Properties of Fluorescence Resonance Energy Transfer of ZnS:Cu-Rhodamine B

ZHAI Ying-ge; CHU Xue-ying; XU Ming-ze; LI Jin-hua; JIN Fang-jun; WANG Xiao-hua

doi:10.3788/fgxb20173808.1028

您当前的位置：

首页 >

文章列表页 >

Properties of Fluorescence Resonance Energy Transfer of ZnS:Cu-Rhodamine B

更新时间：2020-08-12

- Properties of Fluorescence Resonance Energy Transfer of ZnS:Cu-Rhodamine B
- Chinese Journal of Luminescence Vol. 38, Issue 8, Pages: 1028-1032(2017)
- 作者机构：
  
  1. 长春理工大学理学院,吉林长春,130022
  2. 长春理工大学国际教育与交流学院,吉林长春,130022
- 作者简介：
- 基金信息：
  
  Supported by National Natural Science Foundation of China (61205193);Project of Sc
- DOI：10.3788/fgxb20173808.1028
  CLC： O482.31
- Received：23 January 2017，
  
  Revised：22 February 2017，
  
  Published：05 August 2017
- 稿件说明：
移动端阅览
翟英歌, 楚学影, 徐铭泽等. ZnS:Cu-罗丹明B的荧光共振能量转移性质[J]. 发光学报, 2017,38(8): 1028-1032

ZHAI Ying-ge, CHU Xue-ying, XU Ming-ze etc. Properties of Fluorescence Resonance Energy Transfer of ZnS:Cu-Rhodamine B[J]. Chinese Journal of Luminescence, 2017,38(8): 1028-1032
翟英歌, 楚学影, 徐铭泽等. ZnS:Cu-罗丹明B的荧光共振能量转移性质[J]. 发光学报, 2017,38(8): 1028-1032 DOI： 10.3788/fgxb20173808.1028.

ZHAI Ying-ge, CHU Xue-ying, XU Ming-ze etc. Properties of Fluorescence Resonance Energy Transfer of ZnS:Cu-Rhodamine B[J]. Chinese Journal of Luminescence, 2017,38(8): 1028-1032 DOI： 10.3788/fgxb20173808.1028.

摘要

为了解决现有的基于量子点荧光共振能量转移体系的生物毒性问题，选用无毒的ZnS：Cu量子点与罗丹明B构建新型荧光共振能量转移体系。通过共沉淀法成功制备了形貌均一的ZnS：Cu纳米晶量子点。在此基础上，测试了不同掺杂浓度的ZnS：Cu量子点及罗丹明B的荧光光谱。然后，通过对ZnS：Cu量子点的表面修饰构建了以ZnS：Cu量子点为供体、罗丹明B为受体的荧光共振能量转移体系。实验结果表明：ZnS：2% Cu量子点的发光光谱与罗丹明B的吸收光谱在481 nm处有较大重合，说明构建荧光共振能量转移的最佳铜掺杂摩尔分数为2%。通过计算发现以ZnS：2% Cu量子点为供体、罗丹明B为受体的荧光共振能量转移体系的能量转移效率为25.8%。进一步实验结果表明，罗丹明B浓度也能够影响能量转移。

Abstract

In order to solve the biological toxicity of fluorescence resonance energy transfer (FRET) system based on quantum dots

non-toxic ZnS:Cu quantum dots and Rhodamine B were chosen to construct FRET system. ZnS:Cu nanocrystalline quantum dots with good morphology were successfully prepared by precipitation method. On this basis

the fluorescence spectra of ZnS:Cu quantum dots with different concentration of copper and fluorescence spectra of Rhodamine B were tested. Then

FRET system with ZnS:Cu quantum dots as donor and Rhodamine B as acceptor was successfully constructed by the surface modification. Experimental results indicate that the emission spectrum of ZnS:2%Cu matches the excitation spectrum of Rhodamine B most in 481 nm. So the optimum copper doping mole fraction for the construction of FRET system is 2%. The energy transfer efficiency of ZnS:Cu quantum dots as donor and Rhodamine B as acceptor is 25.8%. Further experimental results indicate that the concentration of Rhodamine B also can affect the energy transfer.

关键词

Keywords

references

FRSTER T. Zwischenmolekulare energiewanderung und fluoreszenz[J]. Ann. Phys., 1948, 437(1-2):55-75.

VANOAICA L, BEHERA A, CAMARGO S M R, et al.. Real-time functional characterization of cationic amino acid transporters using a new FRET sensor[J]. Pflgers Arch., 2016, 468(4):563-572.

WANG Y, LIU K, LIU X M, et al.. Critical shell thickness of core/shell upconversion luminescence nanoplastform for FRET application[J]. J. Phys. Chem. Lett., 2011, 2(17):2083-2088.

COST A L, RINGER P, CHROSTEK-GRASHOFF A, et al.. How to measure molecular forces in cells:a guide to evaluating genetically-encoded FRET-based tension sensors[J]. Cell. Mol. Bioeng., 2015, 8(1):96-105.

