Synthesis and Photophysical Properties of A Blue Light-emitting Organic Material

ZHANG Kun; JIN Feng; GAO Yu-long; LU Tian-qi; WANG Po; SUN Lin; TAO Dong-liang; LIAO Rong-b

doi:10.3788/fgxb20173809.1179

您当前的位置：

首页 >

文章列表页 >

Synthesis and Photophysical Properties of A Blue Light-emitting Organic Material

更新时间：2020-08-12

- Synthesis and Photophysical Properties of A Blue Light-emitting Organic Material
- Chinese Journal of Luminescence Vol. 38, Issue 9, Pages: 1179-1184(2017)
- 作者机构：
  
  阜阳师范学院化学与材料工程学院,安徽阜阳,236037
- 作者简介：
- 基金信息：
  
  Supported by National Natural Science Foundation of China (21401024);Natural Scien
- DOI：10.3788/fgxb20173809.1179
  CLC： O626.23
- Received：09 January 2017，
  
  Revised：13 March 2017，
  
  Published Online：26 May 2017，
  
  Published：05 September 2017
- 稿件说明：
移动端阅览
张坤, 金凤, 高玉龙等. 一种新型有机蓝光材料的合成及光物理性质研究[J]. 发光学报, 2017,38(9): 1179-1184

ZHANG Kun, JIN Feng, GAO Yu-long etc. Synthesis and Photophysical Properties of A Blue Light-emitting Organic Material[J]. Chinese Journal of Luminescence, 2017,38(9): 1179-1184
张坤, 金凤, 高玉龙等. 一种新型有机蓝光材料的合成及光物理性质研究[J]. 发光学报, 2017,38(9): 1179-1184 DOI： 10.3788/fgxb20173809.1179.

ZHANG Kun, JIN Feng, GAO Yu-long etc. Synthesis and Photophysical Properties of A Blue Light-emitting Organic Material[J]. Chinese Journal of Luminescence, 2017,38(9): 1179-1184 DOI： 10.3788/fgxb20173809.1179.

摘要

利用Witting反应合成了一种含吡啶和吡唑基团的共轭结构刚性有机分子6-苯基-4'-（4-[4-（1H-吡唑）乙烯]苯基）-2， 2'-联吡啶，采用元素分析、红外光谱、核磁共振氢谱、质谱等方法对其进行了表征。通过理论计算研究了化合物的吸收光谱特点，实验研究了化合物在几种不同溶剂中的紫外吸收光谱及荧光发射光谱。研究结果表明，所合成的化合物具有优良的蓝色荧光性能，作为发光材料具有潜在的应用价值。

Abstract

A new -conjugated organic compound containing imidazole and pyridine

namely

6-phenyl-4-4-[4-(1H-(pyrazole) vinyl] phenyl)-2

2'-bipyridine was successfully synthesized through Wittig reaction. It was characterized by elemental analysis

H NMR and Ms. The absorption spectra of the compound at the level of B3LYP/-31G(d)//B3LYP/6-31G were obtained. The optical properties of the compound were investigated by ultraviolet-visible (UV) absorption spectra and single photon fluorescence spectra in different solvents. The results indicate that the target compound exhibits strong blue light-emitting

which makes it well suitable for fluorescence material.

关键词

Keywords

references

DOU C D, HAN L, ZHAO S S, et al.. Multi-stimuli-responsive fluorescence switching of a donor-acceptor -conjugated compound[J]. J. Phys. Chem. Lett., 2011, 2(6):666-670.

TANG F, WANG C, WANG J S, et al.. Fluorescent organic nanoparticles with enhanced fluorescence by self-aggregation and their application to cellular imaging[J]. ACS Appl. Mater. Interf., 2014, 6(20):18337-18343.

VAN DER VELDE J H M, OELERICH J, HUANG J Y, et al.. The power of two:covalent coupling of photostabilizers for fluorescence applications[J]. J. Phys. Chem. Lett., 2014, 5(21):3792-3798.

安永, 徐茂梁, 王子俊, 等. 新型蓝光材料9,9'-联蒽衍生物的合成及其光电性能[J]. 发光学报, 2011, 32(9):890-895. AN Y, XU M L, WANG Z J, et al.. Synthesis of novel blue light emitting 9,9'-bianthracene derivatives and their optoelectronic properties[J]. Chin. J. Lumin., 2011, 32(9):890-895. (in Chinese)

MITRA K, SINGH S, HIRA S K, et al.. Study of the fluorescence based applications of pyrene-tagged poly(N-vinyl-2-pyrrolidone)[J]. ACS Biomater. Sci. Eng., 2016, 2(9):1630-1640.

