Preparation and Luminescence Properties of Lu2O3: Pr3+ Phosphors Codoped with Li+, Na+, K+, Ca2+, Ba2+ Ions

TUO Juan; WANG Lin-xiang; YE Ying; ZHAO Hai-qin

doi:10.3788/fgxb20183903.0307

您当前的位置：

首页 >

文章列表页 >

Preparation and Luminescence Properties of Lu₂O₃: Pr³⁺ Phosphors Codoped with Li⁺, Na⁺, K⁺, Ca²⁺, Ba²⁺ Ions

更新时间：2020-08-12

- Preparation and Luminescence Properties of Lu₂O₃: Pr³⁺ Phosphors Codoped with Li⁺, Na⁺, K⁺, Ca²⁺, Ba²⁺ Ions
- Chinese Journal of Luminescence Vol. 39, Issue 3, Pages: 307-314(2018)
- 作者机构：
  
  1. 新疆师范大学物理与电子工程学院,新疆乌鲁木齐,830054
  2. 新疆师范大学新疆矿物发光材料及其微结构实验室,新疆乌鲁木齐,830054
  3. 新疆师范大学重点学科物理学,新疆乌鲁木齐,830054
- 作者简介：
- 基金信息：
  
  Supported by Natural Science Foundation of Xinjiang (2017D01A60);Foundation of Key
- DOI：10.3788/fgxb20183903.0307
  CLC： O482.31
- Received：19 August 2017，
  
  Revised：08 November 2017，
  
  Published Online：23 November 2017，
  
  Published：05 March 2018
- 稿件说明：
移动端阅览
庹娟, 王林香, 叶颖等. 金属离子Li+,Na+,K+,Ca2+,Ba2+掺杂Lu2O3∶Pr3+荧光粉的制备及发光特性研究[J]. 发光学报, 2018,39(3): 307-314

TUO Juan, WANG Lin-xiang, YE Ying etc. Preparation and Luminescence Properties of Lu2O3: Pr3+ Phosphors Codoped with Li+, Na+, K+, Ca2+, Ba2+ Ions[J]. Chinese Journal of Luminescence, 2018,39(3): 307-314
庹娟, 王林香, 叶颖等. 金属离子Li+,Na+,K+,Ca2+,Ba2+掺杂Lu2O3∶Pr3+荧光粉的制备及发光特性研究[J]. 发光学报, 2018,39(3): 307-314 DOI： 10.3788/fgxb20183903.0307.

TUO Juan, WANG Lin-xiang, YE Ying etc. Preparation and Luminescence Properties of Lu2O3: Pr3+ Phosphors Codoped with Li+, Na+, K+, Ca2+, Ba2+ Ions[J]. Chinese Journal of Luminescence, 2018,39(3): 307-314 DOI： 10.3788/fgxb20183903.0307.

摘要

用高温固相法制备了Lu

∶

与Lu

∶0.1% Pr

，

（

=Li

，Na

，K

，Ca

，Ba

）荧光粉。用XRD对其结构进行表征，测量了激发光谱、发射光谱和发光衰减曲线，分析了金属离子Li

、Na

、K

、Ca

、Ba

掺杂对Lu

∶Pr

样品发光强度及荧光寿命的影响。结果显示：掺杂金属离子后的样品仍为纯Lu

立方晶相结构；与Lu

∶0.1% Pr

样品在632 nm处的发光强度比较，分别掺杂12%的Li

、8%的Na

、8%的K

获得样品的发光强度提高了7.32，4.11，2.55倍，掺杂了Ca

和Ba

的样品发光强度均减弱；与Lu

∶0.1% Pr

样品荧光寿命比较，掺杂Li

、Na

、K

、Ca

、Ba

获得的样品

能级荧光寿命均缩短。

Abstract

and Lu

:0.1%Pr

(

=Li

) phosphors were synthesized by the high temperature solid-state reaction. The structures of the samples were characterized by XRD

the excitation spectra

emission spectra and luminescence decay curves of the samples were measured. The influences of the doping metal ions of Li

and Ba

on the microstructure

luminescence intensity and fluorescence lifetime for synthesized samples of Lu

:Pr

were researched. The results show that the samples after doping metal ions are still pure Lu

cubic crystal phase structure. The emission intensities of Lu

:0.1%Pr

samples doped with 12%Li

8%Na

and 8%K

increased 7.32

4.11 and 2.55 times than that of Lu

:0.1%Pr

sample

but the emission intensities of samples doped with Ca

and Ba

decreased. Compared with

fluorescence lifetime of Lu

:0.1%Pr

sample

the lifetime of the samples codoped with Li

all decreased.

关键词

Keywords

references

陈向阳, 张志军, 赵景泰. 闪烁材料探索科学世界的一扇窗[J]. 自然杂志, 2015, 37(3):165-174. CHEN X Y, ZHANG Z J, ZHAO J T. Scintillator:a window to explore mysterious scientific world[J]. Chin. J. Nature, 2015, 37(3):165-174. (in Chinese)

洪广言. 稀土发光材料的研究进展[J]. 人工晶体学报, 2015, 44(10):2641-2651. HONG G Y. Research progress of rare earth luminescent materials[J]. J. Synth. Cryst., 2015, 44(10):2641-2651. (in Chinese)

KIM W, BAKER C, BOWMAN S, et al.. Laser oscillation from Ho3+ doped Lu2O3 ceramics[J]. Opt. Mater. Express, 2013, 3(7):913-919.

