence Vol. 40, Issue 4, Pages: 542-551(2019)
- 作者机构：
  
  新疆师范大学化学化工学院, 新疆乌鲁木齐 830054
- 作者简介：
- 基金信息：
  
  Supported by Natural Science Foundation of Xinjiang Uygur Aotonomous Region(2015211B024);Key Discipline of Xinjiang Normal University(17SDK0801)
- DOI：10.3788/fgxb20194004.0542
  CLC： O621.2;O621.3
- Received：21 May 2018，
  
  Revised：06 August 2018，
  
  Published Online：23 August 2018，
  
  Published：05 April 2019
- 稿件说明：
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曾竟, 刘瑞姣, 陈佳敏. 在双波长下识别Fe3+的一种新型可视化荧光探针的合成及性能[J]. 发光学报, 2019,40(4): 542-551

ZENG Jing, LIU Rui-jiao, CHEN Jia-min. Synthesis and Properties of A Novel Colorimetric Fluorescent Probe for Fe3+ at Dual Emission Wavelengths[J]. Chinese Journal of Luminescence, 2019,40(4): 542-551
曾竟, 刘瑞姣, 陈佳敏. 在双波长下识别Fe3+的一种新型可视化荧光探针的合成及性能[J]. 发光学报, 2019,40(4): 542-551 DOI： 10.3788/fgxb20194004.0542.

ZENG Jing, LIU Rui-jiao, CHEN Jia-min. Synthesis and Properties of A Novel Colorimetric Fluorescent Probe for Fe3+ at Dual Emission Wavelengths[J]. Chinese Journal of Luminescence, 2019,40(4): 542-551 DOI： 10.3788/fgxb20194004.0542.

摘要

合成了一种新型四苯乙烯-罗丹明化合物

，通过紫外-可见吸收光谱、分子荧光光谱、裸眼和循环伏安分析法等分别研究了化合物

的聚集诱导发光性能、对金属阳离子的识别性能和电化学性能。实验结果显示:化合物

在乙醇-水的混合溶剂中表现出典型的聚集诱导发光性能；

在EtOH/H

O（

V:V

，1:1，Tris-HCl，pH=7.0）溶液中随Fe

的加入，化合物

的EtOH/H

O（

V:V

，1:1，Tris-HCl，pH=7.0）溶液显示出明显的颜色变化，由无色变成红色，除Al

、Cr

略微变红外，其他金属离子无明显变化，这表明化合物

可作为裸眼识别Fe

的探针；当选用激发波长350 nm 时，在508 nm 处的荧光发射强度发生猝灭，猝灭比为87.5%，检出限为4.5610

-6

mol/L；激发波长为530 nm时，在582 nm处荧光发射强度呈增大趋势，较加入前增大了49.6倍，检出限可达7.410

-7

mol/L。由此可见，

在用不同激发波长激发时，在两个不同荧光发射波长下分别实现了对Fe

的"turn-off"和"turn-on"识别，因此

可作为一种具有高灵敏性和专一选择性的可视化Fe

荧光探针。并经Job's曲线、紫外和荧光滴定、核磁滴定、扫描电镜初步确定了探针

和Fe

的络合机理，探针

和Fe

的络合比为2:1，整个测试在中性条件下进行，使得该类探针在生物体系或环境中有潜在的应用价值。且它的电离势为5.77 eV，电离势与正电极的功函数（5.5 eV）较匹配，有望开发成为空穴传输材料。电子亲合势为3.71 eV，比常见的电子传输材料PBD（

=2.82 eV）的电子亲和能大，有望开发为电子传输材料，所合成的化合物也可作为一类具有潜在应用价值的光电材料。

Abstract

A novel derivative

based on tetraphenylethylene-rhodamine was synthesized. FT-IR

NMR

UV-Vis and solution fluorescence and cyclic voltammetry electrochemical analysis were used to study the structure

optical properties

recognition ability of compound

to metal ions and electrochemical properties. The experimental results showed that compound

possessed a significant aggregation-induced emission(AIE) characteristic in different

(EtOH):

O) mixed solvents. When 10 equiv. of Fe

was added to the solution containing probe

the solution of compound

in EtOH/H

V:V

1:1

Tris-HCl

pH=7.0) changed the color from colorless to red. Except that the addition of Al

or Cr

slightly changed the solution color to reddish

the addition of other metal ions did not induce significant color changes. The fluorescence spectra showed that when fluorescence emission wavelength at 508 nm was quenched with a quenching ratio of 87.5% and the detection limit of Fe

was as low as 4.5610

-6

mol/L. Interestingly

the fluorescence intensity at 582 nm increased with the addition of Fe

which was increased by 49.6 times with the detection limit of Fe

was as low as 7.410

-7

mol/L

which achieved the "turn-off" and "turn-on" visual detection of Fe

at the maximum fluorescence emission wavelengths of 508 nm and 582 nm

respectively. Thus

the probe

is a highly sensitive

specific

and visible fluorescent probe for the detection of Fe

. The mechanisms have been supported by reversibility of the Job's plot

UV-vis and fluorescence titrations

H NMR spectroscopic studies and SEM images. The complexing ratio of probe

with Fe

was determined to be 2:1. The test was conducted in neutral aqueous solutions

which indicated that the probe

could be applicable to the research on the biological and environmental applications associated with Fe

. Cyclic voltammetry electrochemical analysis was used to study their electrochemical properties

the results showed that

had good hole transporting ability and good electron transporting capability.

can be used as a optoelectronic material.

关键词

Keywords

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