Luminescent Properties of Dy3+, Tm3+ Co-doped Ca2MgSi2O7

doi:10.3788/fgxb20183907.0948

您当前的位置：

首页 >

文章列表页 >

Luminescent Properties of Dy³⁺, Tm³⁺ Co-doped Ca₂MgSi₂O₇

更新时间：2020-08-12

- Luminescent Properties of Dy³⁺, Tm³⁺ Co-doped Ca₂MgSi₂O₇
- Chinese Journal of Luminescence Vol. 39, Issue 7, Pages: 948-954(2018)
- 作者机构：
  
  新疆师范大学物理与电子工程学院, 新疆矿物发光材料及其微结构实验室,新疆乌鲁木齐,830054
- 作者简介：
- 基金信息：
  
  Supported by National Natural Science Foundation of China(11464045,11264040);Xinjiang Mineral Luminescence and Application Key Laboratory Bidding Project(KWFG1706)
- DOI：10.3788/fgxb20183907.0948
  CLC： O482.31
- Received：11 December 2017，
  
  Revised：12 March 2018，
  
  Published Online：23 March 2018，
  
  Published：05 July 2018
- 稿件说明：
移动端阅览
胡莲莲, 艾尔肯·斯地克等. Dy³⁺、Tm³⁺共掺杂Ca₂MgSi₂O₇的发光特性[J]. 发光学报, 2018,39(7): 948-954

HU Lian-lian, AIERKEN Sidike, WAN Ying etc. Luminescent Properties of Dy³⁺, Tm³⁺ Co-doped Ca₂MgSi₂O₇[J]. Chinese Journal of Luminescence, 2018,39(7): 948-954
胡莲莲, 艾尔肯·斯地克等. Dy³⁺、Tm³⁺共掺杂Ca₂MgSi₂O₇的发光特性[J]. 发光学报, 2018,39(7): 948-954 DOI： 10.3788/fgxb20183907.0948.

HU Lian-lian, AIERKEN Sidike, WAN Ying etc. Luminescent Properties of Dy³⁺, Tm³⁺ Co-doped Ca₂MgSi₂O₇[J]. Chinese Journal of Luminescence, 2018,39(7): 948-954 DOI： 10.3788/fgxb20183907.0948.

摘要

采用高温固相法合成了系列Ca

MgSi

：Dy

，Tm

发光材料。对样品进行了XRD结构表征，测量了激发光谱、发射光谱、色温和荧光寿命。研究结果表明，Ca

MgSi

：Tm

在355 nm激发下显示出蓝色发光，在CIE1931中的色坐标为

=0.165 9，

=0.082 2，色纯度为89%。通过Dy

和Tm

的叠加激发谱带激发，即在349，353，365 nm激发下，Ca

MgSi

：Dy

，Tm

显示出青白、冷白和暖白光，相关色温值分别为5 193，9 672，4 685 K。300~500 nm区域间可以有效地激发Ca

MgSi

：Dy

，Tm

，并在400~600 nm之间产生蓝光和黄光复合产生的白光，表明该体系可用作白光LED的发光材料。

Abstract

A series of Ca

MgSi

:Dy

luminescent materials were synthesized by high temperature solid phase method. The samples were characterized by XRD structure

and the excitation spectra

emission spectra

color temperature and fluorescence lifetime were measured. The results show that Ca

MgSi

:Tm

exhibits blue luminescence under the excitation of 355 nm. The color coordinate in CIE1931 is

=0.165 9

=0.082 2

and the color purity is 89%。Excited by the superposition excitation bands of Dy

and Tm

(349

353

365 nm)

MgSi

:Dy

phosphors show bright white

cool white and warm white light

and the correlation color values are 5 193

9 672

4 685 K

respectively. In conclusion

MgSi

:Dy

and Tm

can be effectively excited by 300-500 nm regions and emit white light produced by blue and yellow light combinations between 400-600 nm

shows that the system can be used as a luminescent material for white LED.

关键词

Keywords

references

潘政薇, 何洪, 宋秀峰, 等. LED用稀土Eu掺杂硅酸盐基荧光粉的研究进展[J]. 硅酸盐学报, 2009, 37(9):1590-1596. PAN Z W, HE H, SONG X F, et al.. Research progress of rare earth Eu doped silicate based phosphors for LED[J]. J. Chin. Ceram. Soc., 2009, 37(9):1590-1596. (in Chinese)

陈永虎, 施朝淑. 长余辉材料Sr2MgSi2O7:Eu,Dy中稀土离子的发光特性[J]. 发光学报, 2006, 27(1):41-46. CHEN Y H, SHI Z S. Long persistence material Sr2MgSi2O7 emission characteristics of rare earth ions in Eu and Dy[J]. Chin. J. Lumin., 2006, 27(1):41-46. (in Chinese)

