Structure and Spectroscopic Properties of Er3+-doped GeO2-TeO2-Na2O Glass

SHI Dong-mei; ZHAO Ying-gang

doi:10.3788/fgxb20183910.1352

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Structure and Spectroscopic Properties of Er³⁺-doped GeO₂-TeO₂-Na₂O Glass

更新时间：2020-08-12

- Structure and Spectroscopic Properties of Er³⁺-doped GeO₂-TeO₂-Na₂O Glass
- Chinese Journal of Luminescence Vol. 39, Issue 10, Pages: 1352-1358(2018)
- 作者机构：
  
  洛阳理工学院材料科学与工程学院,河南洛阳,471023
- 作者简介：
- 基金信息：
  
  Supported by National Natural Science Foundation of China(51002070);Natural Scienc
- DOI：10.3788/fgxb20183910.1352
  CLC： O482.31
- Received：23 February 2018，
  
  Revised：26 May 2018，
  
  Published Online：11 June 2018，
  
  Published：05 October 2018
- 稿件说明：
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石冬梅, 赵营刚,. Er3+掺杂的锗碲酸盐玻璃结构及光谱性能研究[J]. 发光学报, 2018,39(10): 1352-1358

SHI Dong-mei, ZHAO Ying-gang,. Structure and Spectroscopic Properties of Er3+-doped GeO2-TeO2-Na2O Glass[J]. Chinese Journal of Luminescence, 2018,39(10): 1352-1358
石冬梅, 赵营刚,. Er3+掺杂的锗碲酸盐玻璃结构及光谱性能研究[J]. 发光学报, 2018,39(10): 1352-1358 DOI： 10.3788/fgxb20183910.1352.

SHI Dong-mei, ZHAO Ying-gang,. Structure and Spectroscopic Properties of Er3+-doped GeO2-TeO2-Na2O Glass[J]. Chinese Journal of Luminescence, 2018,39(10): 1352-1358 DOI： 10.3788/fgxb20183910.1352.

摘要

采用熔融淬冷法制备了新型的Er

（

=Ce

，Tb

）掺杂的GeO

-TeO

-Na

O玻璃。测试了样品的差示扫描分析曲线、可见/近红外透过率、拉曼光谱、吸收光谱和1.53 m发光光谱。研究发现适量的TeO

对GeO

的取代提高了玻璃的热稳定性，缩短了样品的吸收截止边。拉曼分析表明该系统玻璃有着宽广的红外透过范围。同时研究了980 nm激发下稀土离子（

=Ce

，Tb

）的加入对Er

掺杂的45GeO

-45TeO

-10Na

O玻璃的光谱性能和能量传递的影响。发现随着Ce

浓度增加大大地提高了1.53 m的发光强度，CeO

的最佳掺杂摩尔分数为0.1%，而Tb

的共掺降低了1.53 m的发光强度。可见Er

/Ce

掺杂的45GeO

-45TeO

-10Na

O玻璃在C波段光纤放大器方面有潜在的应用前景。

Abstract

A new type of Er

(

=Ce

)-doped GeO

-TeO

-Na

O glasses were prepared by melting quenching method. The differential scanning analysis curves

visible/near infrared transmittance

Raman spectra

absorption spectra and 1.53 m luminescence spectra were tested. It is found that the thermal stability is enhanced and the absorption cutoff edge of the samples blue-shifted with the increase of substituted GeO

content for TeO

. Raman analysis shows that the GeO

-TeO

-Na

O glass has a wide range of infrared transmittance. Meanwhile

the influence of rare earth ions (

=Ce

) on the spectral properties and energy transfer of Er

-doped 45GeO

-45TeO

-10Na

O glass under 980 nm excitation has been studied. 1.53 m emission intensity shows a firstly increasing and then decreasing trend

and the optimal CeO

mole fraction is 0.1%. While co-doping Tb

reduces the 1.53 m emission intensity of Er

. It can be seen that the Er

/Ce

-doped 45GeO

-45TeO

-10Na

O glass might be a promising material in the field of C band fiber amplifier.