PRAKASAM M, VIRAPHONG O, MICHAU D, et al.. Critical parameters to obtain Yb3+ doped Lu2O3, and ZnO transparent ceramics[J]. Ceram. Int., 2014, 40(1):1859-1864.

DE JESS MORALES-RAMREZ, GARCA-MURILLO A, CARRILLO-ROMO F D J, et al.. Influence of annealing temperature on structural and optical properties of Lu2O3:Eu3+,Tb3+, transparent films[J]. Mater. Res. Bull., 2015, 70:173-178.

王鹏贺, 王能利, 张希艳. 碳酸盐共沉淀法合成Lu2O3:Er3+纳米粉体及性能表征[J]. 无机化学学报, 2012, 28(11):2335-2340. WANG P H, WANG N L, ZHANG X Y. Carbonate co-precipitation synthesis of Lu2O3:Er3+ nano-powders and its property[J]. Chin. J. Inorg. Chem., 2012, 28(11):2335-2340. (in Chinese)

TROJANPIEGZA J, ZYCH E, HLS J, et al.. Spectroscopic properties of persistent luminescence phosphors:Lu2O3:Tb3+,M2+(M=Ca, Sr, Ba)[J]. J. Phys. Chem. C, 2009, 113(47):20493-20498.

MORALES RAMREZ A, GARCA HERNNDEZ M, YEPEZ VILA J, et al.. Eu3+, Bi3+ codoped Lu2O3 nanopowders:synthesis and luminescent properties[J]. J. Mater. Res., 2013, 28(10):1365-1371.

XIE J, DENG L, SHI Y, et al.. The influence of Pr3+, co-doping on the luminescent properties of Lu2O3:5mol% Eu films[J]. J. Lumin., 2011, 131(5):970-974.

KRSMANOVIC R, ANTIC Z, ZEKOVIC I, et al.. (Y0.5Lu0.5)2O3:Eu3+ nanopowders:combustion synthesis, structure and optical properties[J]. Radiat. Meas., 2010, 45(3-6):438-440.

YANG J, LI C, QUAN Z, et al.. Self-assembled 3D flowerlike Lu2O3 and Lu2O3:Ln3+ (Ln=Eu, Tb, Dy, Pr, Sm, Er, Ho, Tm) microarchitectures:ethylene glycol-mediated hydrothermal synthesis and luminescent properties[J]. J. Phys. Chem. C, 2008, 112(33):12777-12785.

洪广言. 稀土发光材料-基础与应用[M]. 北京:科学出版社, 2011. HONG G Y. Rare Earth Luminescent Materials-Foundation and Application[M]. Beijing:Science Press, 2011. (in Chinese)

徐会兵, 庄卫东, 胡运生, 等. 碱金属离子掺杂对(Y,Gd)BO3:Tb绿色荧光粉性能的影响[C]. 2010年全国冶金物理化学学术会议论文集, 中国, 马鞍山, 2010:268-272. XU H B, ZHUANG W D, HU Y S, et al.. Influence of alkaline metal Ions doping on properties of (Y,Gd)BO3:Tb[C]. Proceedings of The National Conference on Metallurgy and Physical Chemistry in 2010, Maanshan, China, 2010:268-272. (in Chinese)

刘冰洁, 顾牡, 刘小林, 等. Li+, Zn2+共掺杂对Gd2O3:Eu3+纳米粉结构和发光性能的影响[J]. 中国稀土学报, 2007, 25(2):162-166. LIU B J, GU M, LIU X, et al.. Effect of Li+ and Zn2+ co-doping on luminescent properties of Gd2O3:Eu3+ nanoparticles[J]. J. Chin. Soc. Rare Earths, 2007, 25(2):162-166. (in Chinese)

ALARCN-FLORES G, GARCA-HIPOLITO M, AGUILAR-FRUTIS M, et al.. Synthesis and characterization of Y2O3:Pr3+, phosphor powders by simple solvent evaporation[J]. Ceram. Int., 2015, 41(1):743-748.

JIA D, WANG X J, YEN W M. Ground-state measurement of Pr3+ in Y2O3 by photoconductivity[J]. Phys. Solid State, 2008, 50(9):1674-1676.

PASCUAL J L, BARANDIARN Z, SEIJO L. Ab initio theoretical study of luminescence properties of Pr3+ doped Lu2O3[J]. Theoret. Chem. Accounts, 2011, 129(3):545-554.