林莹, 高绍康, 王桂美. 新型荧光粉Ca2MgSi2O7:Eu3+的制备及发光特性的研究[C]. 中国化学会学术年会, 长春, 2006. LIN Y, GAO S K, WANG G M. Preparation and luminescent properties of new phosphor Ca2MgSi2O7:Eu3+[C]. Annual Meeting of Chinese Chemical Society, Changchun, 2006. (in Chinese)

夏威, 雷明凯, 罗昔贤, 等. 宽激发带稀土激活碱土金属硅酸盐发光材料特性研究[J]. 光谱学与光谱分析, 2008, 28(1):41-46. XIA W, LEI M K, LUO X X, et al.. Study on characteristics of rare earth activated alkaline earth metal silicate luminescent materials[J]. Spectrosc. Spect. Anal., 2008, 28(1):41-46. (in Chinese)

马红萍. 溶胶-凝胶法制备的Ca2MgSi2O7:Ce,Tb荧光粉的光学特性[J]. 光学学报, 2009, 29(2):432-437. MA H P. Optical properties of Ca2MgSi2O7:Ce, Tb phosphors prepared by a sol-gel method[J]. Acta Opt. Sinica, 2009, 29(2):432-437. (in Chinese)

章少华, 胡江峰, 王建军, 等. Ce3+和Y3+掺杂对Ca2MgSi2O7:Eu2+荧光粉发光性能的影响[J]. 材料导报, 2010, 24(6):8-10. ZHANG S H, HU J F, WANG J J, et al.. Effects of Ce3+and Y3+doping on luminescence properties of Ca2MgSi2O7:Eu2+ phosphors[J]. Mater. Rev., 2010, 24(6):8-10. (in Chinese)

翟永清, 王莉莉, 马健, 等. 微波辅助凝胶燃烧法合成红色荧光粉Ca2MgSi2O7:Eu3+及性质研究[J]. 人工晶体学报, 2013, 42(1):78-83. ZHAI Y Q, WANG L L, MA J, et al.. Synthesis of red phosphor Ca2MgSi2O7:Eu3+ by microwave assisted gel combustion method and its properties[J]. J. Synth. Cryst., 2013, 42(1):78-83. (in Chinese)

ZHANG X Q, DONG L M, TANG X C, et al.. Preparation and luminescent properties of single white Ca2MgSi2O7:Eu3+, Ce3+, Tb3+ phosphor for WLED[J]. Adv. Mater. Res., 2014, 989-994:395-398.

SAHU I P, BISEN D P, BRAHME N, et al.. Enhancement of the photoluminescence and long afterglow properties of Sr2MgSi2O7:Eu2+ phosphorby Dy3+ co-doping[J]. Res. Chem. Intermed., 2015, 42(3):1823-1843.

PANDEY D, BRAHME N, SHARMA R, et al.. Synthesis photoluminescence study of Ca2MgSi2O7:Ce, Dy, Eu micro phosphor[J]. Adv. Phys. Lett., 2016, 3(2):18-23.

KANG F W, HAN J, PENG M Y. Verifying the "controversial" available sites via typical Bi3+ luminescent feature:exemplarily based on the Ca2MgSi2O7:Bi3+ phosphor[J]. Appl. Chem., 2016, 12:1421-1427.

SAHU I P, BISEN D P, BRAHME N, et al.. Luminescence studies of Sr2MgSi2O7:Eu2+, Dy3+ phosphor prepared by solid state reaction method[J]. Int. J. Lumin. Appl., 2015, 5(4):414-422.

ZHANG H, FU X, NIU S, et al.. Blue luminescence of nanocrystalline CaZrO3:Tm phosphors synthesized by a modified Pechini sol-gel method[J]. J. Lumin.. 2008, 128(8):1348-1352.

宋峰, 苏静, 谭浩, 等. 钨酸钇钠晶体中Tm3+的光谱特性[J]. 物理学报, 2004, 53(10):3591-3595. SONG F, SU J, TAN H, et al.. Spectral characteristics of Tm3+ in yttrium tungstate crystal[J]. Acta Phys. Sinica, 2004, 53(10):3591-3595. (in Chinese)

刘金霞, 吕树臣. 纳米晶ZrO2:Tm3+制备与发光性质研究[J]. 人工晶体学报, 2006, 35(5):1129-1132. LUI J X, LU S C. Study on preparation and luminescence properties ofnanocrystalline ZrO2:Tm3+[J]. J. Synth. Cryst., 2006, 35(5):1129-1132. (in Chinese)

刘丽艳, 孙一丹, 于湛, 等. 稀土Dy3+,Tm3+单掺杂的ZnB4O7磷光体的热释光[J]. 应用化学, 2014, 31(7):835-840. LIU L Y, SUN Y D, YU Z, et al.. Thermoluminescence of rare earth Dy3+and Tm3+single doped ZnB4O7 phosphors[J]. Appl. Chem., 2014. 31(7):835-840. (in Chinese)

CALDIO U, LIRA A,MEZA-ROCHA A N, et al.. White light generation in Dy3+and Ce3+/Dy3+doped zinc-sodium-aluminosilicate glasses[J]. J. Lumin., 2015, 167:327-332.

