Photoluminescence Properties of Eu3+-activated Ca1.9 Eu0.1 NaMg2-x Znx(VO4)3(0 &le; x &le; 1.0) Phosphor

RUAN Wei-wei; LIU Zhi-guo; LIU Cheng-zhen; RUAN Jian; HAN Jian-jun; ZHAO Xiu-jian

doi:10.3788/fgxb20173808.0995

您当前的位置：

首页 >

文章列表页 >

Photoluminescence Properties of Eu³⁺-activated Ca_1.9 Eu_0.1 NaMg_2-x Zn_x(VO₄)₃(0 ≤ x ≤ 1.0) Phosphor

更新时间：2020-08-12

- Photoluminescence Properties of Eu³⁺-activated Ca_1.9 Eu_0.1 NaMg_2-x Zn_x(VO₄)₃(0 ≤ x ≤ 1.0) Phosphor
- Chinese Journal of Luminescence Vol. 38, Issue 8, Pages: 995-1002(2017)
- 作者机构：
  
  硅酸盐建筑材料国家重点实验室武汉理工大学, 湖北武汉 430070
- 作者简介：
- 基金信息：
  
  Supported by National Natural Science Foundation of China(51302202);Ph.D. Programs
- DOI：10.3788/fgxb20173808.0995
  CLC： O482.31
- Received：25 January 2017，
  
  Revised：09 March 2017，
  
  Published：05 August 2017
- 稿件说明：
移动端阅览
阮威威, 刘志国, 刘成振等. Eu3+离子激活荧光粉Ca1.9 Eu0.1 NaMg2-x Znx(VO4)3(0 ≤ x ≤ 1)的发光性质[J]. 发光学报, 2017,38(8): 995-1002

RUAN Wei-wei, LIU Zhi-guo, LIU Cheng-zhen etc. Photoluminescence Properties of Eu3+-activated Ca1.9 Eu0.1 NaMg2-x Znx(VO4)3(0 ≤ x ≤ 1.0) Phosphor[J]. Chinese Journal of Luminescence, 2017,38(8): 995-1002
阮威威, 刘志国, 刘成振等. Eu3+离子激活荧光粉Ca1.9 Eu0.1 NaMg2-x Znx(VO4)3(0 ≤ x ≤ 1)的发光性质[J]. 发光学报, 2017,38(8): 995-1002 DOI： 10.3788/fgxb20173808.0995.

RUAN Wei-wei, LIU Zhi-guo, LIU Cheng-zhen etc. Photoluminescence Properties of Eu3+-activated Ca1.9 Eu0.1 NaMg2-x Znx(VO4)3(0 ≤ x ≤ 1.0) Phosphor[J]. Chinese Journal of Luminescence, 2017,38(8): 995-1002 DOI： 10.3788/fgxb20173808.0995.

摘要

采用固相反应法合成了Eu

离子激活的Ca

1.9

0.1

NaMg

（VO

）

（0

1），并研究了其发光和热猝灭性能。经粉末X射线衍射确认，反应产物由目标相和微量杂质相EuVO

构成。在355 nm激发下，样品中均能同时观察到来自[VO

]

基团和Eu

离子的特征发光。研究结果表明：随着

值的增加，上述两种发光的强度均先增加后降低；而它们的最强激发峰位置由347 nm逐渐地红移至356 nm，Stokes位移也逐渐地减小。这种现象应归因于Zn3d轨道和O2p轨道间很强的轨道杂化效应，这种效应随着

值的增加而逐渐增强。此外，Eu

离子荧光发射强度最大值对应的

值与自激活荧光的不同。当

=1.0时，两者的相对强度差别最大。经荧光热猝灭测试确认，上述现象是由样品中的自激活荧光表现出比Eu

离子荧光更严重的荧光热猝灭造成的。因而，在紫外光激发下，样品发出荧光的颜色具有温度敏感性。

Abstract

-activated Ca

1.9

0.1

NaMg

(VO

)

1) were synthesized by solid-state reaction route

and their photoluminescence and thermal quenching properties were studied. The samples were verified through powder X-ray diffraction

and the target phase was identified with tiny impurity of EuVO

in the obtained product. Excited by 355 nm

all the samples show the characteristic emissions from[VO

]

group and Eu

ion. With the increment of

value

the intensity of either of the above mentioned emissions increases at first and then decreases

while a red-shifting excitation peak from 347 nm to 356 nm and a decreasing Stokes-shift can be observed. Stronger hybridization effect occurres between the Zn3d orbital and the O2p orbital resulted by the increasing

value which is supposed to be responsible for that phenomena. Furthermore

the

value corresponding to the observed intensity maximum for Eu

emission is different from the one for self-activated emission. Their highest difference is observed in the sample of

=1.0. It could be due to an apparently more serious thermal quenching of self-activated emission than that of Eu

ion emission. Then

a temperature-sensitive color of the emission is also observed in the samples excited by the near ultraviolet light.

