Effect of Fe3O4 Nanoparticles on P3HT: PCBM Solar Cells

WANG Li-juan; FAN Si-da; ZHANG Liang; ZHANG Pei-pei; LI Zhan-guo; SUN li-jing

doi:10.3788/fgxb20183910.1410

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Effect of Fe₃O₄ Nanoparticles on P3HT: PCBM Solar Cells

更新时间：2020-08-12

- Effect of Fe₃O₄ Nanoparticles on P3HT: PCBM Solar Cells
- Chinese Journal of Luminescence Vol. 39, Issue 10, Pages: 1410-1416(2018)
- 作者机构：
  
  1. 长春工业大学化学工程学院,吉林长春,130012
  2. 长春理工大学高功率半导体激光国家重点实验室,吉林长春,130022
- 作者简介：
- 基金信息：
  
  Supported by National Natural Science Foundation of China (21403016);Scientific Re
- DOI：10.3788/fgxb20183910.1410
  CLC： O649
- Received：26 January 2018，
  
  Revised：12 March 2018，
  
  Published Online：09 February 2018，
  
  Published：05 October 2018
- 稿件说明：
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王丽娟, 范思大, 张梁等. Fe3O4纳米粒子对P3HT:PCBM电池的影响[J]. 发光学报, 2018,39(10): 1410-1416

WANG Li-juan, FAN Si-da, ZHANG Liang etc. Effect of Fe3O4 Nanoparticles on P3HT: PCBM Solar Cells[J]. Chinese Journal of Luminescence, 2018,39(10): 1410-1416
王丽娟, 范思大, 张梁等. Fe3O4纳米粒子对P3HT:PCBM电池的影响[J]. 发光学报, 2018,39(10): 1410-1416 DOI： 10.3788/fgxb20183910.1410.

WANG Li-juan, FAN Si-da, ZHANG Liang etc. Effect of Fe3O4 Nanoparticles on P3HT: PCBM Solar Cells[J]. Chinese Journal of Luminescence, 2018,39(10): 1410-1416 DOI： 10.3788/fgxb20183910.1410.

摘要

为了提高太阳能电池的性能，研究磁性纳米粒子在外加磁场的作用下对聚合物太阳能电池有源层P3HT:PCBM成膜及太阳能电池性能的影响。本文采用热分解法制备了磁性Fe

纳米粒子，将不同质量分数的Fe

纳米粒子掺入到P3HT:PCBM溶液中，旋涂后在外加磁场的作用下自组成膜。通过TEM、XRD对制备的Fe

纳米粒子进行表征，并利用偏光显微镜、原子力显微镜对成膜质量进行探究。结果表明，采用热分解法制备的Fe

纳米粒子直径在10 nm左右，在外加磁场作用下，Fe

纳米粒子对成膜有一定的调控作用。当Fe

纳米粒子掺杂质量分数为1%时，太阳能电池器件的开路电压增加3.77%，短路电流增加24.93%，光电转换效率提高7.82%。

Abstract

To improve the properties of polymer solar cells

the effect of magnetic nanoparticles on the P3HT:PCBM films as the active layer and the properties of polymer solar cells under the external magnetic field were investigated. The Fe

magnetic nanoparticles were prepared by thermal decomposition. The Fe

nanoparticles of different mass fraction were added to P3HT:PCBM solution.The as-casting films by spin coating method were put into the external magnetic field and the self-assembled Fe

+P3HT:PCBM films were formed. Fe

nanoparticles were characterized by TEM and XRD

and the surface morphology of films was investigated by polarizing microscope(POM) and atomic force microscope(AFM). The results show that Fe

nanoparticles are about 10 nm in diameter

and have a certain regulating effect on building film of P3HT:PCBM. When Fe

nanoparticles are added with a mass fraction 1%

the open circuit voltage(

) of the solar cells increases by 3.77%

the short-circuit current(

) increases by 24.93%

and the photoelectric conversion efficiency(PCE) increases by 7.82%.

关键词

Keywords

references

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Related Institution

College of Physics Electronic Engineering, Hainan Normal University

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Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, School of Materials Science and Engineering, South China University of Technology

Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University

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