关键词

Keywords

references

王伟超, 袁健, 陈东丹, 等. 掺稀土光子玻璃近中红外发光与激光[J]. 中国科学:技术科学, 2015, 45(8):809-824. WANG W C, YUAN J, CHEN D D, et al.. Recent advances in rare-earth-doped photonic glasses for near-and mid-infrared lasers[J]. Sci. Sinica Tech., 2015, 45(8):809-824. (in Chinese)

NIAN S J, ZHANG Y, CAO W J, et al.. Optical properties of Er3+/Yb3+ co-doped bismuth calcium borate glass system for NIR lasers and fiber amplifiers[J]. J. Lumin., 2018, 194:440-445.

徐涛, 欧俊, 郑伟华, 等. -NaYF4:Yb,Er/Tm/Ho上转换纳米晶的制备及其水溶性研究[J]. 发光学报, 2015, 36(11):1266-1270. XU T, OU J, ZHENG W H, et al.. Preparation and water solubility of NaYF4:Yb, Er/Tm/Ho up-conversion nanoparticles[J]. Chin. J. Lumin., 2015, 36(11):1266-1270. (in Chinese)

TIAN Y, WEI T, JING X, et al.. Enhanced 2.7-and 2.9-m emissions in Er3+/Ho3+ doped fluoride glasses sensitized by Pr3+ ions[J]. Mater. Res. Bull., 2016, 76:67-71.

AGAWANE G L, LINGANNA K, IN J H, et al.. Thermo-mechanical studies on Er3+-doped fluorophosphate glasses for near infrared lasers[J]. Ceram. Int., 2017, 43:11177-11181.

LIU Y L, SONG F, JIA G Z, et al.. Strong emission in Yb3+/Er3+ co-doped phosphate glass ceramics[J]. Results Phy., 2017:1987-1992.

徐军. 激光材料科学与技术前沿[M]. 上海:上海交通大学出版社, 2007:238-240. XU J. Laser Materials Science and Technology frontier[M]. Shanghai:Shanghai Jiaotong University Press, 2007:238-240. (in Chinese)

LI T, ZHANG Q Y, LIU Y H, et al.. Infrared-to-visible upconversion and 1.53-m emission of Er3+-doped Al(PO3)3-based fluorophosphate glass[J]. Chin. Phys. Lett., 2004, 21(6):1147-1149.

LU Y, CAI M Z, CAO R J, et al.. Ho3+ doped germanate-tellurite glass sensitized by Er3+ and Yb3+ for efficient 2.0 mm laser material[J]. Mater. Res. Bul., 2016, 84:124-131.

OLIVEIRA A S, DE ARAUJO M T, GOUVEIA-NETO A S, et al.. Upconversion fluorescence spectroscopy of Er3+/Yb3+-doped heavy metal Bi2O3-Na2O-NB2O5-GeO2 glass[J]. J. Appl. Phys., 1998, 83(1):604-606.

OHISHI Y, MORI A,YAMADA M, et al.. Tellurite glass, optical amplifier, and light source:US Patent, 6266181[P]. 2001.

LIU Y X, YANG Q B, REN G Z, et al.. Microstructure and up-conversion luminescence properties of Er3+ and Yb3+ ions co-doped oxyfluoride silicates[J]. J. Alloys Compd., 2008, 454:379-383.

RIVERA V A G, BARBOSA L C. Spectroscopic properties of Er3+-doped sodium-modified tellurite glasses for use as optical amplifiers at 1540 nm[J]. J. Lumin., 2014, 156:116-123.

SAJNA M S, THOMAS SUNIL, ANNMARY K A. Spectroscopic properties of Er3+ ions in multicomponent tellurite glasses[J]. J. Lumin., 2015, 159:55-65.

HUANG F F, CHENG J M, LIU X Q, et al.. Ho3+/Er3+ doped fluoride glass sensitized by Ce3+ pumped by 1550 nm LD for efficient 2.0m laser applications[J]. Opt. Express, 2014, 22(17):20924-20935.

SHEN S X, RICHARDS B, JHA A. Enhancement in pump inversion efficiency at 980 nm in Er3+, Er3+/Eu3+ and Er3+/Ce3+ doped tellurite glass fibers[J]. Opt. Express, 2006, 14(12):5050-5054.

ANDRONOV A A, GRISHIN I A, GUR'EV V A, et al.. Enhancement of the luminescence yield of Er3+ ions at =1.54m in ZBLAN glass additionally doped with Eu3+ and Tb3+ and pumped in the range =0.975m[J]. Tec. Phys. Lett., 1998, 24(5):365-366.

