Enhanced Performance of Polymer Solar Cells Using Rapid Thermal Annealing Treated ZnO Electron Transporting Layer

ZHAO Yu-han; LI Xue; GUAN Hai-yan; DU Jin-feng; ZHANG Jian; LIN Chuan-nan; WANG Jin

doi:10.3788/fgxb20173808.1063

您当前的位置：

首页 >

文章列表页 >

Enhanced Performance of Polymer Solar Cells Using Rapid Thermal Annealing Treated ZnO Electron Transporting Layer

更新时间：2020-08-12

- Enhanced Performance of Polymer Solar Cells Using Rapid Thermal Annealing Treated ZnO Electron Transporting Layer
- Chinese Journal of Luminescence Vol. 38, Issue 8, Pages: 1063-1068(2017)
- 作者机构：
  
  1. 吉林大学电子科学与工程学院集成光电子学国家重点联合实验室,吉林长春,130012
  2. 吉林师范大学功能材料物理与化学教育部重点实验室,吉林四平,136000
- 作者简介：
- 基金信息：
  
  Supported by National Natural Science Foundation of China (61177025,61275024);Scie
- DOI：10.3788/fgxb20173808.1063
  CLC： TM914.4
- Received：13 January 2017，
  
  Revised：30 March 2017，
  
  Published：05 August 2017
- 稿件说明：
移动端阅览
赵宇涵, 李雪, 关海艳等. 快速热退火处理ZnO电子传输层对聚合物太阳能电池性能的改善[J]. 发光学报, 2017,38(8): 1063-1068

ZHAO Yu-han, LI Xue, GUAN Hai-yan etc. Enhanced Performance of Polymer Solar Cells Using Rapid Thermal Annealing Treated ZnO Electron Transporting Layer[J]. Chinese Journal of Luminescence, 2017,38(8): 1063-1068
赵宇涵, 李雪, 关海艳等. 快速热退火处理ZnO电子传输层对聚合物太阳能电池性能的改善[J]. 发光学报, 2017,38(8): 1063-1068 DOI： 10.3788/fgxb20173808.1063.

ZHAO Yu-han, LI Xue, GUAN Hai-yan etc. Enhanced Performance of Polymer Solar Cells Using Rapid Thermal Annealing Treated ZnO Electron Transporting Layer[J]. Chinese Journal of Luminescence, 2017,38(8): 1063-1068 DOI： 10.3788/fgxb20173808.1063.

摘要

采用快速热退火对ZnO薄膜进行后处理，制作了ITO/ZnO/PTB7：PC

BM/MoO

/Ag结构的倒置聚合物太阳能电池，器件能量转换效率达到了8.1%，与传统热退火工艺相比提高了11.26%。通过原子力显微镜、扫描电子显微镜、X光衍射谱、透射光谱和荧光谱对不同退火条件下制备的ZnO薄膜进行表征和分析。结果表明，经快速热退火处理的ZnO薄膜具有良好的

轴取向结晶特性、较大的晶粒尺寸和表面粗糙度，有效地降低了器件的串联电阻

，增大了器件的短路电流

和填充因子FF。

Abstract

ZnO film was commonly used as electron transporting layer(ETL) in inverted polymer solar cell (IPSC) due to its excellent performance. Here

rapid thermal annealing(RTA) was applied to treat the ZnO ETL

and IPSCs with the structure of ITO/ZnO/PTB7:PC

BM/MoO

/Ag were prepared. The ZnO films prepared under different annealing conditions were characterized by atomic force microscopy

scanning electron microscopy

X-ray diffraction

UV-Vis-NIR transmission and photoluminescence (PL) spectra. The power-conversion efficiency (PCE) of IPSC using RTA treated ZnO as electronic transporting layer (ETL) is 8.1%

which is 11.26% higher than that of IPSC with ETL treated by traditional thermal annealing. The ZnO films treated by RTA have good crystalline properties

large grain size and rough surface

which decrease the series resistor (

) and increase the short-circuit current density (

)

fill factor (FF) of IPEC.

关键词

Keywords

references

BLOM P W M, MIHAILETCHI V D, KOSTER L J A, et al.. Device physics of polymer:fullerene bulk heterojunction solar cells[J]. Adv. Mater., 2007, 19(12):1551-1566.

DOU L T, YOU J B, HONG Z R, et al.. 25th anniversary article:a decade of organic/polymeric photovoltaic research[J]. Adv. Mater., 2013, 25(46):6642-6671.

HE Z C, ZHONG C M, SU S J, et al.. Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure[J]. Nat. Photon., 2012, 6(9):591-595.

WHITE M S, OLSON D C, SHAHEEN S E, et al.. Inverted bulk-heterojunction organic photovoltaic device using a solution-derived ZnO underlayer[J]. Appl. Phys. Lett., 2006, 89(14):143517-1-3.

YANG T B, CAI W Z, QIN D H, et al.. Solution-processed zinc oxide thin film as a buffer layer for polymer solar cells with an inverted device structure[J]. J. Phys. Chem. C, 2010, 114(14):6849-6853.

