Luminescence and Optical Temperature Sensing Properties of NaY(MoO4)2:Er3+ Nanocrystalline Phosphor

SUN Ying-fei; LYU Shu-chen; MENG Qing-yu; QU Xiu-rong

doi:10.3788/fgxb20173812.1582

您当前的位置：

首页 >

文章列表页 >

Luminescence and Optical Temperature Sensing Properties of NaY(MoO₄)₂:Er³⁺ Nanocrystalline Phosphor

更新时间：2020-08-12

- Luminescence and Optical Temperature Sensing Properties of NaY(MoO₄)₂:Er³⁺ Nanocrystalline Phosphor
- Chinese Journal of Luminescence Vol. 38, Issue 12, Pages: 1582-1590(2017)
- 作者机构：
  
  哈尔滨师范大学光电带隙材料省部共建教育部重点实验室,黑龙江哈尔滨,150025
- 作者简介：
- 基金信息：
  
  Supported by Harbin Innovative Talent in Science and Technology Research Special Fun
- DOI：10.3788/fgxb20173812.1582
  CLC： O482.31
- Received：01 June 2017，
  
  Revised：25 July 2017，
  
  Published Online：16 August 2017，
  
  Published：05 December 2017
- 稿件说明：
移动端阅览
孙英斐, 吕树臣, 孟庆裕等. NaY(MoO4)2:Er3+纳米晶体荧光粉的发光与光学温度传感特性[J]. 发光学报, 2017,38(12): 1582-1590

SUN Ying-fei, LYU Shu-chen, MENG Qing-yu etc. Luminescence and Optical Temperature Sensing Properties of NaY(MoO4)2:Er3+ Nanocrystalline Phosphor[J]. Chinese Journal of Luminescence, 2017,38(12): 1582-1590
孙英斐, 吕树臣, 孟庆裕等. NaY(MoO4)2:Er3+纳米晶体荧光粉的发光与光学温度传感特性[J]. 发光学报, 2017,38(12): 1582-1590 DOI： 10.3788/fgxb20173812.1582.

SUN Ying-fei, LYU Shu-chen, MENG Qing-yu etc. Luminescence and Optical Temperature Sensing Properties of NaY(MoO4)2:Er3+ Nanocrystalline Phosphor[J]. Chinese Journal of Luminescence, 2017,38(12): 1582-1590 DOI： 10.3788/fgxb20173812.1582.

摘要

采用熔盐法制备了不同煅烧温度的NaY（MoO

）

：Er

荧光粉材料，样品的晶体结构与微观形貌由X射线衍射仪和场发射扫描电镜测得。Er

掺杂的NaY（MoO

）

纳米晶体的斯托克斯荧光发射光谱是在不同煅烧温度下测得的。NaY（MoO

）

：Er

荧光粉材料的两个能级

11/2

15/2

和

3/2

15/2

跃迁的发射强度比随煅烧温度的增加而减小。NaY（MoO

）

：Er

荧光粉材料的温度传感特性依赖于Er

的两个热耦合能级

11/2

15/2

和

3/2

15/2

的发射强度。研究表明，在一个相对大的传感温度范围（303~573 K），600℃煅烧的样品的温度传感灵敏度比900℃煅烧的样品高，样品的温度传感灵敏度随煅烧温度的增加而减小，600℃煅烧的样品的温度传感灵敏度为1.3610

-2

-1

，比900℃煅烧的样品高76.6%。最后，解释了基于不同煅烧温度的温度传感灵敏度的物理机制。

Abstract

The NaY(MoO

)

:Er

phosphors derived at different calcination temperatures were prepared by molten salt method and the crystal structure and microscopic morphology were characterized by means of X-ray diffraction(XRD) and field emission scanning electron microscopy (FE-SEM). The Stokes fluorescence emission spectra of nanocrystals derived at different calcination temperatures have been measured. It can be found that the emission intensity ratio of

11/2

15/2

3/2

15/2

transitions from NaY(MoO

)

