Study on Phase Transition Properties of VO2 Based on Pump-probe Technique

HOU Dian-xin; LU Yuan; FENG Yun-song; DOU Xian-an; LIU Zhi-wei

doi:10.3788/fgxb20183902.0140

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Study on Phase Transition Properties of VO₂ Based on Pump-probe Technique

更新时间：2020-08-12

- Study on Phase Transition Properties of VO₂ Based on Pump-probe Technique
- Chinese Journal of Luminescence Vol. 39, Issue 2, Pages: 140-147(2018)
- 作者机构：
  
  1. 脉冲功率激光技术国家重点实验室,安徽合肥,230037
  2. 电子工程学院,安徽合肥,230037
  3. 红外与低温等离子体安徽省重点实验室,安徽合肥,230037
- 作者简介：
- 基金信息：
  
  Supported by National Science Fund for Distinguished Young Scholars of China (614052
- DOI：10.3788/fgxb20183902.0140
  CLC： O434.14
- Received：10 May 2017，
  
  Revised：17 August 2017，
  
  Published Online：21 August 2017，
  
  Published：05 February 2018
- 稿件说明：
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侯典心, 路远, 冯云松等. 采用泵浦探测技术研究VO2薄膜相变特性[J]. 发光学报, 2018,39(2): 140-147

HOU Dian-xin, LU Yuan, FENG Yun-song etc. Study on Phase Transition Properties of VO2 Based on Pump-probe Technique[J]. Chinese Journal of Luminescence, 2018,39(2): 140-147
侯典心, 路远, 冯云松等. 采用泵浦探测技术研究VO2薄膜相变特性[J]. 发光学报, 2018,39(2): 140-147 DOI： 10.3788/fgxb20183902.0140.

HOU Dian-xin, LU Yuan, FENG Yun-song etc. Study on Phase Transition Properties of VO2 Based on Pump-probe Technique[J]. Chinese Journal of Luminescence, 2018,39(2): 140-147 DOI： 10.3788/fgxb20183902.0140.

摘要

为研究纳秒激光作用下的VO

薄膜的相变特性，采用泵浦-探测技术进行实验。首先，利用直流磁控溅射法制备VO

薄膜，经X射线衍射（XRD）和原子力显微镜（AFM）分析表明样品质量较高。然后，测量VO

薄膜在波长532 nm处的透过率随温度的变化情况，发现透过率随温度升高由32%上升到37%，与红外波段完全相反。在此基础上，选择1 064 nm泵浦光和532 nm探测光研究激光参数中能量密度和重频对VO

薄膜相变特性的影响，同时结合ANSYS有限元软件对纳秒激光作用下VO

薄膜的单脉冲温升情况进行分析。结果表明：VO

薄膜在大于30 mJ/cm

的纳秒激光能量密度作用下，单脉冲温升可达相变温度，最小相变响应时间在14 ns左右。进一步提高纳秒激光能量密度，其相变响应时间略有增加但变化不大。在100 Hz以内改变纳秒激光重频对VO

薄膜的相变响应基本无影响。VO

薄膜的相变恢复时间随着纳秒激光能量密度的增大而呈自然指数增加，其变化过程与基底材料和纳秒激光参数密切相关。因此，可以通过优化VO

薄膜基底材料参数提高其激光防护效果。

Abstract

The phase transition properties of VO

thin films irradiated by nanosecond laser were researched using the pump-probe method. At first

thin films were successfully deposited by DC magnetron sputtering method

and the samples were identified as high quality thin films by analysis of (X-ray diffraction)XRD and (Atomic force microscope)AFM. Then

the transmittance of vanadium oxide thin films at the wavelength of 532 nm with temperature change was measured. It is found that the transmittance increases from 32% to 37% with the temperature going up

which is completely opposite to the situation in infrared band. On this basis

we chose 1 064 nm pump laser and 532 nm probe laser to research the effect of nanosecond laser parameters

energy density and repeat frequency

on the phase transition properties of VO

. In addition

the ANSYS software is also used to analyze the per pulse heating range of VO

thin films under nanosecond laser. The results suggest that the per pulse heating can reach the phase transition temperature of VO

when the nanosecond laser energy density is more than 30 mJ/cm

. The response time increases slightly with the increase of the nanosecond laser energy density

and the minimum response time is around 14 ns. The repetition frequency of nanosecond laser within 100 Hz has no obvious effect on the phase transition response of VO

thin films. The recovery time varies with nanosecond laser energy according to natural exponential law

and it correlates closely with substrate material and nanosecond laser parameters. We can improve the laser protection effect by optimizing the substrate material parameters of VO

thin film.