关键词

Keywords

references

KRAMES M R, SHCHEKIN O B, MUELLER-MACH R. Status and future of high-power light-emitting diodes for solid-state lighting[J]. J. Dis. Technol., 2007, 3(2):160-175.

周青超, 柏泽龙, 鲁路, 等. 白光LED远程荧光粉技术研究进展与展望[J]. 中国光学, 2015, 8(3):313-328. ZHOU Q C, BAI Z L,LU L, et al.. Remote phosphor technology for white LED applications:advances and prospects[J]. Chin. Opt., 2015, 8(3):313-328. (in Chinese)

MCKITTRICK J, SHEA-ROHWER L E. Review:down conversion materials for solid-state lighting[J]. J. Am. Ceram. Soc., 2014, 97(5):1327-1352.

LIN C C, LIU R S. Advances in phosphors for light-emitting diodes[J]. J. Phys. Chem. Lett., 2011, 2(11):1268-1277.

JANSEN T, JVSTEL T, KIRM M, et al.. Site selective, time and temperature dependent spectroscopy of Eu3+ doped apatites (Mg,Ca,Sr)2Y8 Si6O26[J]. J. Lumin., 2017, 186:205-211.

XIE R J, HIROSAKI N, SUEHIRO T, et al.. A simple, efficient synthetic route to Sr2 Si5N8:Eu2+-based red phosphors for white light-emitting diodes[J]. Chem. Mater., 2006, 18(23):5578-5583.

GRIGORJEVAITE J, KATELNIKOVAS A. Luminescence and luminescence quenching of K2Bi(PO4)(MoO4):Eu3+ phosphors with efficiencies close to unity[J]. ACS Appl. Mater. Interf., 2016, 8(46):31772-31782.

SEIBALD M, ROSENTHAL T, OECKLER O, et al.. New polymorph of the highly efficient LED-phosphor SrSi2O2N2:Eu2+-polytypism of a layered oxonitridosilicate[J]. Chem. Mater., 2013, 25(9):1852-1857.

王迪, 孟祥雨, 赵嘉伟, 等. Ca9Al(PO4)7:Eu2+的发光、浓度猝灭及温度稳定性[J]. 光子学报, 2015, 44(5):0516002. WANG D, MENG X Y, ZHAO J W, et al.. Luminescence, concentration quenching and thermal stability of Ca9Al(PO4)7:Eu2+[J]. Acta Photon. Sinica, 2015, 44(5):0516002. (in Chinese)

杨志平, 梁晓双, 赵引红, 等. 橙红色荧光粉Ca3 Y2(Si3O9)2:Sm3+的制备及发光性能的表征[J]. 光子学报, 2014, 43(3):0316002. YANG Z P, LIANG X S, ZHAO Y H, et al.. Preparation and luminescence properties of reddish-orange phosphors Ca3 Y2(Si3O9)2:Sm3+[J]. Acta Photon. Sinica, 2014, 43(3):0316002. (in Chinese)

曹帅. 碱土七钒酸盐发光材料的制备及发光性质研究[D]. 合肥:安徽大学, 2010. CAO S. The Synthesize and Performance Study of Alkaline Earth Metal Seven Vanadates Luminescent Materials[D]. Hefei:Anhui University, 2010. (in Chinese)

刘昊, 阮健, 韩建军, 等. 绿色钒酸盐荧光粉Ca5Mg4(VO4)6的制备和发光性能[J]. 硅酸盐学报, 2013, 41(3):334-341. LIU H, RUAN J, HAN J J, et al.. Preparation and photoluminescence properties of green-emitting vanadate phosphor Ca5Mg4(VO4)6[J]. J. Chin. Ceram. Soc., 2013, 41(3):334-341. (in Chinese)

MATSUSHIMA Y, KOIDE T, HIRO-OKA M, et al.. Self-activated vanadate compounds toward realization of rare-earth-free full-color phosphors[J]. J. Amer. Ceram. Soc., 2015, 98(4):1236-1244.

SHIRAISHI Y, TAKESHITA S, ISOBE T. Two photoenergy conversion modes of YVO4:Eu3+ nanoparticles:photoluminescence and photocatalytic activity[J]. J. Phys. Chem. C, 2015, 119(24):13502-13508.

SETLUR A A, COMANZO H A, SRIVASTAVA A M, et al.. Spectroscopic evaluation of a white light phosphor for UV-LEDs-Ca2 NaMg2 V3O12:Eu3+[J]. J. Electrochem. Soc., 2005, 152(12):H205-H208.

许静, 傅亚, 原金海, 等. Ba3V2O8:Eu3+纳米花的制备及光致发光性能研究[J]. 功能材料, 2012, 43(18):2564-2567. XU J, FU Y, YUAN J H, et al.. Synthesis and photoluminescence property of Ba3V2O8:Eu3+ nanoflowers[J]. J. Funct. Mater., 2012, 43(18):2564-2567. (in Chinese)

DHOBALE A R, MOHAPATRA M, NATARAJAN V, et al.. Synthesis and photoluminescence investigations of the white light emitting phosphor, vanadate garnet, Ca2 NaMg2 V3O12 co-doped with Dy and Sm[J]. J. Lumin., 2012, 132(2):293-298.

