Electrospinning Fabrication of Eu(BPA)3phen/Polyacrylonitrile Fibers and Properties

XIE Guang-bo; ZHANG Zi-jun; ZHANG Jing-jing; WANG Zhi-qiang; LIN Hai

doi:10.3788/fgxb20194004.0468

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Electrospinning Fabrication of Eu(BPA)₃phen/Polyacrylonitrile Fibers and Properties

Synthesis and Properties of Materials | 更新时间：2020-08-12

- Electrospinning Fabrication of Eu(BPA)₃phen/Polyacrylonitrile Fibers and Properties
- Chinese Journal of Luminescence Vol. 40, Issue 4, Pages: 468-475(2019)
- 作者机构：
  
  大连工业大学纺织与材料工程学院,辽宁大连,116034
- 作者简介：
- 基金信息：
  
  Supported by China Postdoctoral Science Foundation General Program(2017M621128);Liaoning Science and Technology Research Program(201601277);Natural Science Foundation of Liaoning Province(201602057)
- DOI：10.3788/fgxb20194004.0468
  CLC： TQ342+.8
- Received：25 May 2018，
  
  Revised：02 August 2018，
  
  Published Online：30 August 2018，
  
  Published：05 April 2019
- 稿件说明：
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解广波, 张子俊, 张晶晶等. 静电纺丝技术制备Eu(BPA)3phen/聚丙烯腈纤维及其性能[J]. 发光学报, 2019,40(4): 468-475

XIE Guang-bo, ZHANG Zi-jun, ZHANG Jing-jing etc. Electrospinning Fabrication of Eu(BPA)3phen/Polyacrylonitrile Fibers and Properties[J]. Chinese Journal of Luminescence, 2019,40(4): 468-475
解广波, 张子俊, 张晶晶等. 静电纺丝技术制备Eu(BPA)3phen/聚丙烯腈纤维及其性能[J]. 发光学报, 2019,40(4): 468-475 DOI： 10.3788/fgxb20194004.0468.

XIE Guang-bo, ZHANG Zi-jun, ZHANG Jing-jing etc. Electrospinning Fabrication of Eu(BPA)3phen/Polyacrylonitrile Fibers and Properties[J]. Chinese Journal of Luminescence, 2019,40(4): 468-475 DOI： 10.3788/fgxb20194004.0468.

摘要

为了增强稀土络合物的物理化学性能和成型加工性能，以扩大稀土发光材料在防伪、荧光标识与OLED等领域中的应用，本文将实验合成的铕的络合物溶于聚丙烯腈，通过静电纺丝技术制备了一种新型的Eu（BPA）

phen/PAN紫外荧光复合纳米纤维。采用扫描电子显微镜（SEM）、X射线能量色散谱仪（EDS）、傅立叶红外光谱仪（FT-IR）、热重差热分析仪（TG-DSC）与荧光光谱仪（FL）对发光纳米纤维的性能进行分析。实验结果表明，复合纤维的直径分布在200~400 nm，且随机取向。热重分析表明，Eu（BPA）

phen/PAN复合纤维的初始分解温度约为310℃，热稳定性较好。此外，研究了掺杂不同浓度Eu（BPA）

phen对纤维发光性能的影响，发现纤维的荧光发射强度随着Eu（BPA）

phen含量的增加呈现先增后减的变化趋势，当Eu（BPA）

phen的含量为2.5%时，荧光强度最高。这种新型的的Eu（BPA）

phen/PAN荧光复合纤维在防伪和OLED等方面具有潜在应用价值。

Abstract

In order to enhance the physicochemical properties and processability of rare earth complexes

and to further expand the practical applications in the field of anti-counterfeiting

fluorescent labeling and OLED

in this paper

novel luminescent composite fibers were prepared by electrospinning of PAN solutions containing the europium complex Eu(BPA)

phen. The characterization of the luminescent fibers has been investigated by scanning electron microscopy(SEM)

energy dispersive spectroscopy(EDS)

Fourier infrared spectrometer(FTIR)

thermogravimetric analysis(TG-DSC) and fluorescence spectroscopy(PL). The results show that the diameter of composite fibers distributs between 200 nm to 400 nm

and random orientation. Thermogravimetric analysis indicates that the initial decomposition temperature of Eu(BPA)

phen/PAN composite fibers is 330℃

approximately. Furthermore

fluorescence spectra studies revealed that with the increasing of the incorporation of complexes into PAN

the fluorescence intensities were remarkable enhanced and reached its maximum value at 2.5% for Eu(BPA)

phen/PAN fibers. The further intensity decreased with the increasing content of the complexes because of typical emission concentration quenching. The novel luminescent composite nanofibers have potential applications in the field of anti-counterfeiting and OLED.

关键词

Keywords

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