YUAN Tao-li, WANG Xiu-feng, MU Qiang etc. Organic Light Emitting Diode Based on Bphen Electron Transport Layer Doped with Alq<sub>3</sub>[J]. Chinese Journal of Luminescence, 2017,38(8): 1069-1075
YUAN Tao-li, WANG Xiu-feng, MU Qiang etc. Organic Light Emitting Diode Based on Bphen Electron Transport Layer Doped with Alq<sub>3</sub>[J]. Chinese Journal of Luminescence, 2017,38(8): 1069-1075 DOI: 10.3788/fgxb20173808.1069.
Organic Light Emitting Diode Based on Bphen Electron Transport Layer Doped with Alq3
Red phosphorescent organic light emitting diodes were fabricated using R-4B phosphorescent dye. The device structure was ITO/MoO
3
(30 nm)/NPB(40 nm)/TCTA (10 nm)/CBP:R-4B(8%) (30 nm)/electron transport layer (40 nm)/LiF(1 nm)/Al(150 nm). The electron transport layers were Alq
3
Bphen:Alq
3
(
x
%) and Bphen
respectively. The electroluminescent properties were studied by using different electron transport layers. The results show that the brightness and the current efficiency of the device using Bphen:Alq
3
(
x
%) as electron transport layer is 3.5 times and 1.1-2.5 times respectively stronger than that of using Alq
3
or Bphen as electron transport layer. Meanwhile
the efficiency roll-off of device became smooth. Using Bphen:Alq
3
as electron transport layer can not only reduce the hopping distance when electrons transmit between LUMO levels
but also restrain the crystallization of Bphen
and as a result
the electron conductivity and efficiency roll-off of the device are improved.
关键词
Keywords
references
SMITH J, BAWOLEK E, LEE Y K, et al.. Application of flexible flat panel display technology to wearable biomedical devices[J]. Electron. Lett., 2015, 51(17):1312-1314.
LUO Y, WANG C H, WANG L, et al.. Flexible organic light-emitting diodes with enhanced light out-coupling efficiency fabricated on a double-sided nanotextured substrate[J]. ACS Appl. Mater. Interf., 2014, 6(13):10213-10219.
SINGH A, NEHM F, MVLLER-MESKAMP L, et al.. OLED compatible water-based nanolaminate encapsulation systems using ozone based starting layer[J]. Organ. Electron., 2014, 15(10):2587-2592.
TSAI Y S, HONG L A, JUANG F S, et al.. Blue and white phosphorescent organic light emitting diode performance improvement by confining electrons and holes inside double emitting layers[J]. J. Lumin., 2014, 153:312-316.
LIU L, LI S, ZHOU Y M, et al.. High-current stressing of organic light-emitting diodes with different electron-transport materials[J]. Microelectron. Reliab., 2017, 71:106-110.
ZHANG Z Q, WANG Q, DAI Y F, et al.. High efficiency fluorescent white organic light-emitting diodes with red, green and blue separately monochromatic emission layers[J]. Org. Electron., 2009, 10(3):491-495.
郝玉英, 李云飞, 孙钦军, 等. 有机电致发光器件中载流子传输与复合的调控[J]. 中国科学:化学, 2013, 43(4):502-509. HAO Y Y, LI Y F, SUN Q J, et al.. Controllable transport and recombination of charge carriers in the electrophosphorescent organic light-emitting devices[J]. Sci. Sin. Chim., 2013, 43(4):502-509. (in Chinese)
TANG C W, VANSLYKE S A. Organic electroluminescent diodes[J]. Appl. Phys. Lett., 1987, 51(12):913-915.
ADACHI C, TOKITO S, TSUTSUI T, et al. Electroluminescence in organic films with three-layer structure[J]. Jpn J. Appl. Phys., 1988, 27(2):L269.
HUANG J S, PFEIFFER M, WERNER A, et al.. Low-voltage organic electroluminescent devices using pin structures[J]. Appl. Phys. Lett., 2002, 80(1):139-141.