LAKSHMINARAYANA G, YANG H, QIU J. White light emission from Tm3+/Dy3+, co-doped oxyfluoride germanate glasses under UV light excitation[J]. J. Solid State Chem., 2009, 182(4):669-676.

孙家跃, 社海燕, 胡文祥. 固体发光材料[M]. 北京:化学工业出版社, 2003. SUN J Y, DU H Y, HU W X. Solid Luminescent Material[M]. Beijing:Chemical Industry Press, 2003. (in Chinese)

杨志平, 刘鹏飞, 宋延春, 等. 白光LED用Ba3La(PO4)3:Dy3+荧光粉的制备与发光性能[J]. 发光学报, 2013, 34(1):35-39. YANG Z P, LIU P F, CONG Y C, et al.. The preparation and luminescence properties of Ba3La(PO4)3:Dy3+ phosphor powder were used in white LED[J]. Chin. J. Lumin., 2013, 34(1):35-39. (in Chinese)

HAN B, ZHANG J, LI P J, et al.. KBaBP2O8:Tm3+ a novel blue-emitting phosphor with high color purity[J]. Jetp Lett., 2014, 99(10):561-564.

FERHI M, HORCHANI-NAIFER K, FRID M. Hydrothermal synthesis and photoluminescence of the monophosphate LaPO4:Eu(5%)[J]. J. Lumin., 2008, 128(11):1777-1782.

HE H, FU R, SONG X, et al.. Observation of fluorescence and phosphorescence in Ca2MgSi2O7:Eu2+, Dy3+ phosphors[J]. J. Electrochem. Soc., 2010, 157(3):J69-J73.

赵谡玲, 侯延冰, 徐征. 不同波长激发下YLiF4:Er3+,Tm3+,Yb3+的发光[J]. 发光学报, 2006, 27(2):191-195. ZHAO J L, HOU Y B, XU Z. Luminescence of YLiF4:Er3+,Tm3+and Yb3+ excited by different wavelengths[J]. Chin. J. Lumin., 2006, 27(2):191-195. (in Chinese)

王齐祖, 田军, 杨晓鸿, 等. Tb3+,Dy3+激活的LaBO3的发光和能量传递[J]. 发光学报, 1995, 16(1):57-62. WANG Q J, TIAN J, YANG X H, et al.. Luminescence and energy transfer of the activated[J]. Chin. J. Lumin., 1995, 16(1):57-62. (in Chinese)

MEZA-ROCHA A N, SPEGHINI A, LOZADA-MORALES R, et al.. Blue and white light emission in Tm3+, and Tm3+/Dy3+, doped zinc phosphate glasses upon UV light excitation[J]. Opt. Mater., 2016, 58:183-187.

BLASSE G, GRABMAIER B C. Luminescent Materials[M]. Berlin:Springer-Verlag, 1994:95.

Views

166

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Luminescence Properties of Eu³⁺， Dy³⁺， Na⁺ Doped Sr₃AlO₄F

Research Progress in Photoluminescent Aerogels

Preparation and Characterization of Zn²⁺-doped MgGa₂O₄∶Ni²⁺ NIR-Ⅱ Phosphors and Their Application in Imaging

Localization Features of Carrier Emission Recombination in Deep-ultraviolet AlGaN-based Multiple Quantum Well Structure

Photoluminescence Properties of Sr₆Lu₂Al₄O₁₅∶Tb³⁺ Phosphor

Related Author

LIANG Ruihan

ZHAO Huiming

ZHANG Yanji

LI Wenxia

MI Xiaoyun

CHEN Xiumei

LI Xingyu

YUAN Ze

Related Institution

Research Institute of Changchun University of Science and Technology in Chongqing

School of Materials Science and Engineering， Changchun University of Science and Technology

School of Flexible Electronics（Future Technologies） & Institute of Advanced Materials（IAM）， Nanjing Tech University

School of Physics， Northeast Normal University

Institute of Novel Semiconductors， School of Microelectronics， Shandong University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