祝艳龙, 徐茂梁, 姜菡雨, 等. 新型蒽衍生物蓝光材料的合成及光电性能研究[J]. 发光学报, 2014, 35(3):354-359. ZHU Y L, XU M L, JIANG H Y, et al.. Synthesis and optical properties of a novel blue-emitting anthracene-based derivative[J]. Chin. J. Lumin., 2014, 35(3):354-359. (in Chinese)

JIN F, PAN C Y, ZHANG W X, et al.. Enhanced two-photon excited fluorescence of mercury complexes with a conjugated ligand:effect of the central metal ion[J]. J. Lumin., 2016, 172:264-269.

BODAPATI R, SARMA M, KANAKATI A, et al.. Asymmetrically substituted and -conjugated 2,2'-bipyridine derivatives:synthesis, spectroscopy, computation, and crystallography[J]. J. Org. Chem., 2015, 80(24):12482-12491.

JIN F, SHU W C, YU X P, et al.. Crystal structures, two-photon excited fluorescence and bioimaging of Zn(Ⅱ) complexes based on an extended 2,2'-bipyridine ligand[J]. Dyes Pigm., 2015, 121:379-384.

GAO Y H, WU J Y, LI Y M, et al.. A sulfur-terminal Zn(Ⅱ) complex and its two-photon microscopy biological imaging application[J]. J. Am. Chem. Soc., 2009, 131(14):5208-5313.

JIN F, XU D L, ZHU H Z, et al.. New conjugated organic dyes with various electron donors:one-and two-photon excited fluorescence, and bioimaging[J]. Dyes Pigm., 2014, 109:42-53.

GAO Y H, ZHOU W, LI L, et al.. Polymorphism in a highly conjugated organic compound:strong photoelectric response[J]. Cryst. Growth Des., 2009, 9(1):253-257.

JIN F, ZHANG Y, WANG H Z, et al.. Diverse structural Ag(Ⅰ) supramolecular complexes constructed from multidentate dicyanoisophorone-based ligands:structures and enhanced luminescence[J]. Cryst. Growth Des., 2013, 13(5):1978-1987.

MAI C L, MOEHL T, HSIEH C H, et al.. Porphyrin sensitizers bearing a pyridine-type anchoring group for dye-sensitized solar cells[J]. ACS Appl. Mater. Interf., 2015, 7(27):14975-14982.

LIU W, ZHENG C J, WANG K, et al.. Novel carbazol-pyridine-carbonitrile derivative as excellent blue thermally activated delayed fluorescence emitter for highly efficient organic light-emitting devices[J]. ACS Appl. Mater. Interf., 2015, 7(34):18930-18936.

FRISCH M J, TRUCKS G W, SCHLEGEL H B, et al.. Gaussian 09, Revision A. 02[M]. Wallingford, CT:Gaussian Inc., 2009:200.

LU T, CHEN F W. Multiwfn:a multifunctional wavefunction analyzer[J]. J. Computat. Chem., 2012, 33(5):580-592.

Views

352

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Preparation, Characterization and Research of Modified Carboxymethyl Chitosan Composite

Improvement of The Performance of Planar Heterojunction Perovskite Solar Cells by Using Pyridine as Additive

Fabrication and Characterization of Green CdSe Quantumn Dot Light Emitting Diodes with ZnO Electron-transport Layer

Synthesis of Novel Blue Light Emitting 9,9'-bianthracene Derivatives and Their Optoelectronic Properties

Preparation and Characterization of Single-crystal ZnO Nanorods via a H₂O₂-assisted Hydrothermal Method

Related Author

WANG Feng-ming

LI Zhong-tian

WEI Chang-ping

DONG Li-dan

WANG Ya-ling

LI Zhi-cheng

YANG Yin

CAO Huan-qi

Related Institution

China Water Northeastern Investigation, Design and Research Co., Ltd.

Changchun Medical College

School of Materials Science and Engineering, Changchun University of Science and Techology

China Electronics Technology Group Corporation No. 18 th Research Institute

School of Chemical Engineering and Technology, Tianjin University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