SEKINE N, CHOU C H, KWAN W L, et al.. ZnO nano-ridge structure and its application in inverted polymer solar cell[J]. Org. Electron., 2009, 10(8):1473-1477.

GUPTA C A, MANGAL S, SINGH U P. Impact of rapid thermal annealing on structural, optical and electrical properties of DC sputtered doped and co-doped ZnO thin film[J]. Appl. Surf. Sci., 2014, 288:411-415.

汪雷. ZnO薄膜生长技术的最新研究进展[J]. 材料导报, 2002, 16(9):33-36. WANG L. Advances in research on deposition techniques for ZnO thin films[J]. Mater. Rev., 2002, 16(9):33-36. (in Chinese)

KAO M C, CHEN H Z, YOUNG S L, et al.. Rapid thermal annealing of ZnO nanocrystalline films for dye-sensitized solar cells[J]. J. Supercond. Nov. Magn., 2010, 23(6):897-900.

MENG X Q, YANG C T, FU W J, et al.. Influence of rapid thermal annealing on structure and interfacial characteristic of ZnO thin films[J]. Surf. Interf. Anal., 2013, 45(2):672-676.

PENG H, XU W P, ZHOU F, et al.. Enhanced efficiency of inverted polymer solar cells using surface modified Cs-doped ZnO as electron transporting layer[J]. Synth. Met., 2015, 205:164-168.

OHYAMA M, KOUZUKA H, YOKO T. Sol-gel preparation of ZnO films with extremely preferred orientation along (002) plane from zinc acetate solution[J]. Thin Solid Films, 1997, 306(1):78-85.

GHOSH R, PAUL G K, BASAK D. Effect of thermal annealing treatment on structural, electrical and optical properties of transparent sol-gel ZnO thin films[J]. Mater. Res. Bull., 2005, 40(11):1905-1914.

YU X, YU X M, HU Z, et al.. Effect of sol-gel derived ZnO annealing rate on light-trapping in inverted polymer solar cells[J]. Mater. Lett., 2003, 108:50-53.

GUAN H Y, XU W P, LI X, et al.. Implementation of photothermal annealing on ZnO electron transporting layer for high performance inverted polymer solar cells[J]. Mater. Lett., 2016, 163:69-71.

申德振, 梅增霞, 梁会力, 等. 氧化锌基材料、异质结构及光电器件[J]. 发光学报, 2014, 35(1):1-60. SHEN D Z, MEI Z X, LIANG H L, et al.. ZnO-based material, heterojunction and photoelctronic device[J]. Chin. J. Lumin., 2014, 35(1):1-60. (in Chinese)

李畅, 章婷, 薛唯, 等. 阴极缓冲层对于不同惰性气氛气压退火处理的P3HT:PCBM光伏性能的影响[J]. 发光学报, 2012, 33(2):221-226. LI C, ZHANG T, XUE W, et al.. Effects of cathode buffer layer on the performance of P3HT:PCBM-based photovoltaic devices annealed under various ambient pressures[J]. Chin. J. Lumin., 2012, 33(2):221-226. (in Chinese)

刘爱华, 杨利营. 采用复合空穴注入层提高有机电致发光器件的性能[J]. 发光学报, 2012, 33(4):422-427. LIU A H, YANG L Y. Improved performance of organic light emitting diodes using combined hole-injecting layer[J]. Chin. J. Lumin., 2012, 33(4):422-427. (in Chinese)

SAGAR P, SHISHODIA P K, MEHRA R M, et al.. Photoluminescence and absorption in sol-gel-derived ZnO films[J]. J. Lumin., 2007, 126(2):800-806.

ZHOU J G, WANG Y L, ZHAO F Y, et al.. Photoluminescence of ZnO nanoparticles prepared by a novel gel-template combustion process[J]. J. Lumin., 2006, 119-120:248-252.

KRZYWIECKI M, GRZADZIEL L, SARFRAZ A, et al.. Zinc oxide as a defect-dominated material in thin films for photovoltaic applications-experimental determination of defect levels, quantification of composition, and construction of band diagram[J]. Phys. Chem. Chem. Phys., 2015, 17(15):10004-10013.

MA W, YANG C, GONG X, et al.. Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology[J]. Adv. Funct. Mater., 2005, 15(10):1617-1622.

PEUMANS P, UCHIDA S, FORREST S R. Efficient bulk heterojunction photovoltaic cells using small-molecular-weight organic thin films[J]. Nature, 2003, 425(6954):158-162.

KIM Y S, TAI W P, SHU S J. Effect of preheating temperature on structural and optical properties of ZnO thin films by sol-gel process[J]. Thin Solid Films, 2005, 491(1-2):153-160.

Views

127

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Application of Ag-ZnO Hybrid Film in Polymer Solar Cell

Related Author

XUE Zhi-chao

LI Qiang

YU Zhi-qing

YU Ming-fu

GUO Xiao-yang

SUN Hong

Related Institution

School of Science, Shenyang Jianzhu University

School of Mechanical Engineering, Shenyang Jianzhu University

State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