ZHANG Shuo, LI Long-long, ZHAO Ning etc. Synthesis and Optical Properties of Ketone-formaldehyde Fluorescence Probe[J]. Chinese Journal of Luminescence, 2018,39(9): 1317-1322
ZHANG Shuo, LI Long-long, ZHAO Ning etc. Synthesis and Optical Properties of Ketone-formaldehyde Fluorescence Probe[J]. Chinese Journal of Luminescence, 2018,39(9): 1317-1322 DOI: 10.3788/fgxb20183909.1317.
Synthesis and Optical Properties of Ketone-formaldehyde Fluorescence Probe
4-amino-4-(4-methoxyphenyl) but-3-en-2-one (1b) and 4-amino-4-(1
3-benzodioxol-5-yl) but-3-en-2-one(2b) were synthesized and investigated as a possible fluorescent probe for formaldehyde detection. The linear absorption and fluorescent spectra of 1b and 2b in different formaldehyde concentration were investigated. The results indicate that the compound 1b and 2b have a intricate variation trend existing in UV-Vis absorption spectra and one-photon fluorescence spectra
respectively. In terms of single photon fluorescence
the fluorescence emission peak of compound 1b is located at 384 nm
which is 50 nm red shift compared with UV absorption peak. The fluorescence emission peak of compound 2b consists of two peaks located at 384 nm and 411 nm
respectively. When 15 mol/L of formaldehyde is added
the fluorescence emission peak of the compound 2b is obviously enhanced and the overlap degree of the two peak is reduced
which can be used to detect the characteristics of formaldehyde. These results show that 4-amino-4-(4-methoxyphenyl) but-3-en-2-one(1b) and 4-amino-4-(1
3-benzodioxol-5-yl) but-3-en-2-one(2b) are able to be as a promising candidate for formaldehyde detection.
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