SASIKALA T, MOORTHY L R, PAVANI K, et al.. Spectroscopic properties of Er3+ and Ce3+ co-doped tellurite glasses[J]. J. Alloys Compd., 2012, 542(25):271-275.

STROHHFER C, KIK P G, POLMAN A. Selective modification of the Er3+4I11/2 branching ratio by energy transfer to Eu3+[J]. J. Appl. Phys., 2000, 88(8):4486-4490.

TANABE S. Rare-earth-doped glasses for fiber amplifiers in broadband telecommunication[J]. Comptes. Rendus. Chimie., 2002, 5:815-824.

张勤远, 王伟超, 姜中宏. 玻璃态物质的本质[J]. 科学通报, 2016, 61(13):1407-1413. ZHANG Q Y, WANG W C, JIANG Z H. What is the nature of glassy state?[J]. Chin. Sci. Bull., 2016, 61(13):1407-1413. (in Chinese)

张锐. 现代材料分析方法[M]. 北京:化学工业出版社, 2007. ZHANG R. Modern Materials Analysis[M]. Beijing:Chemical Industry Press, 2007. (in Chinese)

BRAGLIA M, KRAUS J, MOSSO S. Core/clad composition with high numerical aperture for single-mode fluoride fibres[J]. J. Non-Cryst. Solids, 1996, 201(3):237-245.

HAQUIN H, VASILIE I, FONTENEAU G, et al.. Optical properties of Er3+-doped fluoride glass channel waveguides[J]. SPIE, 2004, 5350:23-25.

王森, 周亚训, 戴世勋, 等. 掺Er3+碲酸盐玻璃光谱性质和热稳定性的提高研究[J]. 光电工程, 2011, 38(6):93-98. WANG S, ZHOU Y X, DAI S X, et al.. The improvement of spectral properties and thermal stability of Er3+-doped tellurite glasses[J]. Opto-Electron. Eng., 2011, 38(6):93-98. (in Chinese)

曹国喜, 胡和方, 干福熹, 等. BaF2/BaO替代对钡镓锗酸盐玻璃结构的影响[J]. 硅酸盐学报, 2004, 32(11):1381-1388. CAO G X, HU H F, GAN F X, et al.. Effect of BaF2/BaO substitution on the structure of barium gallogermanate glass[J]. J. Chin. Ceram. Soc., 2004, 38(11):1381-1388. (in Chinese)

MCKEOWN D A, MERZBACHER C I. Raman spectroscopic studies of BaO-Ga2O3-GeO2 glasses[J]. J. Non-Cryst. Solids, 1995, 183(1-2):61-72.

张常建, 卢安贤. 二元Li2O-GeO2体系玻璃的结构和锗反常现象[J]. 武汉理工大学学报, 2011, 33(2):22-26. ZHANG C J, LU A X. Cation dependence of structure in alkali germinate glasses[J]. J. Wuhan Univ. Technol., 2011, 33(2):22-26. (in Chinese)

LIN S B, WANG P F, SHE J B, et al.. Spectroscopic and thermal properties of Yb3+ doped TeO2-Bi2O3-NB2O5 based tellurite glasses[J]. J. Lumin., 2014, 153:29-33.

王森, 周亚训, 戴世勋, 等. Er3+/Ce3+共掺碲铋酸盐玻璃的制备及光谱特性提高研究[J]. 物理学报, 2012, 61(10):107802. WANG S, ZHOU Y X, DAI S X, et al.. The fabrication of Er3+/Ce3+ co-doped tellurite-bismuth glasses and the improvement of spectroscopic properties[J]. Acta Phys. Sinica, 2012, 61(10):107802. (in Chinese)

WEI T, CHEN F Z, TIAN Y, et al.. Broadband near-infrared emission property in Er3+/Ce3+ co-doped silica-germanate glass for fiber amplifier[J]. Spectrochim. Acta Part A:Mol. Biomol. Spectrosc., 2014, 126(21):53-58.

YANG J H, ZHANG L Y, WEN L, et al.. Comparative investigation on energy transfer mechanisms between Er3+ and Ce3+ (Eu3+, Tb3+) in tellurite glasses[J]. Chem. Phys. Lett., 2004, 384(4-6):295-298.

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