MAPbI(3-x)Brx Perovskite Solar Cells Based on Adjustable Band Gap

WEI Qing-bo; GUI A-min; GAO Jing-nan; ZHOU Pan; FU Feng

doi:10.3788/fgxb20194004.0491

您当前的位置：

首页 >

文章列表页 >

MAPbI_(3-x)Br_x Perovskite Solar Cells Based on Adjustable Band Gap

Device Fabrication and Physics | 更新时间：2020-08-12

- MAPbI_(3-x)Br_x Perovskite Solar Cells Based on Adjustable Band Gap
- Chinese Journal of Luminescence Vol. 40, Issue 4, Pages: 491-496(2019)
- 作者机构：
  
  延安大学化学与化工学院陕西省化学反应工程重点实验室,陕西延安,716000
- 作者简介：
- 基金信息：
  
  Support by National Natural Science Foundation of China(21663030,21666039);Science and Technology Coordination Innovation Project of Shaanxi Province(2017TSCL-N-7-3);Key Laboratory of Education Department of Shaanxi Province(15JS120);Doctoral Research Initial Funding from Yan'an University(YDBK2017-14);Natural Science Foundation of Yan'an University(YDQ2018-15)
- DOI：10.3788/fgxb20194004.0491
  CLC： O472
- Received：08 June 2018，
  
  Revised：13 September 2018，
  
  Published Online：21 September 2018，
  
  Published：05 April 2019
- 稿件说明：
移动端阅览
魏清渤, 归阿敏, 高静楠等. 基于带隙可调的MAPbI(3-x)Brx钙钛矿电池[J]. 发光学报, 2019,40(4): 491-496

WEI Qing-bo, GUI A-min, GAO Jing-nan etc. MAPbI(3-x)Brx Perovskite Solar Cells Based on Adjustable Band Gap[J]. Chinese Journal of Luminescence, 2019,40(4): 491-496
魏清渤, 归阿敏, 高静楠等. 基于带隙可调的MAPbI(3-x)Brx钙钛矿电池[J]. 发光学报, 2019,40(4): 491-496 DOI： 10.3788/fgxb20194004.0491.

WEI Qing-bo, GUI A-min, GAO Jing-nan etc. MAPbI(3-x)Brx Perovskite Solar Cells Based on Adjustable Band Gap[J]. Chinese Journal of Luminescence, 2019,40(4): 491-496 DOI： 10.3788/fgxb20194004.0491.

摘要

采用一步溶液法制备了MAPbI

（3-

）

钙钛矿太阳电池，研究了MABr掺杂含量变化对薄膜形貌及光电性能的影响。研究结果表明，在MAPbI

（3-

）

体系中，随着MABr含量的增加，钙钛矿层晶粒尺寸明显增大；紫外-可见吸收光谱和稳态荧光测试表明峰位发生蓝移；构筑的MAPbI

（3-

）

电池器件的开路电压

=1.02 V，光电转换效率 PCE为12.68%。

Abstract

The MAPbI

(3-

)

perovskite solar cell was deposited in one-step solution approach. This study focuses on the influence of MABr on the morphology

optical absorption and photovoltaic performances. The results show that the surface of the deposited CH

PbI

(3-

)

became rougher and the grain sizes larger with the MABr concentration increasing. UV-Vis-NIR spectra and photoluminescence peak of CH

PbI

(3-

)

film blue shifted with increasing of the MABr concentration. The MAPbI

(3-

)

solar cells exhibite open circuit voltage of 1.02 V with power conversion efficiency of 12.68%.

关键词

Keywords

references

KOJIMA A,TESHIMA K,SHIRAI Y S,et al.. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J]. J. Am. Chem. Soc., 2009,131(17):6050-6051.

IM J H,LEE C R,LEE J W,et al.. 6.5% efficient perovskite quantum-dot-sensitized solar cell[J]. Nanoscale, 2011, 3(10):4088-4093.

KIM H S,LEE C R,IM J H,et al.. Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%[J]. Sci. Rep., 2012,2:591.

LEE M,TEUSCHER J,MIYASAKA T,et al.. Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites[J]. Science, 2012,338(6107):643-647.

BURSCHKA J,PELLET N,MOON S J,et al.. Sequential deposition as a route to high-performance perovskite-sensitized solar cells[J]. Nature, 2013,499:316-319.

STRANKS S D,EPERON G E,GRANCINI G,et al.. Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber[J]. Science, 2013,342(6156):341-344.

YANG D,YANG R X,ZHANG J,et al.. High efficiency flexible perovskite solar cells using superior low temperature TiO2[J]. Energy Environ. Sci., 2015,8(11):3208-3214.

YANG Z,CAI B,ZHOU B,et al.. An up-scalable approach to CH3NH3PbI3 compact films for high-performance perovskite solar cells[J]. Nano Energy, 2015,15:670-678.

LIU M Z,JOHNSTON M B,SNAITH H J. Efficient planar heterojunction perovskite solar cells by vapour deposition[J]. Nature, 2013,501(7467):395-398.