关键词

Keywords

references

MORIN F J. Oxide which show a metal-insulator transition at the neel temperature[J]. Phys. Rev. Lett., 1959, 13(1):34-36.

SRI S, SAI L, KUMAR V, et al.. Study of nolinear optical properties of soidium dopded V2O5 nano particles[J]. Int. J. Nanotechnol. Appl., 2014, 4(3):21-28.

GOODENOUGH J B. The two components of the crystal graphic transition in VO2[J]. Solid State Chem., 1971, 3:490-500.

徐凯, 路远, 凌永顺, 等. 氧化热处理对VO2薄膜红外光学相变特性的影响[J]. 激光与红外, 2015, 45(1):53-57. XU K, LU Y, LING Y S, et al.. Effects of oxidational annealing on infrared optical phase transition properties of VO2 thin films[J]. Laser & Infrared, 2015, 45(1):53-57. (in Chinese)

苟君. 基于氧化钒微测辐射热计的室温太赫兹探测器研究[D]. 成都:电子科技大学, 2014. GOU J. Research on Room Temperature Terahertz Detector Based on VOX Micro Bolometer[D]. Chengdu:University of Electronic Science and Technology of China, 2014. (in Chinese)

孙丹丹, 陈智, 文崎业, 等. 二氧化钒薄膜低温制备及其太赫兹调制特性研究[J]. 物理学报, 2013, 62(1):1-5. SUN D, CHEN Z, WEN Q Y, et al.. VO2 low temperature deposition and terahertz transmission modulation[J]. Acta Phys. Sinica, 2013, 62(1):1-5. (in Chinese)

韦晓莹. 氧化钒半导体功能薄膜的光电特性及其应用基础研究[D].天津:天津大学, 2014. WEI X Y. Optical and Electric Characteristic of Semiconductor Functional Films of Vanadium Oxide and Its Application[D]. Tianjin:Tianjin University, 2014. (in Chinese)

王雅琴, 姚刚,黄子健, 等. 用于红外激光防护的高开关率VO2 薄膜[J]. 物理学报, 2016, 65(5):057102-1-6. WANG Y Q, YAO G, HUANG Z J, et al.. Infrared laser protection of multi-wavelength with high optical switching efficiency VO2 film[J]. Acta Phys. Sinica, 2016, 65(5):057102-1-6. (in Chinese)

马德跃, 李晓霞, 郭宇翔, 等. 非线性高能激光防护材料研究进展[J]. 激光与红外, 2014, 44(6):593-597. MA D Y, LI X X, GUO Y X, et al.. Research progress in nonlinear protective materials against high energy laser[J].Laser & Infrared, 2014, 44(6):593-597. (in Chinese)

TRTICA M S, GAKOVIC B M, RADAK B.B, 等. 纳秒、皮秒和飞秒激光脉冲对材料表面的改性[J]. 光学精密工程, 2011, 19(2):221-227. TRTICA M S, GAKOVIC B M, RADAK B B, et al.. Material surface modification by ns, ps and fs laser pulses[J]. Opt. Precision Eng., 2011, 19(2):221-227. (in English)

LYSENKO S, RUA A J, VIKHIN V, et al.. Light-induced ultrafast phase transition in VO2 thin films[J].Appl. Surf. Sci., 2006, 252:5512-5515.

李宏哲, 盛传祥, 厉申博, 等. 纳秒激光作用下二氧化钒薄膜的相变特性[J]. 强激光与粒子束, 2015, 27(5):059001-1-5. LI H Z, SHENG C X, LI S B, et al.. Phase transition properties of vanadium oxide thin films irradiated by nanosecond laser[J]. High Power Laser and Particle Beams, 2015, 27(5):059001-1-5. (in Chinese)

徐凯, 路远, 凌永顺, 等. 脉冲激光辐照下VO2薄膜温升的有限元分析[J]. 光子学报, 2015, 44(5):1-6. XV K, LU Y, LING Y S, et al.. Finite element analysis of temperature rising in VO2 thin films under irradiation of CO2 pulse laser[J]. Acta Photon. Sinica, 2015, 44(5):1-6. (in Chinese)

BRUNCO D P, KITTL J A, OTICS C E, et al.. Time-resolved temperature measurements during pulsed laser irradation using thin film metal thermometers[J]. Rev. Sci. Instrum., 1993, 64(9):2615-2623.

CAVALLERI A, TOTH C, SIDERS C W, et al.. Femtosecond structural dynamics in VO2 during an ultrafast solid-solid phase transition[J]. Phys. Rev. Lett., 2001, 87:237401.

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