:Er

increases with the decrease of the calcination temperature. Furthermore

the temperature sensing properties of NaY(MoO

)

:Er

phosphors were studied based on the emission intensities from two thermally coupled

11/2

and

3/2

levels of Er

. The results show that the temperature sensing sensitivity of the sample calcinated at 600℃ is somewhat higher than that of the sample calcinated at 900℃in a relatively wide range of sensing temperature (303-573 K). The sensing sensitivity increases with the decreasing of the calcination temperature

and a relative high sensitivity of 1.3610

-2

-1

is obtained for the sample calcinated at 600℃

which is about 76.6% higher than that of the sample obtained at 900℃. Finally

the physical mechanism for the calcination temperature-dependence of temperature sensing sensitivity was explained and predicted.

关键词

Keywords

references

TUAN P V, LE T H, NGA L Q, et al.. Hydrothermal synthesis and characteristic photoluminescence of Er-doped SnO2 nano-particles[J]. Physica B, 2016, 501:34-37.

SUN Y J, ZHAO Z T, LI P W, et al.. Er-doped ZnO nanofibers for high sensibility detection of ethanol[J]. Appl. Surf. Sci., 2015, 356:73-80.

WU X, CHI M L, KWOK K W. Effect of phase transition on photoluminescence of Er-doped KNN ceramics[J]. J. Lumin., 2015, 155:343-350.

WANG X S, ZHANG J B, WANG L Y, et al.. High response gas sensors for formaldehyde based on Er-doped In2O3 nanotubes[J]. J. Mater. Sci. Technol., 2015, 31:1175-1180.

ZHENG H, CHEN B J, YU H Q, et al.. Temperature sensing and optical heating in Er3+ single-doped and Er3+/Yb3+ codoped NaY(WO4)2 particles[J]. RSC Adv., 2014, 4:47556-47563.

LEN-LUIS S F, RODRGUEZ-MENDOZA U R, HARO-GONZLEZ P, et al.. Role of the host matrix on the thermal sensitivity of Er3+ luminescence in optical temperature sensors[J]. Sens. Actuators B: Chem., 2012, 174:176-186.

TIAN Y, TIAN B N, CUI C E, et al.. Size-dependent upconversion luminescence and temperature sensing behavior of spherical Gd2O3:Yb3+/Er3+ phosphor[J]. RSC Adv., 2015, 5:14123-14128.

VETRONE F, NACCACHE R, ZAMARRO A N, et al.. Temperature sensing using fluorescent nanothermometers[J]. ACS Nano, 2010, 4:3254-3258.

WANG X, ZHANG Z G, GAO W W. Excellent optical thermometry based on short-wavelength upconversion emissions in Er3+/Yb3+ codoped CaWO4[J]. Opt. Lett., 2012, 37:4865-4867.

RAKOV N, MACIEL G S. Three-photon upconversion and optical thermometry characterization of Er3+:Yb3+ co-doped yttrium silicate powders[J]. Sens. Actuators B:Chem., 2012, 164:96-100.

PARCHUR A K, NINGTHOUJAM R S, RAI S B, et al.. Luminescence properties of Eu3+ doped CaMoO4 nanoparticles[J]. Dalton Trans., 2011, 40(29):7595.

PARCHUR A K, NINGTHOUJAM R S. Preparation and structure refinement of Eu3+ doped CaMoO4 nanoparticles[J]. Dalton Trans., 2011, 40(29):7590.

MENG Q Y, LIU T, DAI J Q, et al.. Study on optical temperature sensing properties of YO4:Er3+,Yb3+ nanocrystals[J]. J. Lumin., 2016, 179:633-638.

TROJAN-PIEGZA J, ZYCH E. Preparation of nanocrystalline Lu2O3:Eu phosphor via a molten salts route[J]. J. Alloys Compd., 2004, 38:118-122.

WANG F, BANERJEE D, LIU Y S, et al.. Upconversion nanoparticles in biological labeling, imaging, and therapy[J]. Analyst, 2010, 135:1839-1854.

