Preparation of Er,Yb: (LaLu)2O3 Ceramic and Its Upconversion Luminescent Properties

DAI Yu-hang; LI Jian; ZHANG Ying; ZHU Zhong-li

doi:10.3788/fgxb20183904.0488

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Preparation of Er,Yb: (LaLu)₂O₃ Ceramic and Its Upconversion Luminescent Properties

更新时间：2020-08-12

- Preparation of Er,Yb: (LaLu)₂O₃ Ceramic and Its Upconversion Luminescent Properties
- Chinese Journal of Luminescence Vol. 39, Issue 4, Pages: 488-493(2018)
- 作者机构：
  
  1. 中国科学院长春光学精密机械与物理研究所, 吉林长春 130033
  2. 长春理工大学化学与环境工程学院, 吉林长春 130022
- 作者简介：
- 基金信息：
  
  Supported by Jilin Province Science and Technology Development Project(20170204028GX
- DOI：10.3788/fgxb20183904.0488
  CLC： O482.31
- Received：23 August 2017，
  
  Revised：10 November 2017，
  
  Published Online：27 November 2017，
  
  Published：05 April 2018
- 稿件说明：
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代雨航, 李剑, 张莹等. Er,Yb：(LaLu)2O3透明陶瓷制备及上转换发光性能[J]. 发光学报, 2018,39(4): 488-493

DAI Yu-hang, LI Jian, ZHANG Ying etc. Preparation of Er,Yb: (LaLu)2O3 Ceramic and Its Upconversion Luminescent Properties[J]. Chinese Journal of Luminescence, 2018,39(4): 488-493
代雨航, 李剑, 张莹等. Er,Yb：(LaLu)2O3透明陶瓷制备及上转换发光性能[J]. 发光学报, 2018,39(4): 488-493 DOI： 10.3788/fgxb20183904.0488.

DAI Yu-hang, LI Jian, ZHANG Ying etc. Preparation of Er,Yb: (LaLu)2O3 Ceramic and Its Upconversion Luminescent Properties[J]. Chinese Journal of Luminescence, 2018,39(4): 488-493 DOI： 10.3788/fgxb20183904.0488.

摘要

采用柠檬酸燃烧法制备Er，Yb：（LaLu）

陶瓷粉体，用X射线衍射对其进行了物相鉴定，研究表明1 000℃时已经得到纯相的（LaLu）

。采用冷等静压-真空烧结法制备了Er，Yb：（LaLu）

和Er：（LaLu）

陶瓷，对陶瓷的结构和光谱性能进行了详细的研究，研究发现掺杂5% Yb

和10% La

样品的上转换发光强度与未掺Yb

、La

样品相比明显增大，根据上转换光谱显示较强发射峰位于564 nm和661 nm处，对应Er

的

3/2

（

11/2

）

15/2

能级跃迁和

9/2

15/2

能级跃迁，并讨论了Er

-Yb

的能量传递过程及其上转换发光机制。

Abstract

Yb:(LaLu)

ceramic powders were prepared

via

citric combustion method. XRD patterns show that the production prepared at 1 000℃ is pure phase of (LaLu)

. Er

Yb:(LaLu)

and Er:(LaLu)

ceramic was synthesized by cold isostatic-vacuum sintering method. The structural and spectroscopic properties of the ceramics were investigated in detail. The upconversion emission increases obviously when 5% Yb

and 10% La

are doped in the ceramic compared with the samples without Yb

and La

doping. The upconversion fluorescence spectra show that the intense green and red emissions located at around 564 nm and 661 nm are attributed to the radiant transitions of

3/2

(

11/2

)

15/2

and

9/2

15/2

of Er

respectively. The energy transfer process and upconversion luminescence mechanism of Er

-Yb

in co-doped system were studied.

关键词

Keywords

references

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