ZHAO J, CAI Y, YANG J P, et al.. The role of cesium carbonate on the electron injection and transport enhancement in organic layer by admittance spectroscopy[J]. Appl. Phys. Lett., 2012, 101(19):193303-1-4.
CHOUDHURY K R, YOON J H, SO F. LiF as an n-dopant in tris(8-hydroxyquinoline) aluminum thin films[J]. Adv. Mater., 2008, 20(8):1456-1461.
TYAGI P, SRIVASTAVA R, KUMAR A, et al.. Effect of doping of cesium carbonate on electron transport in Tris(8-hydroxyquinolinato) aluminum[J]. Org. Electron., 2013, 14(5):1391-1395.
DENG Y H, LI Y Q, OU Q D, et al.. The doping effect of cesium-based compounds on carrier transport and operational stability in organic light-emitting diodes[J]. Org. Electron., 2014, 15(6):1215-1221.
陆勍, 陈炳月, 杨魏强, 等. 双电子传输层对有机发光二极管效率及其衰减的改善[J]. 发光学报, 2015, 36(9):1053-1058. LU Q, CHEN B Y, YANG W Q, et al.. Improved efficiency and its roll-off of organic light-emitting diodes with double electron transport layers[J]. Chin. J. Lumin., 2015, 36(9):1053-1058. (in Chinese)
杜帅, 张方辉. 基于Bphen:BCP:Cs2CO3作为电子传输层的OLED性能研究[J]. 光电子激光, 2017, 28(1):19-24. DU S, ZHANG F H. Impact of Bphen:BCP:Cs2CO3as electron transport layer on the performance of OLEDs[J]. J. Optoelectron. Laser, 2017, 28(1):19-24. (in Chinese).
李怀坤, 张方辉, 程君, 等. Bphen作为发光层间隔层对黄光OLED的影响[J]. 发光学报, 2016, 37(1):38-43. LI H K, ZHANG F H, CHENG J, et al.. Effects of Bphen as spacer layer in light emitting layer on yellow OLED[J]. Chin. J. Lumin., 2016, 37(1):38-43. (in Chinese)
黄春辉, 李富友, 黄维. 有机电致发光材料与器件导论[M]. 上海:复旦大学出版社, 2005. HUANG C H, LI F Y, HUANG W. Introduction to Organic Light-emitting Materials and Devices[M]. Shanghai:Fudan University Press, 2005. (in Chinese)
XIAO J, WANG X X, ZHU H, et al.. Efficiency enhancement utilizing hybrid charge generation layer in tandem organic light-emitting diodes[J]. Appl. Phys. Lett., 2012, 101(1):013301-1-4.
于军胜, 田朝勇. OLED显示基础及产业化[M]. 成都:电子科技大学出版社, 2015. YU J S, TIAN C Y. OLED Display and Industry[M]. Chengdu:UEST Press, 2015. (in Chinese)
连加荣, 周翔. 利用LiF空穴阻挡/激子限制层提高有机电致发光器件效率[J]. 光学学报, 2010, 30(5):1469-1472. LIAN J R, ZHOU X. Improved efficiency in organic light-emitting devices with LiF hole blocking and exciton confining layers[J]. Acta Opt. Sinica, 2010, 30(5):1469-1472. (in Chinese)
Single-emitting Layer White Organic Light-emitting Diodes with Blue HLCT Material of pCzAnN as Sensitizer Host
Refinement of Polyethyleneimine-coated Zinc Oxide Electron Transport Material and Investigation of Its Enhancing Effect on Air and Ultraviolet Stability of Organic Photovoltaic Devices
High-efficiency Perovskite Light-emitting Diodes via Novel Cobalt-based Hole Transporter Layer
Research Progress of Blue Emission Materials and Devices Based on TADF Sensitized Fluorescence
Rare Earth Ion Doped Perovskite Nanocrystals
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