刘广生, 丁玲红, 张伟风. Na+离子掺杂Gd2O3:Sm3+纳米晶的发光增强[J]. 发光学报, 2010, 31(5):706-711. LIU G S, DING L H, ZHANG W F. Enhanced photoluminescence of Na+-doped Gd2O3:Sm3+ nanocrystals[J]. Chin. J. Lumin., 2010, 31(5):706-711. (in Chinese)

蒲勇, 朱达川, 韩涛. 蓝光激发白光LED用深红色荧光粉Ca1-x-yWO4:xPr3+, yLi+的制备与表征[J]. 发光学报, 2012, 33(1):12-16. PU Y, ZHU D C, HAN T. Preparation and characterization of Ca1-x-yWO4:xPr3+,yLi+ deep red phosphors for white LEDs excited by blue light[J]. Chin. J. Lumin., 2012, 33(1):12-16. (in Chinese)

郑贤火. 非稀土金属离子掺杂对氧化钇粉末荧光性能的影响[D]. 杭州:浙江理工大学, 2016. ZHENG X H. Effects of Non-rare-earth Metal Ions Doping on The Fluorescent Properties of Yttrium Oxide Powder[D]. Hangzhou:Zhejiang University of Technology, 2016. (in Chinese)

杨明珠. 稀土掺杂钇氧化物的发光性能研究[D]. 哈尔滨:哈尔滨工业大学, 2010. YANG M Z. Optic Properties of Yttrium Oxide Doped with Rare Earth Ions[D]. Harbin:Harbin Institute of Technology, 2010. (in Chinese)

LI W, LEE J. Microwave-assisted sol-gel synthesis and photoluminescence characterization of LaPO4:Eu3+, Li+ nanophosphors[J]. J. Phys. Chem. C, 2008, 112(31):11679-11684.

肖莉红, 顾牡, 刘小林, 等. Zn2+掺杂对GdTaO4:Eu3+荧光粉结构和发光性能的影响[J]. 光谱学与光谱分析, 2007, 27(6):1054-1057. XIAO L H, GU M, LIU X L, et al.. Effects of Zn2+ doping on the structural and luminescent properties of GdTaO4:Eu3+ phosphors[J]. Spectrosc. Spect. Anal., 2007, 27(6):1054-1057. (in Chinese)

金海杰, 田莲花. Li+离子掺杂对红色发光材料Y2(W,Mo)O6:Eu3+发光性能的影响[J]. 发光学报, 2011, 32(5):451-455. JIN H J, TIAN L H. Photoluminescence properties of Y2(W,Mo)O6:Eu3+ incorporated with Li+ ions[J]. Chin. J. Lumin., 2011, 32(5):451-455. (in Chinese)

陈文驹, 林美荣, 姜宏丽. 双指数荧光衰减动力学模型分析[J]. 光学学报, 1986, 6(12):1124-1129. CHEN W J, LIN M R, JIANG H L. Study on dynamic model of double exponential fluorescence decay[J]. Acta Opt. Sinica, 1986, 6(12):1124-1129. (in Chinese)

李艳红, 张永明, 李鹏, 等. YVO4:Eu3+纳米晶的沉淀合成及发光性质[J]. 功能材料与器件学报, 2010, 16(1):73-76. LI Y H, ZHANG Y M, LI P, et al.. Synthesis of YVO4:Eu3+ nanocrystals by a precipitation method and luminescence properties[J]. J. Funct. Mater. Dev., 2010, 16(1):73-76. (in Chinese)

伏振兴, 刘碧蕊. La1-xYO3:xPr3+荧光粉的溶液燃烧法合成及发光特性[J]. 光子学报, 2015, 44(8):0816003. FU Z X, LIU B R. Photoluminescence properties and preparation of La1-xYO3:xPr3+ phosphors by solution-combustion[J]. Acta Photon. Sinica, 2015, 44(8):0816003. (in Chinese)

付作岭, 董晓睿, 盛天琦, 等. 纳米晶体中稀土离子的发光性质及其变化机理研究[J]. 中国光学, 2015, 8(1):139-144. FU Z L, DONG X R, SHENG T Q, et al.. Luminescene properties and various mechanisms of rare earth ions in the nanocrystals[J]. Chin. Opt., 2015, 8(1):139-144. (in Chinese)

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Preparation and Photoluminescence Properties of CaLuBO₄: Tb³⁺ Phosphor

Effect of Eu²⁺ Concentration on The Thermal Quenching Mechanism of Sr₂Si₅N₈:Eu²⁺ Red Phosphors

Research Progress in Artificial Micro-nano Structures Enhanced Photoluminescence

Luminescence Properties and Application of Ce³⁺ Doped Ba₃Y₂(BO₃)₄ Phosphor

Methods for Evaluating Hydrolytic Degradation of Mn⁴⁺-activated Fluoride Phosphors

Related Author

SUN Xiao-yuan

FAN Xiao-xuan

HE Jun-jie

LYU Qi-song

JIANG Guang-yuan

DENG Yun

LUO Yong-shi

WU Chun-lei

Related Institution

Department of Physics, Changchun Normal University, Changchun 130032, China

State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences

Faculty of Science, Mudanjiang Normal University

National Engineering Research Center for Rare Earth Materials, General Research Institute for Nonferrous Metals

GRIREM Advanced Materials Co., Ltd.

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