CHEN X, XIA Z G, YI M, et al.. Rare-earth free self-activated and rare-earth activated Ca2 NaZn2V3O12 vanadate phosphors and their color-tunable luminescence properties[J]. J. Phys. Chem. Solids, 2013, 74(10):1439-1443.

XIE H D, TSUBOI T, HUANG W. Luminescence and quantum efficiencies of Eu3+-doped vanadate garnets[J]. J. Am. Ceram. Soc., 2014, 97(5):1434-1441.

SHANNON R D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides[J]. Acta Crystallog. A, 1976, 32(5):751-767.

刘志国, 刘成振, 阮健, 等. 自激活荧光粉Ca2 NaMg2-x Znx(VO4)3(0 x 1.2)的发光性质[J]. 武汉理工大学学报, 2016, 38(1):7-12. LIU Z G, LIU C Z, RUAN J, et al.. Photoluminescence properties of self-activated Ca2 NaMg2-x Znx(VO4)3(0 x 1.2) phosphor[J]. J. Wuhan Univ. Technol., 2016, 38(1):7-12. (in Chinese)

KRAUS W, NOLZE G. Powder Cell for Windows (version 2.3)[M]. Berlin:Federal Institute for Materials Research and Testing, 1999.

KRAUS W, NOLZE G. Powder cell-a program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns[J]. J. Appl. Crystallog., 1996, 29(3):301-303.

LI L P, LI G S, XUE Y F, et al.. Structure, luminescence, and transport properties of EuVO4[J]. J. Electrochem. Soc., 2001, 148(9):J45-J49.

NAKAJIMA T, ISOBE M, TSUCHIYA T, et al.. A revisit of photoluminescence property for vanadate oxides A VO3(A:K, Rb and Cs) and M 3V2O8 (M:Mg and Zn)[J]. J. Lumin., 2009, 129(12):1598-1601.

RONDE H, BLASSE G. The nature of the electronic transitions of the vanadate group[J]. J. Inorg. Nucl. Chem., 1978, 40(2):215-219.

HSU C, POWELL R C. Energy transfer in europium doped yttrium vanadate crystals[J]. J. Lumin., 1975, 10(5):273-293.

YAMAMOTO H, SEKI S, JESER J P, et al.. Thermal quenching of luminescence in a disordered compound:EuNa2Mg2(VO4)3[J]. J. Electrochem. Soc., 1980, 127(3):694-701.

WANG D F, TANG J W, ZOU Z G, et al.. Photophysical and photocatalytic properties of a new series of visible-light-driven photocatalysts M 3V2O8 (M=Mg, Ni, Zn)[J]. Chem. Mater., 2005, 17(20):5177-5182.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Luminescence Properties and Application of Ce³⁺ Doped Ba₃Y₂(BO₃)₄ Phosphor

Methods for Evaluating Hydrolytic Degradation of Mn⁴⁺-activated Fluoride Phosphors

Enhanced Near-infrared Ⅱ Emission in MgAl_xGa_2-_xO₄∶Ni²⁺ Phosphor via Al/Ga Ions Substitution

Regulating Near-infrared Luminescence of ZnGa₂O₄∶Cr³⁺ via F/O Anion Substitution

Luminous Performance and Site-occupation Effect of Sr₂InP₃O₁₁∶Eu³⁺ Red Phosphor

Related Author

SUN Xiaoyuan

LIU Chunmiao

LI Min

TIAN Wanlu

LOU Wenjing

LI Haoxiang

TAN Qinqin

LI Cheng

Related Institution

Department of Physics， Changchun Normal University

Key Laboratory of Luminescence Science and Technology， Chinese Academy of Sciences & State Key Laboratory of Luminescence and Applications， Changchun Institute of Optics， Fine Mechanics and Physics， Chinese Academy of Sciences

School of Materials Science and Engineering， Zhengzhou University

School of Electrical Engineering and Intelligentization， Dongguan University of Technology

Guangdong Provincial Key Laboratory of Nanophotonic Functional Materials and Devices， School of Information and Optoelectronic Science and Engineering， South China Normal University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Photoluminescence Properties of Eu3+-activated Ca1.9 Eu0.1 NaMg2-x Znx(VO4)3(0 ≤ x ≤ 1.0) Phosphor

DOI：10.3788/fgxb20173808.0995

摘要

Abstract

关键词

Keywords

references

Photoluminescence Properties of Eu³⁺-activated Ca_1.9 Eu_0.1 NaMg_2-x Zn_x(VO₄)₃(0 ≤ x ≤ 1.0) Phosphor