VAN DER KROGT G N M, OGINK J, PONSIOEN B, et al.. A comparison of donor-acceptor pairs for genetically encoded FRET sensors:application to the Epac cAMP sensor as an example[J]. PLoS One, 2008, 3(4):e1916.

KEDZIORA K M, JALINK K. Fluorescence Resonance Energy Transfer Microscopy (FRET)[M]. VERVEER P J. Advanced Fluorescence Microscopy:Methods and Protocols. New York:Springer, 2015:67-82.

KERSHAW S V, SUSHA A S, ROGACH A L. Narrow bandgap colloidal metal chalcogenide quantum dots:synthetic methods, heterostructures, assemblies, electronic and infrared optical properties[J]. Chem. Soc. Rev., 2013, 42(7):3033-3087.

MATTSSON L, WEGNER K D, HILDEBRANDT N, et al.. Upconverting nanoparticle to quantum dot FRET for homogeneous double-nano biosensors[J]. RSC Adv., 2015, 5(18):13270-13277.

DENNIS A M, RHEE W J, SOTTO D, et al.. Quantum dot-fluorescent protein FRET probes for sensing intracellular pH[J]. ACS Nano, 2012, 6(4):2917-2924.

LI L, LIU J B, YANG X H, et al.. Quantum dot/methylene blue FRET mediated NIR fluorescent nanomicelles with large Stokes shift for bioimaging[J]. Chem. Commun., 2015, 51(76):14357-14360.

DOS SANTOS M C, HILDEBRANDT N. Recent developments in lanthanide-to-quantum dot FRET using time-gated fluorescence detection and photon upconversion[J]. TrAC Trends Anal. Chem., 2016, 86:60-71.

ALIVISATOS A P, GU W W, LARABELL C. Quantum dots as cellular probes[J]. Annu. Rev. Biomed. Eng., 2005, 7:55-76.

LEI Y, XIAO Q, HUANG S, et al.. Impact of CdSe/ZnS quantum dots on the development of zebrafish embryos[J]. J. Nanopart. Res., 2011, 13(12):6895-6906.

LI J L, ZHANG Y H, AI J J, et al.. Quantum dot cluster (QDC)-loaded phospholipid micelles as a FRET probe for phospholipase A2 detection[J]. RSC Adv., 2016, 6(19):15895-15899.

WANG S Z, ZHANG J G, CHEN H G, et al.. An optical FRET inhibition sensor for serum ferritin based on Mn2+-doped NaYF4:Yb, Tm NIR luminescence up-conversion nanoparticles[J]. J. Lumin., 2015, 168:82-87.

高桂园, 刘璐, 付璇, 等. CdTe量子点-罗丹明B荧光共振能量转移法测定溶菌酶[J]. 发光学报, 2012, 33(8):911-915. GAO G Y, LIU L, FU X, et al.. Fluorescence resonance energy transfer between CdTe QDs and rhodamine B with its application in the determination of lysozyme[J]. Chin. J. Lumin., 2012, 33(8):911-915. (in Chinese)

HABEEBU S S M, LIU J, KLAASSEN C D. Cadmium-induced apoptosis in mouse liver[J]. Toxicol. Appl. Pharmacol., 1998, 149(2):203-209.

GESZKE-MORITZ M, PIOTROWSKA H, MURIAS M, et al.. Thioglycerol-capped Mn-doped ZnS quantum dot bioconjugates as efficient two-photon fluorescent nano-probes for bioimaging[J]. J. Mater. Chem. B, 2013, 1(5):698-706.

DAS U. Development of ZnS nanostructure based luminescent devices[J]. Imperial J. Interdiscip. Res., 2016, 2(6):627-630.

Views

221

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Allyl Fluorescein Molecularly Imprinted Fluorescence Sensor for Rhodamine B

Design and Application of A Fluorescent Probe with Recognition of Hg²⁺ and ClO^-

Spectral Properties of Ethyl 2-(4-methoxyphenyl)-5-phenyl-2H-1,2, 3-triazole-4-carboxylate and Chromogenic Mechanism of Its Rhodamine B Derivatives to Hg²⁺ Ions and Application in Cell Imaging

Synthesis and Properties of A Novel Colorimetric Fluorescent Probe for Fe³⁺ at Dual Emission Wavelengths

Semiconducting Polymer Dots-methylene Blue Fluorescence Energy Transfer System for Determination of Bi(Ⅲ) Ions in Water

Related Author

LI Kai

WANG Xi

LI Yuanyuan

LIU Gang

WANG Tiancong

WANG Yu

NIU Haoyu

ZHANG Mingliang

Related Institution

College of Chemistry， Zhengzhou University

School of Chemistry and Chemical Engineering， Henan University of Technology

College of Chemistry and Chemical Engineering， Hainan Normal University

Key Laboratory of Tropical Medicinal Plant Chemistry of Ministry of Education

海南师范大学化学与化工学院

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