GONZALEZ-PEDRO V,JUAREZ-PEREZ E J,ARSYAD W S,et al.. General working principles of CH3NH3PbX3 perovskite solar cells[J]. Nano Lett., 2014,14(2):888-893.

LIU D Y,KELLY T L. Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques[J]. Nat. Photon., 2014,8(2):133-138.

WOJCIECHOWSKI K,SALIBA M,LEIJTENS T,et al.. Sub-150℃ processed meso-superstructured perovskite solar cells with enhanced efficiency[J]. Energy Environ. Sci., 2014,7(3):1142-1147.

ZHOU H P,CHEN Q,LI G,et al.. Interface engineering of highly efficient perovskite solar cells[J]. Science, 2014,345(6196):542-546.

ZI W,JIN Z,LIU S,et al.. Flexible perovskite solar cells based on green, continuous roll-to-roll printing technology[J]. J. Energy Chem., 2018,27(4):971-989.

LIU Y C,YANG Z,CUI D,et al.. Two-inch-sized perovskite CH3NH3PbX3(X=Cl,Br,I) crystals:growth and characterization[J]. Adv. Mater., 2015,27(25):5176-5183.

WEI Q,YANG Z,YANG D,et al.. The effect of transparent conductive oxide on the performance CH3NH3PbI3 perovskite solar cell without electron/hole selective layers[J]. Sol. Energy, 2016,135:654-661.

GONZALEZ-CARRERO S,GALIAN R E,PREZ-PRIETO J. Maximizing the emissive properties of CH3NH3PbBr3 perovskite nanoparticles[J]. J. Mater. Chem. A, 2015,3(17):9187-9193.

KIM H B,IM I,YOON Y,et al.. Enhancement of photovoltaic properties of CH3NH3PbBr3 heterojunction solar cells by modifying mesoporous TiO2 surfaces with carboxyl groups[J]. J. Mater. Chem. A, 2015,3(17):9264-9270.

KIM Y H,CHO H,HEO J H,et al.. Multicolored organic/inorganic hybrid perovskite light-emitting diodes[J]. Adv. Mater., 2015,27(7):1248-1254.

LEWIS D J,O'BRIEN P. Ambient pressure aerosol-assisted chemical vapour deposition of (CH3NH3)PbBr3,an inorganic-organic perovskite important in photovoltaics[J]. Chem. Commun., 2014,50(48):6319-6321.

RYU S,NOH J H,JEON N J,et al.. Voltage output of efficient perovskite solar cells with high open-circuit voltage and fill factor[J]. Energy Environ. Sci., 2014,7(8):2614-2618.

CHEN Q,ZHOU H P,FANG Y H,et al.. The optoelectronic role of chlorine in CH3NH3PbI3(Cl)-based perovskite solar cells[J]. Nat. Commun., 2015,6:7269.

XIE Y,SHAO F,WANG Y M,et al.. Enhanced performance of perovskite CH3NH3PbI3 solar cell by using CH3NH3I as additive in sequential deposition[J]. ACS Appl. Mater. Interfaces, 2015,7(23):12937-12942.

SHI J J,LUO Y H,WEI H Y,et al.. Modified two-step deposition method for high-efficiency TiO2/CH3NH3PbI3 heterojunction solar cells[J]. ACS Appl. Mater. Interfaces, 2014,6(12):9711-9718.

LIU D Y,YANG J L,KELLY T L. Compact layer free perovskite solar cells with 13.5% efficiency[J]. J. Am. Chem. Soc., 2014,136:17116-17122.

SUN S Y,SALIM T,MATHEWS N,et al.. The origin of high efficiency in low-temperature solution-processable bilayer organometal halide hybrid solar cells[J]. Energy Environ. Sci., 2014,7(1):399-407.

REN X,YANG D,YANG Z,et al.. Solution-processed Nb:SnO2 electron transport layer for efficient planar perovskite solar cells[J]. ACS Appl. Mater. Interfaces, 2017,9(3):2421-2429.

YANG D,YANG R X,WANG K,et al.. High efficiency planar-type perovskite solar cells with negligible hysteresis using EDTA-complexed SnO2[J]. Nat. Commun., 2018,9(1):3239.

Views

244

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research Progress on Photogating Effect in Regulating Response Characteristics of Photodetectors

Advances in High-energy Irradiation Stability and Damage Mechanisms of Perovskite Materials

Regulation of Perovskite Crystallization Process and Its Mechanism Based on Green Anti-solvent Engineering

Review of Advances in Large-area Perovskite Solar Cell Thin-film Fabrication Techniques

Red Low-threshold Amplified Spontaneous Emission of Perovskite Films Achieved by A-site Substitution and Defect Passivation

Related Author

LIU Hao

SONG Hongwei

CHEN Cong

LIU Xiaoqing

LU Shuai

XIA Mengling

LIU Zhijun

YANG Ping

Related Institution

School of Material Science and Engineering， Hebei University of Technology

State Key Laboratory of Integrated Optoelectronics， College of Electronic Science and Engineering， Jilin University

School of Materials Science and Engineering， Wuhan University of Technology

R&D Institute of Fluid and Powder Engineering， Dalian University of Technology

College of Mechanical Engineering， Dalian University of Technology

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