DEBASU M L, ANANIAS D, PASTORIZA-SANTOS I, et al.. All-in-one optical heater-thermometer nanoplatform operative from 300 to 2000 K based on Er3+ emission and blackbody radiation[J]. Adv. Mater., 2013, 25:4868-4874.

JAQUE D, VETRONE F. Luminescence nanothermometry[J]. Nanoscale, 2012, 4:4301-4326.

DONG B, CAO B S, HE Y Y, et al.. Temperature sensing and in vivo imaging by molybdenum sensitized visible upconversion luminescence of rare-earth oxides[J]. Adv. Mater., 2014, 24:1987-1993.

LI J J, SUN S, LIU J T, et al.. Pumping-route-dependent concentration quenching and temperature effect of green up-and down-conversion luminescence in Er3+/Yb3+ co-doped Gd2(WO4)3 phosphors[J]. Mater. Res. Bull., 2013, 48:2159-2165.

HARO-GONZLEZ P, MARTN I R, MARTN L L, et al.. Characterization of Er3+ and Nd3+ doped strontium barium niobate glass ceramic as temperature sensors[J]. Opt. Mater., 2011, 33:742-745.

ALENCAR M A R C, MACIEL G S, DE ARAJO C B, et al.. Er3+-doped BaTiO3 nanocrystals for thermometry:influence of nanoenvironment on the sensitivity of a fluorescence based temperature sensor[J]. Appl. Phys. Lett., 2004, 84:4753-4755.

DONG B, HUA R, CAO B, et al.. Wolfbeis, size dependence of the upconverted luminescence of NaYF4:Er,Yb microspheres for use in ratiometric thermometry[J]. Phys. Chem. Chem. Phys., 2014, 16:20009-20012.

TIAN Y Y, TIAN Y, HUANG P, et al.. Effect of Yb3+ concentration on upconversion luminescence and temperature sensing behavior in Yb3+/Er3+ co-doped YNbO4 nanoparticles prepared via molten salt route[J]. Chem. Eng. J., 2016, 297:26-34.

CAO B, HE Y, FENG Z, et al.. Optical temperature sensing behavior of enhanced green upconversion emissions from Er-Mo:Yb2Ti2O7 anophosphor[J]. Sens. Actuators B: Chem., 2011, 159:8-11.

DONG B, LIU D, WANG X, et al.. Optical thermometry through infrared excited green upconversion emissions in Er3+-Yb3+ codoped Al2O3[J]. Appl. Phys. Lett., 2007, 90(18):181117-1-3.

Views

207

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Photoluminescence and Multifunctional Applications of NaGdMgTeO₆∶Eu³⁺ Phosphors

Quadruple-signal Responsive Temperature Sensing Based on Non-thermal Quenched Upconversion Luminescence in ZrO₂∶Yb³⁺/Er³⁺

Temperature- and Concentration-dependent Luminescence and Fluorescence Dynamic Temperature Sensing of NaGd（MoO₄）₂∶Tb³⁺Phosphors

Self-reference Temperature Sensing via Fluorescence Enhancement of Microsphere-cavity-coupled Inorganic Halide Perovskite Quantum Dots

Photoluminescence and Temperature Sensing Properties of Color-tunable CsLa（WO₄）₂∶Pr³⁺ Phosphors

Related Author

LIU Fangfang

DAI Zhengmang

ZHOU Weiwei

LI Rongqing

XIA Zhengrong

WANG Zifeng

YANG Miai

ZHU Haodong

Related Institution

Huainan No.6 High School

Anhui Engineering Research Center for Photoelectrocatalytic Electrode Materials， School of Electrical Engineering， Huainan Normal University

School of Physics and Opto-Electronic Technology， Baoji University of Arts and Sciences

College of Science， Dalian Maritime University

Institute of Laser Engineering， Faculty of Materials and Manufacturing， Beijing University of Technology

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